| 1 | Chloro-free synthesis of LiPF_(6)using the fluorine-oxygen exchange technique显示文摘A hydrogen fluoride-free and chloro-free method for synthesizing LiPF_(6) was developed.Employing CaF_(2) as the direct fluorinating reagent instead of hydrogen fluoride made it much safer and more environmentfriendly than conventional methods and reduced the metal residues in product owing to the relatively low-acid reaction conditions less corrosive to equipments.The use of P_(2)O_(5) as phosphorus source instead of traditionally employed PCl_(5) significantly reduced the chloro residue in product.Ca(H_(2)PO_(4))_(2),the only by-product of the process,could be easily converted into Ca_(3)(PO_(4))_(2),a best-selling chemical.The above advantages not only reduce the production costs by ca.20%,but also significantly improve the product purity.The fluorine-oxygen exchange reaction is a completely new technique for LiPF_(6) production and may bring about technological revolution in the related industry. | Jian Liu Yuanli Cai Huan Pang Bin Cao Chengzhi Luo Zhenghao Hu Chaoqun Xiao Hu Zhang Fulu Lv Yitao Cao Lei Yu | 2022 | Chinese Chemical Letters2022，33，8： | 1 |
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