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| 1 | Synthesis of Ni_2P promoted trimetallic NiMoW/γ-Al_2O_3 catalysts for diesel oil hydrotreatment显示文摘The Ni2P promoted and γ-Al2O3 supported NiMoW sulfide catalyst consisting of 4 wt% Mo, 22 wt% W, 2 wt% Ni and 2.5 wt% Ni2P was synthesized by a co-impregnation method. The catalysts were characterized by N2 adsorption-desorption, X-ray diffraction (XRD), diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, NH3 temperature-programmed desorption (NH3-TPD) and transmission electron microscopy (TEM). The results showed that Ni2P, Ni, Mo and W species were highly dispersed over γ-Al2O3. The hydrodesulfurization (HDS) of dibenzothiophene (DBT) showed that the presence of Ni2P brought a strong promotional effect on the HDS activity, which was further confirmed by the HDS and hydrodenitrogenation (HDN) of diesel oil under industrial conditions. The enhancement in HDN activity and stability by Ni2P addition could be attributed more to the effect of new active sites of Ni2P than that of acidity modification. The as-prepared Ni2P-NiMoW/γ-Al2O3 catalyst showed better hydrotreating performance than NiMoW/γ-Al2O3 and commercial catalysts. | Ling Lan Shaohui Ge Kunhong Liu Yuandong Hou Xiaojun Bao | 2011 | Journal of Natural Gas Chemistry2011，20，2： | 3 |
| 2 | Influences of preparation methods of ZrO2 support and treatment conditions of Cu/ZrO2 catalysts on synthesis of methanol via CO hydrogenation 显示文摘 | Bai Yongge He Dehua Ge Shaohui | 2010 | Catalysis Today2010，，149： | 1 |
| 3 | Interfering with cellular signaling pathways enhances sensitization to combined sodium butyrate and GCV treatment in EBV-positive tumor cells显示文摘 | Yuwen He Shaohui Cai Ge Zhang Xiaoqing Li Liting Pan Jun Du | 2008 | Virus Research2008，，1： | 1 |
| 4 | Synthesis and characterization of titania MQ silicone resin hybrid nanocomposite via sol- gel process显示文摘 | Hongping Xiang Jianfeng Ge Shaohui Cheng | 2011 | Journal of Sol- Gel Science and Technology2011，59，3： | 1 |
| 5 | Interfering with cellular signaling pathways enhances sensitization to combined sodium butyrate and GCV treatment in EBV-positive tumor cells显示文摘 | Yuwen He Shaohui Cai Ge Zhang Xiaoqing Li Liting Pan Jun Du | 2008 | Virus Research2008，，1： | 1 |
| 6 | Influences of preparation methods of ZrO2 support and treatment conditions of Cu/ZrO2 catalysts on synthesis of methanol via CO hydrogenation 显示文摘 | Yongge Bai Dehua He Shaohui Ge | 2010 | Catalysis Today2010，149，： | 1 |
| 7 | Synthesis and characterization of titania/MQ silicone resin hybrid nanocomposite via sol-gel process显示文摘 | Xiang Hongping Ge Jianfeng Cheng Shaohui | 2011 | J Sol-Gel Sci Techn2011，59，： | 1 |
| 8 | Engineering the morphology/porosity of oxygen-doped carbon for sulfur host as lithium-sulfur batteries显示文摘Despite the intriguing merits of lithium-sulfur(Li-S) systems, they still suffer from the notorious‘‘shuttling-effect' of polysulfides. Herein, carbon materials with rational tailoring of morphology and pores were designed for strong loading/adsorption with the controlling of energy-storage ability.Through rational tailoring, it is strongly verified that such engineering of evolutions result in variational of sulfur immobilization in the obtained carbon. As expected, the targeted sample delivers a stable capacity of 925 m Ah g^(-1) after 100 loops. Supporting by the 'cutting-off' manners, it is disclosed that mesopores in carbon possess more fascinated traits than micro/macropores in improving the utilization of sulfur and restraining Li_(2)S_x(4≤x≤8). Moreover, the long-chain polysulfide could be further consolidated by auto-doping oxygen groups. Supported by in-depth kinetic analysis, it is confirmed that the kinetics of ion/e-transfer during charging and discharging could be accelerated by mesopores, especially in stages of the formation of solid S_(8) and Li_(2)S, further improving the capacity of ion-storage in Li-S battery. Given this, the elaborate study provide significant insights into the effect of pore structure on kinetic performance about Li-storage behaviors in Li-S battery, and give guidance for improving sulfur immobilization. | Limin Zhang Wenqing Zhao Shaohui Yuan Feng Jiang Xingqi Chen Yue Yang Peng Ge Wei Sun Xiaobo Ji | 2021 | Journal of Energy Chemistry2021，30，9： | 1 |
| 9 | Micropore engineering on hollow nanospheres for ultra-stable sodium-selenium batteries显示文摘Attracted by high energy density and considerable conductivity of selenium(Se),Na-Se batteries have been deemed promising energy-storage systems.But,it still suffers from sluggish kinetic behaviors and similar“shuttling effect”to S-electrodes.Herein,utilizing uniform hollow carbon spheres as precursors,Se-material is effectively loaded through vapor-infiltration method.Owing to the distribution of optimized pores,the content of microspores could be up to~60%(<2 nm),serving important roles for the physical confinement effect.Meanwhile,the rich oxygen-containing groups and N-elements could be noted,inducing the evolution of electron-moving behaviors.More significantly,assisted by the interfacial C-Se bonds and tiny Se distributions,Se electrodes are activated during cycling.Used as cathodes for Na-Se systems,the as-resulted samples display a capacity of 593.9 mA h g^(-1)after 100 cycles at the current density of 0.1 C.Even after 6000 cycles,the capacity could be still kept at about 225 mA h g^(-1)at 5.0 C.Supported by the detailed kinetic analysis,the designed microspores size induces the increasing redox reaction of nano Se,whilst the surface traits further render the enhancement of pseudo-capacitive contributions.Moreover,after cycling,the product Sex(x<4)in pores serves as the primary active material.Given this,the work is anticipated to provide an effective strategy for advanced electrodes for Na-Se systems. | Gongke Wang Yumeng Chen Yu Han Lixue Yang Wenqing Zhao Changrui Chen Zihao Zeng Shuya Lei Shaohui Yuan Peng Ge | 2023 | Journal of Energy Chemistry2023，，5： | 0 |
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