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| 1 | Wet and dry deposition fluxes of heavy metals in Pearl River Delta Region(China):Characteristics,ecological risk assessment,and source apportionment显示文摘The atmospheric deposition of heavy metals poses serious risks to the ecological system and human health. To advance our knowledge of atmospheric dry/wet heavy metal deposition in the PRD region, monthly fluxes were examined based on soluble/insoluble fractions of five heavy metal elements(Cu, Pb, Cd, Cr and Zn) in samples collected from January 2014 to December 2015 at Guangzhou(urban) and Dinghushan(suburban) sites. The ratios of wet/dry deposition fluxes indicated that heavy metal deposition was governed by wet deposition rather than dry deposition in the PRD region. Affected by the shifting of the Asian monsoon, wet deposition fluxes exhibited significant seasonal variation between summer monsoon seasons(April to September) and winter monsoon seasons(October to February) in this region. Cd was classified as an extremely strong potential ecological risk based on solubility and the Hakanson ecological risk index. Source contributions to wet deposition were calculated by PMF, suggesting that dust, biomass burning, industries,vehicles, long-range transport and marine aerosol sources in Guangzhou, and Zn fertilizers,marine aerosol sources, agriculture, incense burning, biomass burning, vehicles and the ceramics industry in Dinghushan, were the potential sources of heavy metals. | Lyumeng Ye Minjuan Huang Buqing Zhong Xuemei Wang Qiulan Tu Haoran Sun Chao Wang Luolin Wu Ming Chang | 2018 | Journal of Environmental Sciences2018，30，8： | 20 |
| 2 | Comparison of microstructures and mechanical properties of composite extruded AZ31 sheets显示文摘The microstructures and mechanical properties of the composite extruded AZ31/AZ31 and AZ31/4047 Al sheets were investigated and made a comparison to the conventional extruded AZ31 sheet.Owing to the introduced intense shear deformation at the interface during the composite extrusion,grain refinement and tilted texture were detected in AZ31 layers of the AZ31/AZ31 and AZ31/4047 Al sheets,while the conventional extruded AZ31 sheet exhibited a relative coarse,inhomogeneous microstructure and strong basal texture.The compressiontension yield ratio was increased gradually from the AZ31 to the AZ31/AZ31 and AZ31/4047 Al sheets.Besides,the AZ31/4047 Al sheet could successfully accomplish the whole bending forming process at room temperature,while the AZ31 and AZ31/AZ31 sheets were both bend-formed to failure with significant cracks in the outer tensile region under the identical bending parameters.Moreover,under the same bending strain,both the outward offset degree of strain neutral layer and the sheet thickening were more serious in the AZ31/4047 Al composite sheet than those of the AZ31 and AZ31/AZ31 sheets.The foremost reason was the quite wide gap of material properties between Mg alloy AZ31 layer(tensile loading in the outer region)and Al 4047 layer(compressive loading in the inner region). | Yanfu Chai Yan Song Bin Jiang Jie Fu Zhongtao Jiang Qingshan Yang Haoran Sheng Guangsheng Huang Dingfei Zhang Fusheng Pan | 2019 | Journal of Magnesium and Alloys2019，7，4： | 11 |
| 3 | Activated carbons and amine-modified materials for carbon dioxide capture- a review显示文摘 | Zhenhe CHEN Shubo DENG Haoran WEI Bin WANG Jun HUANG Gang YU | 2013 | Frontiers of Environmental Science & Engineering2013，7，3： | 9 |
| 4 | Is seawater geochemical composition recorded in marine carbonate? Evidence from iron and manganese contents in Late Devonian carbonate rocks显示文摘Iron and manganese are the important redoxsensitive elements in the ocean. Previous studies have established a series of paleo-depositional redox proxies based on the form and content of iron in sedimentary rocks(e.g., degree of pyritization, FeHR/FeT, Fe/Al). These proxies were developed and applied on siliciclastic-rich marine sediments. Although marine carbonate rocks are generally considered to preserve the geochemical signals of ancient seawater, neither Fe nor Mn content in marine carbonate rocks(Fecarb, Mncarb) has been independently used as a proxy to quantify environmental cues in paleo-oceans. Both Fe and Mn are insoluble in oxic conditions(Fe_2O_3, Fe(OH)_3,MnO_2), while their reduced forms(Fe^(2+) and Mn^(2+)) are soluble. Therefore, oxic seawater should have low concentrations of dissolved Fe^(2+)and Mn^(2+), and accordingly carbonate rocks precipitated from oxic seawater should have low Fecarband Mncarb, and vice versa. To evaluate whether Fecarband Mncarbcan be used to quantify oxygen fugacity in seawater, we measured Fecarband Mncarbof Upper Devonian marine carbonate rocks collected from nine sections in South China. Fecarbof intraplatform basin samples wassignificantly higher than that of shelf samples, while shelf and basin samples had comparable Mncarb. The modeling result indicates that the dramatic difference in Fecarbcannot be explained by variation in oxygen fugacity between the shelf and basin seawater. Instead, both Fecarband Mncarb appear to be more sensitive to benthic flux from sediment porewater that is enriched in Fe^(2+)and Mn^(2+). Porewater Fe^(2+)and Mn^(2+)derive from bacterial iron and manganese reduction; flux was controlled by sedimentation rate and the depth of the Fe(Mn) reduction zone in sediments, the latter of which is determined by oxygen fugacity at the water–sediment interface. Thus, high Fecarbof the basin samples might be attributed to low sedimentation rate and/or low oxygen fugacity at the seafloor. However, invariant Mncarbof the shelf and basin samples might be the consequence of complete reduction of Mn in sediments. Our study indicates that marine carbonate rocks may not necessarily record seawater composition, particularly for benthic carbonate rocks. The influence of benthic flux might cause carbonate rocks' geochemical signals to deviate significantly from seawater values. Our study suggests that interpretation of geochemical data from carbonate rocks, including carbonate carbon isotopes, should consider the process of carbonate formation. | Zhe Wang Wen Guo Ting Nie Haoran Ma Tianzheng Huang Yuanlin Sun Bing Shen | 2019 | Acta Geochimica2019，38，2： | 5 |
| 5 | Marine Carbon-Sulfur Biogeochemical Cycles during the Steptoean Positive Carbon Isotope Excursion(SPICE) in the Jiangnan Basin, South China显示文摘Global occurrences of Steptoean Positive Carbon Isotope Excursion(SPICE) during Late Cambrian recorded a significant perturbation in marine carbon cycle, and might have had profound impacts on the biological evolution. In previous studies, SPICE has been reported from the Jiangnan slope belt in South China. To evaluate the bathymetric extent of SPICE, we investigate the limestone samples from the upper Qingxi Formation in the Shaijiang Section in the Jiangnan Basin. Our results show the positive excursions for both carbonate carbon(δ^(13)C) and organic carbon(δ^(13)C_(org)) isotopes, as well as the concurrent positive shifts in sulfur isotopes of carbonate associated sulfate(CAS, δ^(34)S_(CAS)) and pyrite(δ^(34)S_(pyrite)), unequivocally indicating the presence of SPICE in the Jiangnan Basin. A 4‰ increase in δ^(13)C_(carb) of the Qingxi limestone implies the increase of the relative flux of organic carbon burial by a factor of two. Concurrent positive excursions in δ^(34)S_(CAS) and δ^(34)S_(pyrite) have been attributed to the enhanced pyrite burial in oceans with extremely low concentration and spatially heterogeneous isotopic composition of seawater sulfate. Here, we propose that the seawater sulfur isotopic heterogeneity can be generated by volatile organic sulfur compound(VOSC, such as methanethiol and dimethyl sulfide) formation in sulfidic continental margins that were widespread during SPICE. Emission of 32S-enriched VOSC in atmosphere, followed by lateral transportation and aerobic oxidation in atmosphere, and precipitation in open oceans result in a net flux of ^(32)S from continental margins to open oceans, elevating δ^(34)S of seawater sulfate in continental margins. A simple box model indicates that about 35% to 75% of seawater sulfate in continental margins needs to be transported to open oceans via VOSC formation. | Yang Peng Yongbo Peng Xianguo Lang Haoran Ma Kangjun Huang Fangbing Li Bing Shen | 2016 | Journal of Earth Science2016，27，2： | 5 |
| 6 | Bimodular effects of D614G mutation on the spike glycoprotein of SARS-CoV-2 enhance protein processing,membrane fusion,and viral infectivity显示文摘Dear Editor,By the end of June 2020,the pandemic of coronavirus diseases 2019(COVID-19)had resulted in more than 10 million individuals,all over the world,being infected with the severe acute respiratory syndrome coronavirus 2(SARS-CoV-2).1 The high contagiousness of SARS-CoV-2 virus was largely attributed to the relatively unique sequence composition in its spike(S)glycoprotein,which is in charge of the host entry by interacting with its cellular receptor angiotensin-converting enzyme 2(ACE2).2,3 The S glycoprotein can be processed into an N terminal S1 fragment that is responsible for receptor binding,and a C terminal S2 fragment that functions to promote membrane fusion.4 SARS-CoV-2 is a type of single-stranded positive-sense ribonucleic acid(RNA)virus,and an increasing number of mutations were identified across the SARS-CoV-2 genome,including the region encoding S glycoprotein.Nevertheless,the functional implications of these mutations remain largely unknown,we here reported the mutation analysis of S gene and a functional exploration of the dominant D614G mutation. | Xiaoyi Jiang Zhengrong Zhang Chenxi Wang Hongguang Ren Lihua Gao Haoran Peng Zubiao Niu He Ren Hongyan Huang Qiang Sun | 2020 | Signal Transduction and Targeted Therapy2020，5，1： | 5 |
| 7 | Hexagonal boron nitride nanosheet for effective ambient N2 fixation to NH3显示文摘Industrial production of NH3 from N2 and H2 significantly relies on Haber-Bosch process,which suffers from high energy consume and CO2 emission.As a sustainable and environmentally-benign alternative process,electrochemical artificial N2 fixation at ambient conditions,however,is highly required efficient electrocatalysts.In this study,we demonstrate that hexagonal boron nitride nanosheet (h-BNNS) is able to electrochemically catalyze N2 to NH3.In acidic solution,h-BNNS catalyst attains a high NH3 formation rate of 22.4 μg·h-1·mg-1cat.and a high Faradic efficiency of 4.7% at-0.75 V vs.reversible hydrogen electrode,with excellent stability and durability.Density functional theory calculations reveal that unsaturated boron at the edge site can activate inert N2 molecule and significantly reduce the energy barrier for NH3 fonmation. | Ya Zhang Huitong Du Yongjun Ma Lei Ji Haoran Guo Ziqi Tian Hongyu Chen Hong Huang Guanwei Cui Abdullah M. Asiri Fengli Qu Liang Chen Xuping Sun | 2019 | Nano Research2019，12，4： | 5 |
| 8 | CO_2 methanation over TiO_2–Al_2O_3 binary oxides supported Ru catalysts显示文摘TiO_2 modified Al_2O_3 binary oxide was prepared by a wet-impregnation method and used as the support for ruthenium catalyst. The catalytic performance of Ru/TiO_2–Al_2O_3catalyst in CO_2 methanation reaction was investigated. Compared with Ru/Al_2O_3 catalyst, the Ru/TiO_2–Al_2O_3catalytic system exhibited a much higher activity in CO_2 methanation reaction. The reaction rate over Ru/TiO_2–Al_2O_3 was 0.59 mol CO_2·(g Ru)1·h-1, 3.1 times higher than that on Ru/Al_2O_3[0.19 mol CO_2·(gRu)-1·h-1]. The effect of TiO_2 content and TiO_2–Al_2O_3calcination temperature on catalytic performance was addressed. The corresponding structures of each catalyst were characterized by means of H_2-TPR, XRD, and TEM. Results indicated that the averaged particle size of the Ru on TiO_2–Al_2O_3support is 2.8 nm, smaller than that on Al_2O_3 support of 4.3 nm. Therefore, we conclude that the improved activity over Ru/TiO_2–Al_2O_3catalyst is originated from the smaller particle size of ruthenium resulting from a strong interaction between Ru and the rutile-TiO_2 support, which hindered the aggregation of Ru nanoparticles. | Jinghua Xu Qingquan Lin Xiong Su Hongmin Duan Haoran Geng Yanqiang Huang | 2016 | Chinese Journal of Chemical Engineering2016，24，1： | 4 |
| 9 | Vesicular Li3V2(PO4)3/C hollow mesoporous microspheres as an efficient cathode material for lithium-ion batteries显示文摘Vesicular lithium vanadium phosphate/carbon hollow mesoporous microspheres were fabricated using a facile polyvinylpyrrolidone-assisted aerosol-spray-assisted method and subsequent heat-treatment. While changing the content of polyvinylpyrrolidone, we found that carbon content was adjustable on the surface of lithium vanadium phosphate. By optimizing the carbon content among the composites, the electrochemical performance can be enhanced significantly. The results of electrochemical performance tests suggested that the samples exhibited good cycle performance and high discharge capability in the voltages between 3.0-4.8 V. The observed excellent electrochemical performances could be attributed to the proper content of carbon coating and the vesicular hollow mesoporous microsphere structure, increasing the transmission rate of lithium ions and reducing the structural change during charging and discharging effectively. | Hongxia Sun Haoran Du Mengkang Yu Kuangfu Huang Nan Yu Baoyou Geng | 2019 | Nano Research2019，12，8： | 4 |
| 10 | Gas template-assisted spray pyrolysis: A facile strategy to produce porous hollow Co3O4 with tunable porosity for high-performance lithium-ion battery anode materials显示文摘 | Haoran Du Kuangfu Huang Min Li Yuanyuan Xia Yixuan Sun Mengkang Yu Baoyou Geng | 2018 | Nano Research2018，11，3： | 4 |
| 11 | Unveiling annealing texture formation and static recrystallization kinetics of hot-rolled Mg-Al-Zn-Mn-Ca alloy显示文摘The development of Mg-Al-Zn-Mn-Ca series alloys provides a potential prospect to achieve high strength and formability at room temperature(RT).The formation of elliptical annular texture is treated as a crucial factor for the enhanced RT formability.However,the origin of such an elliptical annular texture formation has been rarely reported.Herein,we unveiled the formation and evolution of elliptical annular texture in the hot-rolled Mg-1.6 Al-0.8 Zn-0.4 Mn-0.5 Ca(AZMX1100,wt.%)alloy after annealing at different temperatures for 1 h,and its static recrystallization(SRX)kinetics in given annealing temperature for different time.The results revealed that the formation of elliptical annular texture in the hot-rolled AZMX1100 alloy after annealing was derived from nucleation-oriented SRX mechanism,which took place in 200-300°C,induced by cracked chain-shaped Al2 Ca phases,contraction twins,intersections of double twins,intersections of double twins and grain boundaries and non-basal slips.On further annealing from300-450°C,the grains with 45°–70°transverse direction(TD)preferentially grew,which made elliptical annular texture extended along the TD.Based on the Johnson-Mehl-Avrami-Kolmogorov(JMAK)model,Avrami exponent n value was estimated to be 0.68–1.02,attributed to non-random SRX nucleation,giving rise to the lower activation energy QRof nucleation of^74.24 k J/mol.Since the co-segregation of Al,Zn and Ca atoms in grain boundaries created a strong interaction of solutes and grain boundaries,the hot-rolled AZMX1100 alloy exhibited the higher activation energy Qg(~115.48 k J/mol)of grain growth. | Qinghang Wang Bin Jiang Aitao Tang Jie Fu Zhongtao Jiang Haoran Sheng Dingfei Zhang Guangsheng Huang Fusheng Pan | 2020 | Journal of Materials Science & Technology2020，36，8： | 3 |
| 12 | Load Distribution Research on Pitch Bearing of Wind Turbine Generators显示文摘变桨轴承是风电机组传动与控制系统的关键部件,安装形式特殊且承受复杂的轴向、径向力和倾覆力矩等交变载荷。文中基于经典的赫兹弹性接触理论,建立了刚性套圈承受多向力和倾覆力矩的双排四点接触球变桨轴承的力学模型。在此基础上,应用弹性等理论研究套圈变形对轴承载荷分布的影响,推导轴承外载荷和滚动体接触力等载荷作用下转盘轴承内、外套圈的弯曲变形方程,联立非线性超越方程组给出了四点接触球转盘轴承分布载荷的求解方法。以某型号变桨轴承为例,分别采用刚性和柔性套圈2种模型对轴承载荷分布进行了计算和对比分析。结果表明2种模型下轴承载荷分布有显著区别,柔性套圈模型下的承载区间减小,载荷分布更加均匀,滚动体的承载能力有很大的提升。相关力学问题的研究可为变桨轴承结构设计提供必要的理论依据。 | RUI Xiaoming ZHENG Hui HUANG Haoran | 2013 | 中国电机工程学报2013，33，32： | 3 |
| 13 | A high-performance Mg-4.9Gd-3.2Y-1.1Zn-0.5Zr alloy via multidirectional forging after analyzing its compression behavior显示文摘A high-performance Mg-4.9Gd-3.2Y-1.1Zn-0.5Zr alloy has been fabricated by multidirectional forging(MDF)after analyzing its compression behavior.The as-homogenized alloy exhibits a high activation energy Q of deformation(~285 kJ/mol).The size of DRXed grains after compression tends to decrease as the Z-H parameter(Z)increases,showing a grain size exponent m of~4.0.Lamellar LPSO phases,kinking deformation,and bimodal microstructure are detected at the relatively low compression temperature of 350 and 400℃,while sufficient DRX can be achieved at 500℃,accompanied by the dissolution of lamellar LPSO.According to the processing maps,MDF was successfully conducted under an appropriate condition.After peak-aged at 200℃for 78 h,the MDFed billet exhibits a tensile yield strength(TYS)of 331 and 305 MPa at room temperature and 200℃,respectively.The high strength mainly results from the combination of fine grains,low Schmid factor for basal slip,sufficientβ’ageing precipitates,and directionally arranged interdendritic LPSO phases,etc.This paper provides a feasible way for the fabrication of high-performance,low-RE-content,and large-scale Mg components for industrial production. | Xiaojie Zhou Yuan Yao Jian Zhang Xiaomin Chen Weiying Huang Jing Pan Haoran Wang Maopeng Weng | 2021 | Journal of Materials Science & Technology2021，，11： | 3 |
| 14 | Heterogeneous Mg isotopic composition of the early Carboniferous limestone: implications for carbonate as a seawater archive显示文摘Carbonate precipitation and hydrothermal reaction are the two major processes that remove Mg from seawater.Mg isotopes are significantly(up to 5%)fractionated during carbonate precipitation by preferential incorporation of ^(24)Mg,while hydrothermal reactions are associated with negligible Mg isotope fractionation by preferential sequestration of^( 26)Mg.Thus,the marine Mg cycle could be reflected by seawater Mg isotopic composition(δ^(26)Mg_(sw)),which might be recorded in marine carbonate.However,carbonates are both texturally and compositionally heterogeneous,and it is unclear which carbonate component is the most reliable for reconstructing δ^(26)Mg_(sw).In this study,we measured Mg isotopic compositions of limestone samples collected from the early Carboniferous Huangjin Formation in South China.Based on petrographic studies,four carbonate components were recognized:micrite,marine cement,brachiopod shell,and mixture.The four components had distinct δ^(26)Mg:(1)micrite samples ranged from -2.86% to -2.97%;(2)pure marine cements varied from -3.40% to -3.54%,while impure cement samples containing small amount of Rugosa coral skeletons showed a wider range(-3.27% to-3.75%);(3)values for the mixture component were-3.17% and -3.49%;and (4)brachiopod shells ranged from -2.20% to -3.07%,with the thickened hinge area enriched in ^( 24)Mg.Due to having multiple carbonate sources,neither the micrite nor the mixture component could be used to reconstruct δ^(26)Mg_(sw).In addition,the marine cement was homogenous in Mg isotopes,but lacking the fractionation by inorganic carbonate precipitation that is prerequisite for the accurate determination of δ^(26)Mg_(sw).Furthermore,brachiopod shells had heterogeneous C and Mg isotopes,suggesting a significant vital effect during growth.Overall,the heterogeneous δ^(26)Mg of the Huangjin limestone makes it difficult to reconstruct δ^(26)Mg_(sw)using bulk carbonate/calcareous sediments.Finally,δ^(26)Mg_(sw)was only slightly affected by the faunal composition of carbonate-secreting organisms,even though biogenic carbonate accounts for more than 90% of marine carbonate production in Phanerozoic oceans and there is a wide range(0.2%–4.8%)of fractionation during biogenic carbonate formation. | Haoran Ma Yihe Xu Kangjun Huang Yuanlin Sun Shan Ke Yang Peng Xianguo Lang Zhen Yan Bing Shen | 2018 | Acta Geochimica2018，37，1： | 3 |
| 15 | Geochemical records of carbon in recent sediments of Erhai Lake, China: Implication of effects of the Himalayas uplift on global environmental changes显示文摘THE formation and uplift of the Himalayas and the Tibetan Plateau may have been responsible for the past150 Ma global environmental changes, resulting in the development of a three-tiered landform in southernChina. The Yunnan-Guizhou Plateau, as the middle tier in eastern slope of the Himalayas, has beencomplex environmental unit with great altitude gradients and plateau landform characters. Both monsoonsfrom the Pacific and the Indian resulting in apparent environmental changes on variable time scales influence it. Environmental geochemical effect of low latitude-high altitude could be yielded, and well recorded in the geological bodies in this region. To build and verify a quantitative model of environmental evolution it is necessary to obtain high-resolution data of elemental cycles and mass equilibrium. | WAN Guojiang~1, BAI Zhanguo~(1,2), WANG Haoran~1 and HUANG Ronggui~1 1. State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China 2. State Key Laboratory of Plant Nutrition Research of Chinese Ministry of Agriculture, Institute of Soil and Fertilizer, Chinese Academy of Agricultural Sciences, Beijing 100081, China | 1999 | Chinese Science Bulletin1999，44，S2： | 2 |
| 16 | Recent progress of morphable 3D mesostructures in advanced materials显示文摘Soft robots complement the existing efforts of miniaturizing conventional,rigid robots,and have the potential to revolutionize areas such as military equipment and biomedical devices.This type of system can accomplish tasks in complex and time-varying environments through geometric reconfiguration induced by diverse external stimuli,such as heat,solvent,light,electric field,magnetic field,and mechanical field.Approaches to achieve reconfigurable mesostructures are essential to the design and fabrication of soft robots.Existing studies mainly focus on four key aspects:reconfiguration mechanisms,fabrication schemes,deformation control principles,and practical applications.This review presents a detailed survey of methodologies for morphable mesostructures triggered by a wide range of stimuli,with a number of impressive examples,demonstrating high degrees of deformation complexities and varied multi-functionalities.The latest progress based on the development of new materials and unique design concepts is highlighted.An outlook on the remaining challenges and open opportunities is provided. | Haoran Fu Ke Bai Yonggang Huang Yihui Zhang | 2020 | Journal of Semiconductors2020，41，4： | 2 |
| 17 | Overview of recent progress in condition monitoring for insulated gate bipolar transistor modules:Detection,estimation,and prediction显示文摘The insulated gate bipolar transistor(IGBT)is one of the most fragile components in power electronics converters.In order to improve the reliability of IGBTs,various measurements are taken according to the condition monitoring(CM)technique.Traditional CM techniques include the measurement and estimation of the device operation conditions.Recently,emerging techniques have been developed,not only for the detection and estimation but also for the prognostics of IGBTs with the condition data.In this paper,a review is performed on the recent progress in the CM techniques for IGBTs.First,some emerging electrical and thermal measurements are reviewed.Based on the sensed data,the health indicator estimation techniques are summarised.Moreover,for the emerging prognostics and health management applications,some remaining using lifetime(RUL)prediction methods are reviewed.Finally,the research gaps and directions are discussed for the CM in IGBT applications. | Meng Huang Haoran Wang Liangjun Bai Kang Li Ju Bai Xiaoming Zha | 2021 | High Voltage2021，6，6： | 2 |
| 18 | Cracking the superheavy pyrite enigma:possible roles of volatile organosulfur compound emission显示文摘The global deposition of superheavy pyrite(pyrite isotopically heavier than coeval seawater sulfate in the Neoproterozoic Era and particularly in the Cryogenian Period)defies explanation using the canonical marine sulfur cycle system.Here we report petrographic and sulfur isotopic data(δ^(34)Spy)of superheavy pyrite from the Cryogenian Datangpo Formation(660–650 Ma)in South China.Our data indicate a syndepositional/early diagenetic origin of the Datangpo superheavy pyrite,with ^(34)S-enriched H_(2)S supplied from sulfidic(H_(2)S rich)seawater.Instructed by a novel sulfur-cycling model,we propose that the emission of ^(34)S-depleted volatile organosulfur compounds(VOSC)that were generated via sulfide methylation may have contributed to the formation of ^(34)S-enriched sulfidic seawater and superheavy pyrite.The global emission of VOSC may be attributed to enhanced organic matter production after the Sturtian glaciation in the context of widespread sulfidic conditions.These findings demonstrate that VOSC cycling is an important component of the sulfur cycle in Proterozoic oceans. | Xianguo Lang Zhouqiao Zhao Haoran Ma Kangjun Huang Songzhuo Li Chuanming Zhou Shuhai Xiao Yongbo Peng Yonggang Liu Wenbo Tang Bing Shen | 2021 | National Science Review2021，8，10： | 2 |
| 19 | Wafer-scale patterned growth of type-II Dirac semimetal platinum ditelluride for sensitive room-temperature terahertz photodetection显示文摘As the lastly unexplored electromagnetic wave,terahertz(THz)radiation has been exploited in a plenty of contexts such as fundamental research,military and civil fields.Most recently,representative two-dimensional(2D)topological semimetal,platinum ditelluride(PtTe_(2))has attracted considerable research interest in THz detection due to its unique physical properties.However,to achieve practical applications,the low-cost,large-scale,controllable synthesis and efficient patterning of 2D materials are key requirements,which remain a challenge for PtTe_(2)and its photodetectors(PDs).Herein,a facile approach is developed to obtain waferscale(2-inches)patterned PtTe_(2)arrays using one-step tellurium-vapor transformation method and micro-Nano technology.PtTe_(2)PD arrays are fabricated with the as-grown PtTe_(2)arrays evenly distributed on a 2-inch wafer,exhibiting high conductivity(~2.7×105 S m^(-1))and good electrical consistency.Driven by the Dirac fermions,PtTe_(2)PDs achieve a broadband(0.02-0.3 THz)response with a fast response speed(~4.7μs),a high sensitivity(~47 pW Hz^(-1/2))and high-resolution transmission THz-imaging capability,which displays the potential of large-area THz array imaging.These results are one step towards the practical applications of integrated PD arrays based on 2D materials. | Zhuo Dong Wenzhi Yu Libo Zhang Liu Yang Luyi Huang Yan Zhang Zeqian Ren Haoran Mu Cheng Chen Junrong Zhang Jie Li Lin Wang Kai Zhang | 2023 | InfoMat2023，5，5： | 1 |
| 20 | Low-bandgap conjugated polymers based on benzodipyrrolidone with reliable unipolar electron mobility exceeding 1 cm^(2) V^(-1)s^(-1)显示文摘The employment of an intrinsic quinoidal building block,benzodipyrrolidone(BDP),on constructing conjugated polymers(PBDP-2F and PBDP-2CN)with high electron mobility and unipolar transport characteristic in polyethylenimine ethoxylated(PEIE)modified organic field-effect transistors(OFETs)is reported.The intrinsic quinoidal characteristic and excellent coplanarity of BDP can lower the lowest unoccupied molecular orbital(LUMO)levels and improve ordered interchain packing of the resulting polymers in solid states,which are favorable for electron-injection and transport.By using PEIE as the interlayer to block the hole injection,unipolar n-type transport characteristics with high electron mobility of 0.58 and 1.01 cm^(2) V^(-1)s^(-1)were achieved by the OFETs based on PBDP-2F and PBDP-2CN,respectively.More importantly,the extracted mobilities are highly reliable with the reliability factor of above 80%.To the best of our knowledge,PBDP-2CN is the very first quinoid-based conjugated polymer with reliable electron mobility exceeding 1 cm^(2) V^(-1)s^(-1).This work represents a significant step in exploring intrinsic quinoidal CPs for application in n-channel OFETs and logic complementary circuits. | Mingqun Yang Tian Du Xuxia Zhao Xuelong Huang Langheng Pan Shuting Pang Haoran Tang Zhongxiang Peng Long Ye Yunfeng Deng Mingliang Sun Chunhui Duan Fei Huang Yong Cao | 2021 | Science China Chemistry2021，64，7： | 1 |
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