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1Pb isotopic geochemical study on the crustal structure of Tongbaishan显示文摘Pb isotopic composition of the Tongbai complex, distributed in the Tongbaishan to the west of the Dabieshan, ranges between the Dabie core complex and the Dabie ultral-high pressure (UHP) metamorphic complex, the latter having more radiogenic Pb isotopic composition than the former. Granites from the Jigongshan pluton, which intruded mainly into the Tongbai complex, are distinct from the Tongbai complex but similar to the Dabie core complex in Pb isotopic composition, showing that the magma of the Jigongshan granites was derived from the partial melting of the Dabie core complex. According to Pb isotopic compositional variation model in the vertical crustal section and magma source from the Jigongshan pluton, it is suggested that the Tongbai complex was an upper rock serial of the Dabie core complex, which is beneath the Dabie UHP metamorphic complex in the crustal structure of the Tongbai-Dabie orogenic belt. The Tongbai complex was not well preserved in the Dabie area due to the high exhumed crustal section. However, the crustal section in the Tongbai area was exhumed less than that in the Dabie area, and the deep crust in the Tongbai area still contains the basement composition similar to the Dabie core complex. Therefore, the crustal basements from the Dabie to Tongbai areas are united. The present distribution of the basement blocks in different locations of the Tongbai-Dabie orogenic belt reflects different exposure of the crustal section.ZHANG Hongfei, ZHANG Benren, ZHONG Zenqiu, SOU Shutian, ZHANG Haizu and WANG Linsen(China University of Geosciences, Wuhan 430074, China) 2003Progress in Natural Science:Materials International2003,13,1:10
2Origin of the unusually high dibenzothiophene concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin,China显示文摘The origin of the unusually high dibenzothiophene (DBT) concentrations in Lower Ordovician oils from the Tazhong Uplift,Tarim Basin was studied by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS).The most abundant sulfur compounds in the oils are S 1 species with doublebond equivalent (DBE) values of 1-19 and 11-48 carbon atoms.The range of the number of carbon atoms in the sulfur compounds detected by the FT-ICR MS (S 1 species with DBE=9) is about ten times larger than that for sulfur compounds detected by GC/MS (DBTs).This suggests that FT-ICR MS is a much better approach than GC/MS for characterization of DBTs in crude oils.The abundance of S 1 species with DBE=1-8 decreased with increasing thermal maturity,while the abundance of S 1 species with DBE=9 (primarily DBTs) increased.Therefore,thermal maturity is an important factor in the formation of oils with high DBT concentrations.Unusually high abundances of S 1 species with low DBE values (1-8),which include sulfide,thiophene and benzothiophene,were observed in several oils,especially the TZ83 (O 1) oil with high or very high thermal maturity.Thermochemical sulfate reduction (TSR) was thought to be the reason for the high abundance of these low DBE compounds in deep reservoirs,and thermochemical sulfate reduction could affect the distribution and composition of DBTs in the oils.According to the results of FT-ICR MS analysis,there are no signs that TSR is occurring or has occurred recently for most of the Lower Ordovician oils.Li Sumei Pang Xiongqi Shi Quan Zhang Baoshou Zhang Haizu Pan Na Zhao Ming 2011Petroleum Science2011,8,4:9
3Comprehensive diag”nostic review of the (13)~C-enriched crude oils exemplified by TD2∈ and TZ62S in Tarim Basin, NW China显示文摘The crude oils typically from the CambrianLower Ordovician source rocks of Tarim Basin, NW'China, such as TD2 and TZ62S, are13C-enriched with the stable carbon isotopic ratios(VPDB) approaching-28 %.In this paper, the main research viewpoints on this issue are summarized, and combined with results from organic and inorganic carbon isotope stratum curves of the outcrop at the Ya'erdang Mountain in Tarim Basin. In addition, more alternative interpretations are discussed. On one hand, the inverse fractionation features of stable carbon and hydrogen isotopes of these crude oils may imply their protogenous nature. On the other hand, the anisotropy of source rocks and contribution from older stratum source rocks need verifying as well. For the sake of the final resolution of this issue, some further study topics are recommended.Hu Liu Zewen Liao Haizu Zhang Yankuan Tian Bin Cheng Xiaohong Chang 2015Chinese Journal Of Geochemistry2015,34,1:3
4Kinetic study of the hydrocarbon generation from marine carbonate source rocks characterization of products of gas and liquid hydrocarbon显示文摘The kinetic parameters of hydrocarbon generation from the marine carbonate source rocks were determined and calibrated through kinetic simulating experiment. The kinetic parameters of hydrocarbon generation then were extrapolated to geological condition by using the relative software. The result shows that gaseous hydrocarbons (C_1, C_2, C_3, C_(4-5)) were generated in condition of 150℃GENG Xinhua GENG Ansong XIONG Yongqiang LIU Jinzhong ZHANG Haizu ZHAO Qingfang 2006Chinese Science Bulletin2006,51,23:3
5Synthesis and performance of Li 3 (V 1? x Mg x ) 2 (PO 4 ) 3 cathode materials显示文摘Changsong Dai Zhenyu Chen Haizu Jin Xinguo Hu 2010Journal of Power Sources2010,,17:1
6Differential Thermal Regimes of the Tarim and Sichuan Basins in China:Implications for Hydrocarbon Generation and Conservation显示文摘The uncertainty surrounding the thermal regimes of the ultra-deep strata in the Tarim and Sichuan basins,China,is unfavorable for further hydrocarbon exploration.This study summarizes and contrasts the present-day and paleo heat flow,geothermal gradient and deep formation temperatures of the Tarim and Sichuan basins.The average heat flow of the Tarim and Sichuan basins are 42.5±7.6 mW/m^(2)and 53.8±7.6 mW/m^(2),respectively,reflecting the characteristics of’cold’and’warm’basins.The geothermal gradient with unified depths of 0-5,000 m,0-6,000 m and 0-7,000 m in the Tarim Basin are 21.6±2.9℃/km,20.5±2.8℃/km and 19.6±2.8℃/km,respectively,while the geothermal gradient with unified depths of 0-5,000 m,0-6,000 m and 0-7,000 m in the Sichuan Basin are 21.9±2.3℃/km,22.1±2.5℃/km and23.3±2.4℃/km respectively.The differential change of the geothermal gradient between the Tarim and Sichuan basins with depth probably results from the rock thermal conductivity and heat production rate.The formation temperatures at depths of 6,000 m,7,000 m,8,000 m,9,000 m and 10,000 m in the Tarim Basin are 80℃-190℃,90℃-220℃,100℃-230℃,110℃-240℃and 120℃-250℃,respectively,while the formation temperatures at depths of 6,000 m,7,000 m,8,000 m and 9,000 m in the Sichuan Basin are 120℃-200℃,140℃-210℃,160℃-260℃and 180℃-280℃,respectively.The horizontal distribution pattern of the ultra-deep formation temperatures in the Tarim and Sichuan basins is mainly affected by the basement relief,fault activity and hydrothermal upwelling.The thermal modeling revealed that the paleo-heat flow in the interior of the Tarim Basin decreased since the early Cambrian with an early Permian abrupt peak,while that in the Sichuan Basin experienced three stages of steady state from Cambrian to early Permian,rapidly rising at the end of the early Permian and declining since the late Permian.The thermal regime of the Sichuan Basin was always higher than that of the Tarim Basin,which results in differential oil and gas generation and conservation in the ultra-deep ancient strata.This study not only promotes theoretical development in the exploration of ultra-deep geothermal fields,but also plays an important role in determining the maturation phase of the ultra-deep source rocks and the occurrence state of hydrocarbons in the Tarim and Sichuan basins.CHANG Jian LI Dan QIU Nansheng ZHU Chuanqing ZHONG Ningning FENG Qianqian ZHANG Haizu WANG Xiang 2022Acta Geologica Sinica(English Edition)2022,96,4:1
7Origin of the unusually high dibenzothiophene oils in Tazhong-4 Oilfield of Tarim Basin and its implication in deep petroleum exploration显示文摘Sumei Li Quan Shi Xiongqi Pang Baoshou Zhang Haizu Zhang 2012Organic Geochemistry2012,,:1
8Stable isotope(δ^(13)C_(ker),δ^(13)C_(carb),δ^(18)O_(carb)) distribution along a Cambrian outcrop section in the eastern Tarim Basin,NW China and its geochemical significance显示文摘This study investigated the geochemical features of the lower Paleozoic strata of Yaerdang Mountain outcrop along with the core samples from well TD2∈ in the eastern Tarim Basin,NW China.The total organic carbon abundance,hydrocarbon-generating precursor biospecies,and stable isotope ratios of organics and carbonate(δ^(13)C_(ker),δ^(13)C_(carb) and δ^(18)O_(carb)) were comprehensively studied for their possible correlative constraints during sedimentary evolution.The results revealed that the δ^(13)C_(ker)(VPDB) of Cambrian kerogens along the outcrop section varied from-34.6‰ to-28.4‰,indicating an increasing tendency from the lower Cambrian to the upper Cambrian.This was on the whole accompanied by the variation in the δ^(13)C_(carb) and δ^(18)O_(carb) along the profile,which might be associated with the changes in the sea level and also in the compositional variation of benthic and planktonic biomass.The large variation in the stable carbon isotope ratios up to 6‰ along the outcrop section reflected the heterogeneity of the Cambrian source rocks from the eastern Tarim Basin.Hence,the ^(13)C-enriched crude oils from well TD2∈might have been derived from a localized stratum of Cambrian source rocks.The results from this study showed the possibility of multiple source kitchens in the Cambrian-lower Ordovician portion of Tarim Basin.Hu Liu Zewen Liao Haizu Zhang Yankuan Tian Bin Cheng Shan Yang 2017Geoscience Frontiers2017,8,1:1
9Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H202/CH3COOH显示文摘Zhao Jing Liao Zewen Zhang Lfihui Creux R Yang Chupeng Chrostowska A Zhang Haizu Graciaa A 2010Appl Geochem2010,25,9:1
10Multiple-sourced features of marine oilsin the Tarim Basin, NW China - Geochemical evidencefrom occluded hydrocarbons inside asphaltenes 显示文摘Tian Yankuan Zhao Jing Yang Chupeng Liao Zewen ZhangLühui Zhang Haizu 2012J AsianEarth Sci2012,5455,17:1
11Geochemical quantification of mixed marine oils fromTazhong Area of Tarim Basin, NW China 显示文摘Tian Yankuan Yang Chupeng Liao Zewen Zhang Haizu 2012J Pet Sci Eng2012,9091,96:1
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