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2篇 您的检索式:作者名="Hashemnejad"
    题名 作者 年代 出处 被引量
1用于甲烷水蒸气重整的镍基催化剂的失活和再生(英文)显示文摘The deactivation of nickel catalysts used in Arak and Razi petrochemical complexes followed by catalyst regeneration was evalu-ated. The characterization of the different structures was made by powder X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive X-ray spectroscopy(EDS),transmission electron microscopy(TEM),and carbon & sulfur analyzer. The Ni particle size was estimated from XRD patterns and TEM graphs. The agglomeration of nickel particle and the poison by sulfur components were recognized as the main reasons in deactivation of Arak and Razi catalysts,respectively. The activity of the used catalysts before and after regeneration was measured on methane steam reforming at a CH4:H2O ratio of 1:3 at 850 oC. The regeneration processes for Arak and Razi samples were performed with CO2 as an oxidative atmosphere and steam as a regenerating agent,respectively. The results show that,(1) no residual sulfur components were on the regenerated Razi catalyst surface without changing the structure of the catalyst and the regenerated catalyst has gained 80% of its catalytic activity,and that(2) the nickel particle size of regenerated Arak specimen decreased remarkably as measured by Debye-Scherrer equation from XRD patterns. TEM images were in agreement with the XRD results and indicated a decrease in nickel particle size of regenerated catalyst. Additionally,in both regenerated catalysts all the coke on the surface of the support was eliminated after regeneration.Seyed Meysam HASHEMNEJAD Matin PARVARI 2011催化学报2011,32,2:5
2Methane reforming to syngas over LaNi x Fe 1? x O 3 (0<ce:hsp sp='0.25'/>≤<ce:hsp sp='0.25'/> x <ce:hsp sp='0.25'/>≤<ce:hsp sp='0.25'/>1) mixed-oxide perovskites in the presence of CO 2 and O 2显示文摘Hamidreza Arandiyan Junhua Li Lei Ma S.M. Hashemnejad M.Z. Mirzaei Jinghuan Chen Huazhen Chang Caixia Liu Chizhong Wang Liang Chen 2012Journal of Industrial and Engineering Chemistry2012,,6:1
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