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您的检索式：作者名="Huoliang Gu"
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| 1 | Recent advances in the rational design of single-atom catalysts for electrochemical CO_(2) reduction显示文摘Electrochemical CO_(2) reduction(CO_(2)R)represents a sustainable way to store intermittent renewable energies and produce carbon-neutral fuels,yet the energy efficiency remains a huge bottleneck owning to its sluggish kinetics and complex reaction pathways.Highly active,selective,and robust electrocatalysts are strongly demanded to accelerate CO_(2) conversion and deploy this technology to practical applications.In this review,we focus on single-atom catalysts(SACs),a unique category of electrocatalysts with atomically dispersed metal active sites,which have shown distinctive performances in CO_(2)R and offer an ideal platform for in-depth mechanistic studies at the atomic level.Despite various SACs with attractive CO_(2)R performances have been reported,the relationship between electronic/geometric structure of SACs and the corresponding electrocatalytic performance still needs to be discussed with caution.Here we take a broad overview on the recent progress in understanding the structure–function correlation of SACs in CO_(2)R,with the purpose of providing deep insights and guiding the future rational design of SACs.First,we provide the fundamental understandings of CO_(2)R on SACs,following different reaction pathways.Then,we describe the progresses in the development of well-defined SACs and the mechanistic studies on the influences from particular structural parameters,such as first-shell and second-sphere coordination,conductive supports and interface with a secondary catalyst.Finally,some perspectives are highlighted on the path towards efficient CO_(2)R on SACs. | Huoliang Gu Jing Wu Liming Zhang | 2022 | Nano Research2022，15，11： | 0 |
| 2 | Enhanced electrochemical CO_(2)-to-C_(2+) conversion from synergistic interaction between terrace and step sites on monocrystalline highindex Cu facets显示文摘1. Introduction The increasing global demand for sustainable energy sources and emerging environmental issues have pushed the development of energy conversion and storage technologies to the forefront of chemical research [1,2]. In particular, electrochemical CO_(2) reduction(CO_(2) R) to value-added fuels and chemicals presents a feasible pathway for renewable energy storage and could help mitigate the ever-increasing CO_(2) emissions [3]. | Chenyuan Zhu Zhibin Zhang Lixiang Zhong Siwen Zhao Guoshuai Shi Bowen Wu Huoliang Gu Jing Wu Xinyang Gao Kaihui Liu Liming Zhang | 2022 | Journal of Energy Chemistry2022，31，7： | 0 |
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