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| 1 | Biohydrogen-production from beer lees biomass by cow dung compost显示文摘 | Fan Yaoting Zhang Gaosheng Gao Xinyang | 2006 | Biomass and Bioenergy2006，30，： | 1 |
| 2 | Quasi-Solid-State Ion-Conducting Arrays Composite Electrolytes with Fast Ion Transport Vertical-Aligned Interfaces for All-Weather Practical Lithium-Metal Batteries显示文摘The rapid improvement in the gel polymer electrolytes(GPEs)with high ionic conductivity brought it closer to practical applications in solid-state Li-metal batteries.The combination of solvent and polymer enables quasi-liquid fast ion transport in the GPEs.However,different ion transport capacity between solvent and polymer will cause local nonuniform Li+distribution,leading to severe dendrite growth.In addition,the poor thermal stability of the solvent also limits the operating-temperature window of the electrolytes.Optimizing the ion transport environment and enhancing the thermal stability are two major challenges that hinder the application of GPEs.Here,a strategy by introducing ion-conducting arrays(ICA)is created by vertical-aligned montmorillonite into GPE.Rapid ion transport on the ICA was demonstrated by 6Li solid-state nuclear magnetic resonance and synchrotron X-ray diffraction,combined with computer simulations to visualize the transport process.Compared with conventional randomly dispersed fillers,ICA provides continuous interfaces to regulate the ion transport environment and enhances the tolerance of GPEs to extreme temperatures.Therefore,GPE/ICA exhibits high room-temperature ionic conductivity(1.08 mS cm^(−1))and long-term stable Li deposition/stripping cycles(>1000 h).As a final proof,Li||GPE/ICA||LiFePO_(4) cells exhibit excellent cycle performance at wide temperature range(from 0 to 60°C),which shows a promising path toward all-weather practical solid-state batteries. | Xinyang Li Yong Wang Kai Xi Wei Yu Jie Feng Guoxin Gao Hu Wu Qiu Jiang Amr Abdelkader Weibo Hua Guiming Zhong Shujiang Ding | 2022 | Nano-Micro Letters2022，14，12： | 1 |
| 3 | Differential transcriptomic landscapes of multiple organs from SARS-CoV-2 early infected rhesus macaques显示文摘SARS-CoV-2 infection causes complicated clinical manifestations with variable multi-organ injuries,how-ever,the underlying mechanism,in particular immune responses in different organs,remains elusive.In this study,comprehensive transcriptomic alterations of 14 tissues from rhesus macaque infected with SARS-CoV-2 were analyzed.Compared to normal controls,SARS-CoV-2 infection resulted in dysregulation of genes involving diverse functions in various examined tissues/organs,with drastic transcriptomic changes in cerebral cortex and right ventricle.Intriguingly,cerebral cortex exhibited a hyperinflammatory state evidenced by sig-nificant upregulation of inflammation response-related genes.Meanwhile,expressions of coagulation,angio-genesis and fibrosis factors were also up-regulated in cerebral cortex.Based on our findings,neuropilin 1(NRP1),a receptor of SARS-CoV-2,was significantly elevated in cerebral cortex post infection,accompanied by active immune response releasing inflammatory factors and signal transmission among tissues,which enhanced infection of the central nervous system(CNS)in a positive feedback way,leading to viral encephalitis.Overall,our study depicts a multi-tissue/organ tran-scriptomic landscapes of rhesus macaque with early infection of SARS-CoV-2,and provides important insights into the mechanistic basis for COVID-19-asso-ciated clinical complications. | Chun-Chun Gao Man Li Wei Deng Chun-Hui Ma Yu-Sheng Chen Yong-Qiao Sun Tingfu Du Qian-Lan Liu Wen-Jie Li Bing Zhang Lihong Sun Si-Meng Liu Fengli Li Feifei Qi Yajin Qu Xinyang Ge Jiangning Liu Peng Wang Yamei Niu Zhiyong Liang Yong-Liang Zhao Bo Huang Xiao-Zhong Peng Ying Yang Chuan Qin Wei-Min Tong Yun-Gui Yang | 2022 | Protein & Cell2022，13，12： | 1 |
| 4 | In-situ polymerized carbonate induced by Li-Ga alloy as novel artificial interphase on Li metal anode显示文摘Li metal is considered an ideal anode material because of its high theoretical capacity and low electrode potential.However,the practical usage of Li metal as an anode is severely limited because of inevitable parasitic side reactions with electrolyte and dendrites formation.At present,single-component artificial solid electrolyte interphase cannot simultaneously meet the multiple functions of promoting ion conduction,guiding lithium ion deposition,inhibiting dendrite growth,and reducing interface side reactions.Therefore,multi-component design on Li metal surface is widely investigated to achieve long-term cycling.Herein,we report a Li_(2)Ga-carbonate polymer interphase layer to solve volume changes,Li dendrites formation and side-reactions.As a result,the Li symmetric cell can be stabilized at 3.0 m A/cm^(2)in carbonate electrolyte with limited volume of 20μL.Coupled with 13.6 mg/cm^(2)(loading of 2 mAh/cm^(2))LiFePO_(4)cathode,discharge capacity retains at 90%for over 150 cycles under limited electrolyte conditions.With such an alloy-polymer interphase layer,higher energy density Li metal batteries become prominent in the near future. | Ziping Wang Shuyuan Xie Xuejie Gao Xinyang Chen Lina Cong Jun Liu Haiming Xie Chuang Yu Yulong Liu | 2023 | Chinese Chemical Letters2023，34，9： | 0 |
| 5 | Dual-single-atoms of Pt-Co boost sulfur redox kinetics for ultrafast Li-S batteries显示文摘Applications of lithium-sulfur(Li-S)batteries are still limited by the sluggish conversion kinetics from polysulfide to Li_(2)S.Although various single-atom catalysts are available for improving the conversion kinetics,the sulfur redox kinetics for Li-S batteries is still not ultrafast.Herein,in this work,a catalyst with dual-single-atom Pt-Co embedded in N-doped carbon nanotubes(Pt&Co@NCNT)was proposed by the atomic layer deposition method to suppress the shuttle effect and synergistically improve the interconversion kinetics from polysulfides to Li_(2)S.The X-ray absorption near edge curves indicated the reversible conversion of Li_(2)Sx on the S/Pt&Co@NCNT electrode.Meanwhile,density functional theory demonstrated that the Pt&Co@NCNT promoted the free energy of the phase transition of sulfur species and reduced the oxidative decomposition energy of Li_(2)S.As a result,the batteries assembled with S/Pt&Co@NCNT electrodes exhibited a high capacity retention of 80%at 100 cycles at a current density of 1.3 mA cm^(−2)(S loading:2.5 mg cm^(−2)).More importantly,an excellent rate performance was achieved with a high capacity of 822.1 mAh g^(−1) at a high current density of 12.7 mA cm^(−2).This work opens a new direction to boost the sulfur redox kinetics for ultrafast Li-S batteries. | Hanyan Wu Xuejie Gao Xinyang Chen Weihan Li Junjie Li Lei Zhang Yang Zhao Ming Jiang Runcang Sun Xueliang Sun | 2024 | Carbon Energy2024，6，3： | 0 |
| 6 | Enhanced electrochemical CO_(2)-to-C_(2+) conversion from synergistic interaction between terrace and step sites on monocrystalline highindex Cu facets显示文摘1. Introduction The increasing global demand for sustainable energy sources and emerging environmental issues have pushed the development of energy conversion and storage technologies to the forefront of chemical research [1,2]. In particular, electrochemical CO_(2) reduction(CO_(2) R) to value-added fuels and chemicals presents a feasible pathway for renewable energy storage and could help mitigate the ever-increasing CO_(2) emissions [3]. | Chenyuan Zhu Zhibin Zhang Lixiang Zhong Siwen Zhao Guoshuai Shi Bowen Wu Huoliang Gu Jing Wu Xinyang Gao Kaihui Liu Liming Zhang | 2022 | Journal of Energy Chemistry2022，31，7： | 0 |
| 7 | Surface modification of hollow capsule by Dawson-type polyoxometalate as sulfur hosts for ultralong-life lithium-sulfur batteries显示文摘Reasonable construction of sulfur host with high conductivity,large sulfur storage gap,strong chemical adsorption,and fast oxidation–reduction kinetics of polysulfide is very significant for its practical use in lithium-sulfur batteries(LSBs).In this paper,the surface modification of MIL-88A(Fe)is carried out by Dawson-type polyoxometalate(POM),and a hollow capsule shell material with P_(2)W_(18),Fe_(3)O_(4),and C components is synthesized by the subsequent carbonization process.When applied as the sulfur host,the hollow capsule shell material can efficiently improve the conductivity of sulfur electrode and restrain the volumetric change of active sulfur while charging and discharging.On this foundation,electrochemical analysis and density functional theory(DFT)calculation show that the P_(2)W_(18)on the outer layer of the capsule shell have effective electrocatalytic activity and potent chemical bond on the lithium polysulfides(LiPSs),which is helpful to block the shuttle effect.Therefore,the as-assembled LSBs display the outstanding specific capacity and prominent cycle stability.Specifically,it delivers an excellent reversible capacity of 1063 mAh/g after 100 cycles of charge–discharge at a rate of 0.5 C,accounting for a preservation by 96%in comparison to that of the initial cycle.Moreover,even after 2000 cycles at 1 C,the reversible specific capacity of 585 mAh/g can still be maintained with an average decay rate of only 0.021%. | Mingliang Wang Di Yin Yundong Cao Xinyang Dong Guanggang Gao Xun Hu Cheng Jin Linlin Fan Jian Yu Hong Liu | 2022 | Chinese Chemical Letters2022，33，9： | 0 |
| 8 | Deep eutectic solvent-based gel electrolytes for flexible electrochromic devices with excellent high/low temperature durability显示文摘With the increasing interest in the application of electrochromism to flexible and wearable electronics in recent years,flexible electrochromic devices(ECDs)that can function at extreme temperatures are required.However,the functionalities of flexible ECDs are severely hampered by the inadequate choice of electrolytes,which might ultimately result in performance fading during low-and high-temperature operations.Here,we develop a deep eutectic solvent(DES)-based gel electrolyte that can maintain its optical,electrical,and mechanical properties over a wide range of temperatures(-40 to 150℃),exhibiting an extremely high visible-range transmittance over 90%,ion conductivity of 0.63 mS cm^(-1),and fracture strain exceeding 2000%.Owing to the excellent processability of the DES-based electrolytes,provided by dynamic interactions such as the lithium and hydrogen bonding between the DES and polymer matrix,a directly written patterning in ECDs is realized for the first time.The fabricated ECDs exhibit an excellent electrochromic behavior superior to the behavior of the ECDs fabricated with traditional gel electrolytes.The introduction of such DES-based electrolytes is expected to pave the way for a widespread application of electrochromic products. | Peiyan Sun Jian Chen Yaowu Li Xueqing Tang Hongzhao Sun Ge Song Xinyang Mu Taoyang Zhang Xiuling Zha Feifan Li Yanfeng Gao Shan Cong Zhigang Zhao | 2023 | InfoMat2023，5，2： | 0 |
| 9 | A Cobalt(Ⅲ)Corrole with a Tethered Imidazole for Boosted Electrocatalytic Oxygen Reduction Reaction显示文摘Developing electrocatalysts with high activity and selectivity for the oxygen reduction reaction(ORR)is vital to promote the performance of the next-generation energy technologies,which depend on the efficiency of the catalytic reduction of dioxygen.In the structure of cytochrome c oxidases(CcOs),a histidine imidazole residue binding to the axial position of Fe plays a crucial role in facilitating the selective reduction of O_(2)to water.Inspired by nature,we herein report on the synthesis of CoIII corrole 1 tethered with an imidazole ligand as well as its electrocatalytic ORR and O_(2)binding features.As compared to the imidazolium-free analogue,complex 1 displayed remarkably boosted activity for the selective four-electron/four-proton(4e-/4H+)ORR with a half-wave potential of E1/2=0.82 V versus reversible hydrogen electrode(RHE)in 0.1 mol/L KOH solutions.Importantly,we demonstrate that the tethered axial imidazole ligand improves the O_(2)binding ability of 1 thermodynamically and dynamically,which is crucial to boost electrocatalytic ORR performance.This work presents an example to improve electrocatalytic ORR activity and selectivity of Co corroles by introducing an axial imidazole ligand to enhance the O_(2)binding and activation. | Yimei Gao Benxing Mei Yizhen Wu Qian Zhao Zijia Bao Haonan Qin Yuhan Xu Haoyuan Lv Xinyang Peng Yan He Ting Luo Ran Yao Wei Zhang Haitao Lei Rui Cao | 2023 | Chinese Journal of Chemistry2023，41，21： | 0 |
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