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| 1 | Interface issues of lithium metal anode for high-energy batteries: Challenges, strategies, and perspectives显示文摘Lithium(Li)metal is considered as one of the most promising anode materials for next-generation high-energy-density storage systems.However,the practical application of Li metal anode is hindered by interfacial instability and air instability due to the highly reactivity of Li metal.Unstable interface in Li metal batteries(LMBs)directly dictates Li dendrite growth,“dead Li”and low Coulombic efficiency,resulting in inferior electrochemical performance of LMBs and even safety issues.In addition,its sensitivity to ambient air leads to the severe corrosion of Li metal anode,high requirements of production and storage,and increased manufacturing cost.Plenty of efforts in recent years have overcome many bottlenecks in these fields and hastened the practical applications of high-energy-density LMBs.In this review,we focus on emerging methods of these two aspects to fulfill a stable and low cost electrode.In this perspective,design artificial solid electrolyte interphase(SEI)layers,construct three-dimensional conductive current collectors,optimize electrolytes,employ solid-state electrolytes,and modify separators are summarized to be propitious to ameliorate interfacial stability.Meanwhile,ex situ/in situ formed protective layers are highlighted in favor of heightening air stability.Finally,several possible directions for the future research on advanced Li metal anode are addressed. | Yiyao Han Bo Liu Zhen Xiao Wenkui Zhang Xiuli Wang Guoxiang Pan Yang Xia Xinhui Xia Jiangping Tu | 2021 | InfoMat2021，3，2： | 11 |
| 2 | Revisiting Scientific Issues for Industrial Applications of Lithium–Sulfur Batteries显示文摘Inspired by high theoretical energy density(-2600 W h kg^(-1))and cost-effectiveness of sulfur cathode,lithium–sulfur batteries are receiving great attention and considered as one of the most promising next-generation high-energy-density batteries.However,over the past decades,the energy density and reliable safety levels as well as the commercial progress of lithium-sulfur batteries are still far from satisfactory due to the disconnection and huge gap between fundamental research and practical application. | Bo Liu Ruyi Fang Dong Xie Wenkui Zhang Hui Huang Yang Xia Xiuli Wang Xinhui Xia Jiangping Tu | 2018 | Energy & Environmental Materials2018，1，4： | 9 |
| 3 | High-energy cathode materials for Li-ion batteries: A review of recent developments显示文摘Lithium ion batteries(LIBs) represent one of the most promising solutions for environmentally friendly transportation such as electric vehicles. The demand for high energy density, low cost and environmentally friendly batteries makes high-capacity cathode materials very attractive for future LIBs. Layered Li NixCoyMnzO2(x+y+z=1), Li-rich oxides and Li-V-O compounds have attracted much attention due to their high capacities in recent years. In this review, we focus on the state-of-the-art research activities related to Li NixCoyMnzO2, Li-rich oxides and Li-V-O compounds, including their structures, reaction mechanisms during cycling, challenges and strategies that have been studied to improve their electrochemical performances. | ZHANG YiDi LI Yi XIA XinHui WANG XiuLi GU ChangDong TU JiangPing | 2015 | Science China(Technological Sciences)2015，58，11： | 7 |
| 4 | All-solid-state electrochromic devices based on WO3‖NiO films:material developments and future applications显示文摘Electrochromism refers to the persistent and reversible change of optical properties by an applied voltage pulse.Electrochromic(EC)devices have been extensively studied because of their commercial applications in smart windows of green buildings,display devices and thermal control of equipments.In this review,a basic EC device design is presented based on useful oxides and solid-state electrolytes.We focus on the state-of-the-art research activities related to the structures of tungsten oxide(WO_3)and nickel oxide(NiO),summarizing the strategies to improve their EC performances and further applications of devices. | Ding Zhou Dong Xie Xinhui Xia Xiuli Wang Changdong Gu Jiangping Tu | 2017 | Science China Chemistry2017，60，1： | 7 |
| 5 | Facile fabrication of integrated three-dimensional C- MoSe2/reduced graphene oxide composite with enhanced performance for sodium storage显示文摘先进电极材料的谨慎小心的设计和制造为开发高效的钠离子电池是重要的。此处,我们报导一出灵巧的一步舞为与高孔和大表面区域合成的 C-MoSe 2/rGO 的建设的热水的策略。MoSe 2 nanosheets 的两倍修正在这被认识到由介绍减少的 graphene 氧化物(rGO ) 合成骨骼和外部碳保护的层。MoSe 2 nanosheets 被碳层很好包并且强烈也在互连的 rGO 网络上抛锚了。作为在钠离子电池的阳极,设计 C-MoSe 2/rGO 合成交付显著地提高的钠离子存储,与 445 mAh 潨灳瑩的一个高特定的能力? | Dong Xie Wangjia Tang Yadong Wang Xinhui Xia Yu Zhong Ding Zhou DonghuangWang Xiuli Wang Jiangping Tu | 2016 | Nano Research2016，9，6： | 7 |
| 6 | Hydrothermal synthesized porous Co(OH)_2 nanoflake film for supercapacitor application显示文摘Porous Co(OH)2 film directly grown on nickel foam is prepared by a facile hydrothermal method.The as-prepared Co(OH)2 film possesses a structure consisting of randomly porous nanoflakes with thicknesses of 20-30 nm.The capacitive behavior of the Co(OH)2 film is investigated by cyclic voltammograms and galvanostatic charge-discharge tests in 2 mol/L KOH.The porous Co(OH)2 film exhibits a high discharge capacitance of 935 F g-1 at a current density of 2 A g-1 and excellent rate capability.The specific capacitance keeps a capacitance of 589 F g-1 when the current density increases to 40 A g-1.The specific capacitance of 82.6% is maintained after 1500 cycles at 2 A g-1. | ZHANG YongQi XIA XinHui KANG Jing TU JiangPing | 2012 | Chinese Science Bulletin2012，57，32： | 6 |
| 7 | Effect of rapid quenching on the microstructure and electrochemical characteristics of La_(0.6)Ce_(0.4)Ni_(3.6)Co_(0.65)Mn_(0.4)Al_(0.2)Ti_(0.05_(FeB)_(0.1) hydrogen storage alloy显示文摘In order to improve the cycling stability of AB5 type alloy electrodes,rapid quenching technology and new alloy composition design were employed.A hydrogen storage alloy with nominal composition La0.6Ce0.4Ni3.6Co0.65Mn0.4Al0.2Ti0.05(FeB)0.1 was prepared by vacuum magnetic levitation melting under high purity argon atmosphere,followed by rapid quenching at different cooling rates.XRD results show that all alloys exhibit the single-phase CaCu5-type structure.Electrochemical tests indicate that rapid quenching can slightly improve the cycling life of the alloy.Nevertheless,the high-rate dischargeability of the quenched alloys is lower than that of the as-cast alloy. | ZHANG Peilong SONG Xiping WANG Xiuli PEI Pei LUO Guiping TU Jiangping CHEN Guoliang | 2010 | Rare Metals2010，29，6： | 4 |
| 8 | Integrated carbon nanospheres arrays as anode materials for boosted sodium ion storage显示文摘Developing cost-effective advanced carbon anode is critical for innovation of sodium ion batteries. Herein, we develop a powerful combined method for rational synthesis of free-standing binder-free carbon nanospheres arrays via chemical bath plus hydrothermal process. Impressively,carbon spheres with diameters of 150-250 nm are randomly interconnected with each other forming highly porous arrays. Positive advantages including large porosity, high surface and strong mechanical stability are combined in the carbon nanospheres arrays. The obtained carbon nanospheres arrays are tested as anode material for sodium ion batteries(SIBs) and deliver a high reversible capacity of 102 mAh g^(-1) and keep a capacity retention of 95% after 100 cycles at a current density of 0.25 A g^(-1) and good rate performance(65 mAh g^(-1) at a high current density of 2 A g^(-1)). The good electrochemical performance is attributed to the stable porous nanosphere structure with fast ion/electron transfer characteristics. | Wangjia Tang Jianbo Wu Xiuli Wang Xinhui Xia Jiangping Tu | 2018 | Green Energy & Environment2018，3，1： | 3 |
| 9 | Directional construction of Cu2S branch arrays for advanced oxygen evolution reaction显示文摘Metal sulphide electrocatalyst is considered as one of the most promising low-cost candidates for oxygen evolution reaction(OER).In this work,we report a novel free-standing Cu2S branch array via a facile TiO2-induced electrodeposition-sulfurization method.Interestingly,cross-linked Cu2S nanoflake branch is strongly anchored on the TiO2 backbone forming high-quality Cu2S/TiO2/Cu2S core-branch arrays.The branch formation mechanism is also proposed.As compared to the pure Cu2S nanowire arrays,the asprepared Cu2S/TiO2/Cu2S core-branch arrays show much better alkaline OER performance with lower overpotential(284 mV at 10 mA cm^-2)and smaller Tafel slope(72 dec-1)as well as enhanced longterm durability mainly due to larger exposed area and more active electrocatalytic sites.Our work provides a new way for construction of advanced metal sulphide electrocatalysts for electrochemical energy conversion. | Shengjue Deng Yanbin Shen Dong Xie Yangfan Lu Xiaolong Yu Liang Yang Xiuli Wang Xinhui Xia Jiangping Tu | 2019 | Journal of Energy Chemistry2019，28，12： | 3 |
| 10 | High?Index?Faceted Ni_3S_2 Branch Arrays as Bifunctional Electrocatalysts for Efficient Water Splitting显示文摘For efficient electrolysis of water for hydrogen generation or other valueadded chemicals, it is highly relevant to develop low-temperature synthesis of low-cost and high-e ciency metal sulfide electrocatalysts on a large scale. Herein, we construct a new core–branch array and binder-free electrode by growing Ni_3S_2 nanoflake branches on an atomic-layer-deposited(ALD) TiO_2 skeleton. Through induced growth on the ALD-TiO_2 backbone, cross-linked Ni_3S_2 nanoflake branches with exposed { 210} highindex facets are uniformly anchored to the preformed TiO_2 core forming an integrated electrocatalyst. Such a core–branch array structure possesses large active surface area, uniform porous structure, and rich active sites of the exposed { 210 } high-index facet in the Ni_3S_2 nanoflake. Accordingly, the TiO_2@Ni_3S_2 core/branch arrays exhibit remarkable electrocatalytic activities in an alkaline medium, with lower overpotentials for both oxygen evolution reaction(220 mV at 10 mA cm^(-2)) and hydrogen evolution reaction(112 m V at 10 mA cm^(-2)), which are better than those of other Ni_3S_2 counterparts. Stable overall water splitting based on this bifunctional electrolyzer is also demonstrated. | Shengjue Deng Kaili Zhang Dong Xie Yan Zhang Yongqi Zhang Yadong Wang Jianbo Wu Xiuli Wang Hong Jin Fan Xinhui Xia Jiangping Tu | 2019 | Nano-Micro Letters2019，11，1： | 2 |
| 11 | TiC/C core/shell nanowires arrays as advanced anode of sodium ion batteries显示文摘High-perfo rmance anodes of sodium ion batteries(SIBs)largely depends on rational architecture design and binder-free smart hybridization.Herein,we report TiC/C core/shell nanowires arrays prepared by a one-step chemical vapor deposition(CVD)method and apply it as the anode of SIBs for the first time.The conductive TiC core is intimately decorated with carbon shell.The as-obtained TiC/C nanowires are homogeneously grown on the substrate and show core/shell heterostructure and porous architecture with high electronic conductivity and reinforced stability.Owing to these merits,the TiC/C electrode displays good rate performance and outstanding cycling performance with a capacity of 135.3 mAh/g at 0.1 A/g and superior capacity retention of 90.14%after 1000 cycles at 2 A/g.The reported strategy would provide a promising way to construct binder-free arrays electrodes for sodium ion storage. | Yanbin Shen Yahao Li Shengjue Deng Guoxiang Pan Qinqin Xiong Xiaokun Ding Yangfan Lu Qi Liu Xinhui Xia Xiuli Wang Jiangping Tu | 2020 | Chinese Chemical Letters2020，31，3： | 2 |
| 12 | N-doped CoO nanowire arrays as efficient electrocatalysts for oxygen evolution reaction显示文摘Rational design of cost-effective high-performance electrocatalysts for oxygen evolution reaction (OER) is of great significance for electrochemical water splitting. Herein, we adopt a nitrogen doping method to fabricate self-supported N-doped CoO nanowire arrays (N-CoO) as active electrocatalysts via a facile hydrothermal combined doping method. The N-CoO nanowires are strongly composited with the carbon cloth substrate forming free-standing electrode with reinforced stability and high electronic conductivity. Owing to the increased accessible and electroactive areas, rich/short pathways for charge transfer and enhanced electronic conductivity, the N-CoO electrode exhibits excellent electrocatalytic performance for OER with a low overpotential (319 mV at 10 mA cm^-2 and 410 mV at 100 mA cm^-2) and a low Tafel slope of 74 mV dec^-1 as well as superior long-term stability with no decay in 24 h continuous test in alkaline solution. Our reported design and optimization strategy provide a promising way to construct interesting well-aligned arrays for application in energy storage and conversion. | Kaili Zhang Xinhui Xia Shengjue Deng Dong Xie Yangfan Lu Yadong Wang Jianbo Wu Xiuli Wang Jiangping Tu | 2019 | Journal of Energy Chemistry2019，28，10： | 2 |
| 13 | Doping Effects on Electronic Conductivity and Electrochemical Performance of LiFePO_4显示文摘Olivine-structured pure LiFePO4 and doped Li(M, Fe)PO4 (M=La, Ce, Nd, Mn, Co, Ni) have been synthesized by a solvothermal method. X-ray diffraction and field emission scanning electron microscopy analyses indicate that the as-prepared LiFePO4 is well-crystallized nanopowders without any detectable impurity phases. The electronic conductivity of LiFePO4 is enhanced by around 1-3 orders by doping. It was found that doping alone is not suffcient for the high-rate performance of LiFePO4 and surface coating with such as carbon should be needed. The best dopant for LiFePO4 is Nd among those studied in the present work. Accordingly, doping with 1 mol fraction Nd leads to an increase in 70 mAh/g at 0.1 C for the hydrothermally synthesized sample and 50 mAh/g at 1.0 C after carbon-coating in comparison with the undoped samples. | Jiezi Hu Jian Xie Xinbing Zhao Hongming Yu Xin Zhou Gaoshao Cao Jiangping Tu | 2009 | Journal of Materials Science & Technology2009，25，3： | 2 |
| 14 | Correction to:High‑Index‑Faceted Ni3S2 Branch Arrays as Bifunctional Electrocatalysts for Efficient Water Splitting显示文摘In the original publication,Figure S4 is an ancillary image to compare the specific surface areas of TiO2/Ni3S2 and Ni3S2 samples and it was incorrectly published.To better serve our readers,the correct figure is provided in this correction.The BET values are correct and unaffected.The corresponding figure caption,data analysis and conclusions are not affected and thus not to be changed.The authors would like to apologize for any inconvenience caused. | Shengjue Deng Kaili Zhang Dong Xie Yan Zhang Yongqi Zhang Yadong Wang Jianbo Wu Xiuli Wang Hong Jin Fan Xinhui Xia Jiangping Tu | 2021 | Nano-Micro Letters2021，13，1： | 1 |
| 15 | Electroless preparation and tribological properties of Ni-P- Carbon nanotube composite coatings under lubricated condition 显示文摘 | Chen Weixiang Tu Jiangping Gan Haiyang | 2002 | Surface and Coatings Technology2002，160，1： | 1 |
| 16 | Mesoporous Co3O4 monolayer hollow-sphere array as electrochemical pseudocapacitor material 显示文摘 | Xia Xinhui Tu Jiangping Wang Xiuli | 2011 | Chemical Communications2011，47，： | 1 |
| 17 | A facile path from fast synthesis of Li-argyrodite conductor to dry forming ultrathin electrolyte membrane for high-energy-density allsolid-state lithium batteries显示文摘All-solid-state lithium batteries(ASSLBs),utilizing sulfide solid electrolyte,are considered as the promising design on account of their superior safety and high energy density,whereas the time-consuming preparation process of sulfide electrolyte powders and the thickness of electrolyte layer hinder their practical application.Herein,an innovative ultimate-energy mechanical alloying plus rapid thermal processing approach is employed to rapidly synthesize the crystalline Argyrodite-type conductor Li_(5.3)PS_(4.3)ClBr_(0.7)(LPSCIBr)with superior ionic conductivity(11.7 mS cm^(-1)).Furthermore,to realize the higher energy density of the battery,an ultrathin LPSCIBr sulfide electrolyte membrane with superior ionic conductivity of 6.5 mS cm^(-1)is fabricated with the aid of polytetrafluoroethylene(PTFE)binder and the reinforced cellulose mesh.Moreover,a simple solid electrolyte interphase(SEI)is constructed on the surface of lithium metal to enhance anodic stability.Benefiting from the joint efforts of these merits,the modified ASSLBs with a high cell-level energy density of 311 Wh kg^(-1) show an excellent cyclic stability.The assembled all-solid-state Li_(2) S/Li pouch cell can operate even under the severe conditions of bending and cutting,demonstrating the enormous potential of the sulfide electrolyte membrane for ASSLBs application. | Zhao Jiang Hongling Peng Jingru Li Yu Liu Yu Zhong Changdong Gu Xiuli Wang Xinhui Xia Jiangping Tu | 2022 | Journal of Energy Chemistry2022，31，11： | 1 |
| 18 | Preparation and Tribological Properties of Inorganic Fullerene-like MoS2 显示文摘 | Tongzheng Zou Jiangping Tu Haidong Huang | 2006 | Advanced Engineering Materials2006，4，8： | 1 |
| 19 | Binder-free carbon fiber/TiNb2O7 composite electrode as superior high-rate anode for lithium ions batteries显示文摘Construction of advanced high-rate anodes is critical for the development of high-power lithium ion batteries(LIBs).In this work, we report a binder-free carbon fiber(CF)/titanium niobium oxide(TiNb_2O_7(TNO)) composite electrode via a simple solvothermal method combined with heat treatment.Continuous TNO film consisting of cross-linked TNO nanoparticles of 30-50 nm is strongly anchored on the carbon fiber forming integrated CF/TNO composite electrode. Owing to the intimate threedimensional structure, the as-prepared CF/TNO electrode presents exceptional high-rate performance(245 mAh/g at 1 C, and 138 mAh/g at 80 C) and enhanced cyclability with a capacity of 150 mAh/g at the current density of 10 C after 1000 cycles. Our results demonstrate the CF/TNO electrode as efficient anode for application in high-power lithium ion batteries. | Shenghui Shen Shengjue Deng Yu Zhong Jianbo Wu Xiuli Wang Xinhui Xia Jiangping Tu | 2017 | Chinese Chemical Letters2017，28，12： | 1 |
| 20 | Microstxucture and tribological behavior of pulsed laser deposited a-CNx films 显示文摘 | ZHENG Xiaohua TU Jiangping SONG Renguo | 2010 | Appl Surf Sci2010，256，10： | 1 |
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