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| 1 | Fabrication of PVDF nanofibrous hydrophobic composite membranes reinforced with fabric substrates via electrospinning for membrane distillation desalination显示文摘To improve the mechanical properties of the electrospun nanofibrous membrane, the nonwoven fabrics and spacer fabrics were employed as support substrates to fabricate polyvinylidene fluoride(PVDF) nanofibrous composite membranes. The influences of the substrate on membrane morphology, hydrophobicity, pore size and pore size distribution,porosity, mechanical strength and permeability were comprehensive evaluated. The electrospun composite membranes had a three dimension bead-fiber interconnected open structure and a rough membrane surface. The membrane surface presented a multilevel re-entrant structure and all the water contact angles were above 140°. In contrast with the pure PVDF nanofibrous membrane, the stress at break and the elastic modulus of the composite membranes increased by 4.5–16 times and 17.5–37 times, respectively. Since the spacer fabrics had less resistance to mass transfer, the membranes composited with spacer fabrics exhibited greater permeate fluxes compared with the composite membranes with the nonwoven fabrics as substrates.During the membrane distillation test, the highest permeate flux was up to 49.3 kg/m^2/hr at the feed temperature of 80°C. The long-time and repeat operation of membrane distillation desalination indicated the fabricated membrane with a good resistance to scaling and wetting.The results suggested the potential of the electrospun composite membrane for membrane distillation application. | Kuiling Li Deyin Hou Chaochen Fu Kai Wang Jun Wang | 2019 | Journal of Environmental Sciences2019，31，1： | 4 |
| 2 | Synthesis of novel chiral bisoxazoline ligands with a spiro[4,4]-1,6-nonadiene skeleton显示文摘A new type of chiral bisoxazoline ligands 1 based on spiro[4,4]-1,6-nonadiene backbone was easily prepared in six steps from racemic spiro[4,4]-nonane-1,6-dione,with the Pd-catalyzed coupling of the enol triflates with CO and amino alcohols as the key steps for the construction of the oxazoline moiety. The structure of the ligand (R,S,S)-1b was unambiguously established by X-ray crystallographic analysis. The chiral Cu(II) complex generated in situ from the combination of spiro bisoxazoline ligand (S,S,S)-1c and Cu(OTf)2 was effective in the catalysis of asymmetric chlorination of the β-ketoester,methyl 1-oxo-2,3-dihydro-1H-indene-2-carboxylate,affording the corresponding chlorinated derivative in 99% yield with 17% ee. | HAN ZhaoBin WANG Zheng ZHANG XuMu DING KuiLing | 2010 | Chinese Science Bulletin2010，55，25： | 1 |
| 3 | Copolymerization of cyclohexene oxide with CO2 by using intramolecular dinuclear zinc catalysts显示文摘 | XIAO Youli WANG Zheng DING Kuiling | 2005 | Chem Eur J2005，11，： | 1 |
| 4 | A novel twophase oxidative coupling of 2 -naphthols suspended in aqueous Fe^3+ solutions 显示文摘 | DING Kuiling WANG Yang ZHANG Lijun | 1996 | Tetrahedron1996，52，3： | 1 |
| 5 | Novd two - phase oxidative cress - coupling of the two - component molecular crystal of 2 - naphthol and 2 - naphthylamine 显示文摘 | Ding Kuiling Xu Qiguo Wang Yang | 1997 | Chemical Communications (Cambridge)1997，7，： | 1 |
| 6 | Synthesis of a new type of P,N-ligand with a spiro skeleton for Ir-catalyzed asymmetric hydrogenations显示文摘 | Zhaobin Han Zheng Wang Xumu Zhang Kuiling Ding | 2010 | Tetrahedron: Asymmetry2010，，11： | 1 |
| 7 | Making Spiroketal-based Diphosphine (SKP) Ligands via a Catalytic Asymmetric Approach显示文摘 | Xiaoming Wang Kuiling Ding | 2018 | Chinese Journal of Chemistry2018，36，10： | 1 |
| 8 | Practical by ligand design: a new class of monodentate phosphoramidite ligands for rhodium-catalyzed enantioselective hydrogenations显示文摘 | Zhao Baoguo Wang Zheng Ding Kuiling | 2006 | Adv Synth Cat2006，348，： | 1 |
| 9 | Model predictive control-based power dispatch for distribution system considering plug- n electric vehicle uncertainty 显示文摘 | Su Wencong Wang Jianhui Zhang Kuiling | 2014 | Electric Power Systems Research2014，106，： | 1 |
| 10 | Aromatic Spiroketal Bisphosphine Ligands: Palladium‐Catalyzed Asymmetric Allylic Amination of Racemic Morita–Baylis–Hillman Adducts显示文摘 | Xiaoming Wang Fanye Meng Yan Wang Zhaobin Han Yong‐Jun Chen Li Liu Zheng Wang Kuiling Ding | 2012 | Angew Chem Int Ed2012，，37： | 1 |
| 11 | Elaboration of novel copper-based catalysts显示文摘 | Chu Wei Wang Kuiling Zhang Tao | 2001 | J Nat Gas Chem2001，10，2： | 1 |
| 12 | Synthesis of chiral 1,3-bis(1-(diarylphosphoryl)ethyl)-benzenes via Ir-catalyzed double asymmetric hydrogenation of bis(diarylvinylphosphine oxides)显示文摘A class of chiral 1,3-bis(diarylphosphinoethyl)benzenes, which are key intermediates for the synthesis of PCP-type chiral pincer ligands, were prepared in high diastereomeric ratios and excellent ee values via double asymmetric hydrogenation of the corresponding bis(diarylvinylphosphine oxide) substrates using a SpinPhox/Ir(I) complex as the catalyst. The hydrogenation product 5a was readily transformed into the corresponding borane-protected chiral PCP-type pincer ligand 7a with high enantiomeric excess, exemplifying a viable synthetic route to optically active chiral PCP pincer ligands. | LIU Xu HAN ZhaoBin WANG Zheng DING KuiLing | 2014 | Science China Chemistry2014，57，8： | 0 |
| 13 | Biomimetic asymmetric catalysis显示文摘Enzymes are the core for biological transformations in nature.Their structures and functions have drawn enormous attention from biologists as well as chemists since last century.The large demand of bioactive molecules and the pursuit of efficiency and greenness of synthesis have spurred the rapid development of biomimetic chemistry in the past several decades.Biomimetic asymmetric catalysis,mimicking the structures and functions of enzymes,has been recognized as one of the most promising synthetic strategies for the synthesis of valuable chiral compounds.This review summarizes the evolution of asymmetric catalysis inspired by aldolases,vitamin B_(1)/B_(6)-dependent enzymes,NAD(P)H,flavin,hydrogenases,heme oxygenases,nonheme oxygenases,and dinuclear/multinuclear metalloenzymes in aspects of biomimetic design,catalyst development and related catalytic transformations.Those well-established synthetic approaches originating from biological reactions have demonstrated the unique prowess of biomimetic asymmetric catalysis in bridging the gap between bio-catalysis and chemical synthesis. | Xiao Xiao Kaini Xu Zhong-Hua Gao Zhou-Hao Zhu Changqing Ye Baoguo Zhao Sanzhong Luo Song Ye Yong-Gui Zhou Senmiao Xu Shou-Fei Zhu Hongli Bao Wei Sun Xiaoming Wang Kuiling Ding | 2023 | Science China Chemistry2023，66，6： | 0 |
| 14 | A novel electro-Fenton hybrid system for enhancing the interception of volatile organic compounds in membrane distillation desalination显示文摘Membrane distillation(MD)is a promising alternative desalination technology,but the hydrophobic membrane cannot intercept volatile organic compounds(VOCs),resulting in aggravation in the quality of permeate.In term of this,electro-Fenton(EF)was coupled with sweeping gas membrane distillation(SGMD)in a more efficient way to construct an advanced oxidation barrier at the gas-liquid interface,so that the VOCs could be trapped in this layer to guarantee the water quality of the distillate.During the so-called EF-MD process,an interfacial interception barrier containing hydroxyl radical formed on the hydrophobic membrane surface.It contributed to the high phenol rejection of 90.2% with the permeate phenol concentration lower than 1.50 mg/L.Effective interceptions can be achieved in a wide temperature range,even though the permeate flux of phenol was also intensified.The EF-MD system was robust to high salinity and could electrochemically regenerate ferrous ions,which endowed the long-term stability of the system.This novel EF-MD configuration proposed a valuable strategy to intercept VOCs in MD and will broaden the application of MD in hypersaline wastewater treatment. | Hongxin Liu Kuiling Li Kunpeng Wang Zhiyong Wang Zimou Liu Sichao Zhu Dan Qu Yu Zhang Jun Wang | 2024 | Journal of Environmental Sciences2024，，4： | 0 |
| 15 | Enantioselective Ring Opening of meso-Epoxides with Aro- matic Amines Catalyzed by Dinuclear Magnesium Complexes显示文摘与 n-Bu2Mg 从 chiral multidentate semi-azacrown 醚 ligands 的反应在 situ 产生的 dinuclear 镁建筑群被发现是为有苯胺衍生物的 meso-epoxides 的 enantioselective 戒指洞的有效催化剂,负担得起相应 chiral 在有多达 90% ee 的好收益的氨基的白酒。 | Hongli Bao Zheng Wang Tianpa You Kuiling Ding | 2013 | Chinese Journal of Chemistry2013，31，1： | 0 |
| 16 | Styrax japonicus functional genomics:an efficient virus induced gene silencing(VIGS)system显示文摘VIGS(Virus-induced gene silencing),a method for posttranscriptional gene silencing,is an effective technique for investigating the activities of genes in plants.Since there is no report for available VIGS system in Styrax japonicus,the application of a VIGS approach that results in a gene knockdown to study gene function is limited.In this study,we compared the characteristics that could affect the viability of VIGS in S.japonicus,including the acetosyringone(AS)concentration,the Agrobacterium’s optical density and the inoculation method.The stable reference genes of S.japonicus were selected to validate the gene’s knockdown by quantitative PCR.As a result,we successfully constructed 2 VIGS systems based on TRV virus:vacuum with AS concentration of 200μmol·L^(-1)and OD600of 0.5,and friction-osmosis with AS concentration of 200μmol·L^(-1)and OD600of 1.0,which silencing efficiency was 83.33%and 74.19%,respectively.The successfully applied VIGS method provides a rapid and effective reverse gene functional analysis approach in S.japonicus to identify unknown gene functions. | Gangyu Sun Yiqian Ju Cuiping Zhang Lulu Li Xinqiang Jiang Xiaoman Xie Yizeng Lu Kuiling Wang Wei Li | 2024 | Horticultural Plant Journal2024，10，1： | 0 |
| 17 | Global multifaceted biodiversity patterns,centers,and conservation needs in angiosperms显示文摘The Convention on Biological Diversity seeks to conserve at least 30%of global land and water areas by 2030,which is a challenge but also an opportunity to better preserve biodiversity,including flowering plants(angiosperms).Herein,we compiled a large database on distributions of over 300,000 angiosperm species and the key functional traits of 67,024 species.Using this database,we constructed biodiversity-environment models to predict global patterns of taxonomic,phylogenetic,and functional diversity in terrestrial angiosperms and provide a comprehensive mapping of the three diversity facets.We further evaluated the current protection status of the biodiversity centers of these diversity facets.Our results showed that geographical patterns of the three facets of plant diversity exhibited substantial spatial mismatches and nonoverlapping conservation priorities.Idiosyncratic centers of functional diversity,particularly of herbaceous species,were primarily distributed in temperate regions and under weaker protection compared with other biodiversity centers of taxonomic and phylogenetic facets.Our global assessment of multifaceted biodiversity patterns and centers highlights the insufficiency and unbalanced conservation among the three diversity facets and the two growth forms(woody vs.herbaceous),thus providing directions for guiding the future conservation of global plant diversity. | Ao Luo Yaoqi Li Nawal Shrestha Xiaoting Xu Xiangyan Su Yichao Li Tong Lyu Kilara Waris Zhiyao Tang Xiaojuan Liu Luxiang Lin Yongsheng Chen Kuiling Zu Wenqi Song Shijia Peng Niklaus E.Zimmermann Loïc Pellissier Zhiheng Wang | 2024 | Science China(Life Sciences)2024，67，4： | 0 |
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