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| 1 | Studies on photo-electro-chemical catalytic degradation of acid scarlet 3R dye显示文摘A new type of photo-electro-chemical catalytic reactor was designed.Cathode and anode of the new reactor were made of high-purity graphite and titanium dioxide electrode re-spectively.A saturated calomel electrode (SCE) was used as the reference electrode.Under the condition of ultraviolet radiation and anodic bias-voltage,acid scarlet 3R was degraded by the process of photoelectrocatalysis with titanium dioxide electrode in anodic compartment,while it was degraded by electrogenerated Fenton’s reagent and hydrogen peroxide through reducing dissolved oxygen with graphite electrode in catholyte.The new reactor made the best use of photogenerated holes and photogenerated charge on the anode of the new reactor,which achieved the purpose of degrading acid scarlet 3R in the cathodic and anodic compartments simultaneously,i.e.“two electrodes and double effect”.The experimental results showed that,compared with other photoelectrocatalysis reactors (“two electrodes and single effect” reactor),the new reactor has obviously enhanced the degradation of acid scarlet 3R dye.With the con-centration of the dye being 30 mg·L?1 in water,under the operating conditions that when the inert supporting electrolyte concentration was 0.02 mol·L?1 sodium sulfate,initial solution pH = 3,and cathodic potential ?Ec = 0.66 V,the highest decolorizing efficiency of 92% was accomplished in cathodic compartment,and that of 60% in anodic compartment. | LI Mingyu1,XIONG Lin1,CHEN Yunyun2,ZHANG Na1,ZHANG Yuanming2 & YIN Hua1 1.Department of Environmental Engineering,Jinan University,Guangzhou 510630,China 2.Department of Chemistry,Jinan University,Guangzhou 510630,China | 2005 | Science China Chemistry2005，48，4： | 13 |
| 2 | A new grid-associated algorithm in the distributed hydrological model simulations显示文摘This paper presents a new grid-associated algorithm to improve the performance of a D8 algorithm based distributed hydrological model computation.The algorithm is based on the well known single-flow D8 algorithm of grid flow.This algorithm allocates calculation priorities according to the distance between the units and the outlet,then carries out the ergodic computations of the hydrological units according to the priority division.For the parallelized algorithm,a standard thread-level shared memory system for parallel programming(OpenMP-Open specifications for Multi Processing) was introduced,and the parallel coding was implemented in C lan-guage.A case study showed that the absolute speed-up ratio of the grid-associated algorithm is 1.64 over the original D8 algorithm,and the linear speed-up ratio of the parallel associated algorithm is 2.42 under 4 cores.The parallel grid-associated algorithm can be applied to a variety of research fields that use the grid method. | XU Rui1,2,HUANG XiaoXue1,LUO Lin1 & LI ShaoCai3 1 State Key Laboratory of Hydraulics and Mountain River Engineering College of Architecture and Environment,Sichuan University,Chengdu 610065,China 2 College of Electronic Engineering,Guilin University of Electronic Technology,Guilin 541004,China 3 College of Life Sciences,Sichuan University,Chengdu 610065,China | 2010 | Science China(Technological Sciences)2010，53，1： | 8 |
| 3 | Influence of MnO_2 on the photocatalytic activity of P-25 TiO_2 in the degradation of methyl orange显示文摘Influences of α-MnO2, β-MnO2, and δ-MnO2 on the photocatalytic activity of Degussa P-25 TiO2 have been investigated through the photocatalytic degradation of methyl orange. The TiO2 photocatalyst, before and after being contaminated by MnO2, was characterized by UV-visible diffuse reflectance spectroscopy (UV-vis DRS), photoluminescence (PL), and X-ray photoelectron spectroscopy (XPS). The results showed that photocatalytic activity of TiO2 could be inhibited significantly or completely deactivated due to the presence of even a small amount of MnO2 particles. It was found that the poisoning effect varied with the crystal phases of MnO2 and the effect was in the order δ-MnO2 >α-MnO2 >β-MnO2. The poisoning effect was attributed to the formation of heterojunctions between MnO2 and TiO2 particles. The heterojunctions changed the chemical state of Ti4+ and O2 sites in the crystalline phase of TiO2. MnO2 in contact with TiO2 particles also broadens the band-gap of TiO2, which decreases UV absorption of TiO2. It can also create some deep impurity energy levels serving as photoelec-tron-photohole recombination center, which accelerates the electron-hole recombination. | LI ShunJun1, MA ZiChuan1,2, WANG Lin1 & LIU JingZe2 1 College of Chemistry and Material Sciences, Hebei Normal University, Shijiazhuang 050016, China 2 College of Life Science, Hebei Normal University, Shijiazhuang 050016, China | 2008 | Science China Chemistry2008，51，2： | 7 |
| 4 | Indoor imitation experimental study on driving factors of rainfall-runoff process显示文摘The driving actions of rainfall-runoff process can be attributed to two aspects. The first is the influence of precipitation process, and the second is that of the ground pad. The re- search results of 179 indoor experiments conducted to imitate rainfall-runoff process indicate that both precipitation duration and intensity play important roles in affecting confluence lag time, which is obviously inconsistent with the traditional hypotheses. The nonlinear relationship is of great significance to the confluence curve especially when the precipitation duration is less than the total confluence time or the precipitation intensity is small. Therefore it can be concluded that the unit hydrograph (UH) can be applied to rainfall-runoff process imitation in the humid areas in the south China region. However, the UH application should be strictly modified in accordance with precipitation conditions in the arid and semiarid region of north China where the precipitation duration is short and the intensity is unstable. It will be hard to get ideal imitation results if the UH is applied blindly without considering specific conditions in the north China region. This also explains the unsatisfactory imitation results caused by using various hydrological models in the north China region. When the precipitation duration is short, and the watershed has not reached total watershed concentration, the characteristics of confluence change greatly, which reflects the actual situation in the north China region. Therefore necessary nonlinear corrections should be made when UH is applied. If the duration is longer than the total confluence time and the balance between pondage and discharge is stricken, the imitation research results will be applicable to both rainfall-runoff relation with longer duration in the south China region and the basic theoreti- cal research on runoff generation and concentration. On conditions of adequate rainfall, peak discharge is in linear relationship with intensity, but has nothing to do with the ground pad. There is a negative linear relationship between intensity and time to peak . The amount of pondage capacity in a catchment is in linear relationship with intensity and peak discharge, with obvious influence by the ground pad status and interception, and it has nothing to do with the position of interceptions. | ZHANG Shifeng1, LIU Changming 1, XIA Jun1, TAN Ge 1, LI Lin1, LIU Caitang1, ZHOU Changqing 1 & GUO Lei2 1. Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China 2. College of Water Resources and Hydropower Engineering, Wuhan University, Wuhan 430072, China | 2005 | Science China Earth Sciences2005，48，3： | 3 |
| 5 | Multi-carbazole derivatives for two-photon absorption data storage:Synthesis,optical properties and theoretical calculation显示文摘Two novel quadrupolar organic compounds, 3-(4-((E)-2-(9-butyl-9H-carbazol-6-yl) vinyl)styryl)-9-propyl-9H-carbazole (BCSPC) and 3-(3-(3-((1E)-2-(4-((E)-2-(3-(3,5-bis(9-butyl-9H-carbazol-6-yl)phenyl)-9-butyl-9H-carbazol-6-yl)vinyl)phenyl) vinyl)-9-butyl-9H-carbazol-6-yl)-5-(9-butyl-9H-carbazol-6-yl)phenyl)-9-butyl-9H-carbazole (BCPBC), with different conjugated arms, have been designed and synthesized. Their one-and two-photon absorption (TPA) and excited fluorescence properties have been experimentally investigated. The two-photon absorption cross-sections of two compounds were estimated by two-photon excited fluorescence technique using 200 fs, 76 MHz, Ti:sapphire laser, which are 22 and 154 GM for BCSPC and BCPBC, respectively. The optimal excitation wavelengths are 780 nm for both BCSPC and BCPBC. A data recording experiment proved the potential application of the materials. | LI Lin1, YANG JiaXiang1,2, WANG CaiXia1, HU ZhangJun1, TIAN YuPeng1,2, LI Jing3, WANG ChuanKui3, LI Ming4, CHENG GuangHua4, TANG HuoHong5, HUANG WenHao5, TAO XuTang2 & JIANG MinHua2 1Department of Chemistry, Anhui University, Hefei 230039, China 2State Key Laboratory of Crystal Materials, Institute of Crystal Materials of Shandong University, Jinan 250100, China 3Department of Physics, Shandong Normal University, Jinan 250014, China 4State Key Laboratory of Transient Optics and Photonics, Xi’an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi’an 710119, China 5Department of Precision Machinery and Precision Instrumentation, University of Science and Technology of China, Hefei 230026, China | 2010 | Science China Chemistry2010，53，4： | 2 |
| 6 | A genome-wide survey of maize lipid-related genes: candidate genes mining,digital gene expression profiling and colocation with QTL for maize kernel oil显示文摘Lipids play an important role in plants due to their abundance and their extensive participation in many metabolic processes.Genes involved in lipid metabolism have been extensively studied in Arabidopsis and other plant species.In this study,a total of 1003 maize lipid-related genes were cloned and annotated,including 42 genes with experimental validation,732 genes with full-length cDNA and protein sequences in public databases and 229 newly cloned genes.Ninety-seven maize lipid-related genes with tissue-preferential expression were discovered by in silico gene expression profiling based on 1984483 maize Expressed Sequence Tags collected from 182 cDNA libraries.Meanwhile,70 QTL clusters for maize kernel oil were identified,covering 34.5% of the maize genome.Fifty-nine (84%) QTL clusters co-located with at least one lipid-related gene,and the total number of these genes amounted to 147.Interestingly,thirteen genes with kernel-preferential expression profiles fell within QTL clusters for maize kernel oil content.All the maize lipid-related genes identified here may provide good targets for maize kernel oil QTL cloning and thus help us to better understand the molecular mechanism of maize kernel oil accumulation. | LI Lin1,LI Hui1,LI JiYing1,XU ShuTu1,YANG XiaoHong1,LI JianSheng1 & YAN JianBing1,2 1National Maize Improvement Centre of China,China Agricultural University,Beijing 100193,China 2International Maize and Wheat Improvement Centre (CIMMYT),Apdo.Postal 6-641,06600 Mexico,D.F.,Mexico | 2010 | Science China(Life Sciences)2010，53，6： | 2 |
| 7 | A New Investigation of Mannich Reaction显示文摘During the synthesis of the derivatives of styryl ketonic Mannich bases, a side -product IM,other than the normal Mannich base MA, is obtained. Mannich reaction is further studied and the formation mechanism of product IM is postulated and discussed on the basis of deuterium labelling. | Li Yuan MOU2, Zi Yun LIN1, Li Ya ZHU1*, Xiao Tian LIANG1 1Institute of Materia Medica, Chinese Academy of Medical Sciencesand Peking Union Medical College, Beijing 100050 2Center for Biophysical Science and Engineering University of Alabama at Birmingham | 2001 | Chinese Chemical Letters2001，12，6： | 1 |
| 8 | Economic principles and fundamental model of the sustainable utilization of ecological resources显示文摘By analyzing the basic rules and measurement principles of the sustainable utilization of ecological resources and constructing its mathematical model, this paper points out that the sustainable utilization of ecological resources is in nature to use the double-period model thousands of times for the dynamic distribution of ecological resources effectively. And it points out that in order to realize the sustainable utilization of ecological resources we must follow the basic principle - non-decreasing ecological capital and put forward corresponding standards, measures, policies and proposals. | Li Lin Du Jinpei Li Lin1 | 2006 | Ecological Economy2006，2，4： | 1 |
| 9 | Possible Energy Network with polygeneration system and CCS for China显示文摘On basis of adopting polygeneration systems for power and alternative fuels,capturing CO2 with near zero energy penalties,and storing CO2 on sites,a new kind of Energy Network can integrate energy utilization,CO2 capture,transportation and storage synthetically.Techno-economic analysis of this solution focusing on Inner Mongolia and the Yangtze River Delta districts had been carried with comparison to the chain method for energy utilization and CO2 sequestration.This solution can save 21.5% of energy,and reduce 35% of total costs.The adoption of advanced polygeneration systems contributes 52.2% of the total saved costs,and the integration of energy utilization and CO2 sequestration in the Energy Network contributes 47.8%.From the aspect of CCS,the CO2 sequestration cost in the Energy Network can be as low as 12 $/t due to the lower energy penalties of capture in polygeneration systems and the combination of CO2 source and sink.The Energy Network exhibits attractive performance on energy saving,costs reduction for CCS,which may be a promising solution for sustainable development of China. | GAO Lin1,LI Sheng1,2,JIN HongGuang1 & LIN Hu1 1 Institute of Engineering Thermophysics,Chinese Academy of Sciences,Beijing 100190,China 2 Graduate School of Chinese Academy of Sciences,Beijing 100039,China | 2010 | Science China(Technological Sciences)2010，53，1： | 1 |
| 10 | Relation of phospholipase A2-Ⅴ and indoxam to hippocampal neuronal death显示文摘BACKGROUND: Ⅴ secretory phospholipase A2 (sPLA2-Ⅴ) is abundant in many mammal tissues. However, it remains unknown whether sPLA2-Ⅴ causes biological or pathological response in central nervous system. OBJECTIVE: To observe the effect of phospholipase A2-Ⅴ (PLA2-Ⅴ) and its inhibitor (indoxam) on hippocampal neuron survival. DESIGN: A repetitive measurement. SETTING: The Animal Center of South Carolina University. MATERIALS: Sprague-Dawley pregnancy day-7, 14, 21 female rats were selected; Reagents: sPLA2- Ⅴ and indoxam were obtained from the Dennis Research Laboratories METHODS: The experiment was finished at the animal center in South Carolina University from January to December, 2004. 0, 12.5, 25, 50 and 100 μg/L sPLA2-Ⅴ were added to neuron with none-MgCl2 Eagle's medium at 37 ℃, then changed to normal neuron culture medium after 3 hours. 1, 2.5, 5 and 10 μmol/L indoxam was added at 6 hours after 100 μg/L sPLA2-Ⅴwas put to Day-21 SD rat hippocampal embryonic neurons with none-MgCl2 Eagle's medium at 37 ℃. After 3 hours in the inhibition experiment, it was changed to normal neuron culture medium. The embryonic hippocampal neurons were primarily cultured, and the neuron survival ratio was detected with morphological method. MAIN OUTCOME MEASURES: Survival ratio of hippocampal neurons. RESULTS: ① Effects of sPLA2-Ⅴon neuron survival: When sPLA2-Ⅴ was 0, 12.5, 25, 50 and 100 μg/L, the neuron survival ratios in embryonic neurons of day-7 SD rats were (95.3±1.1)%, (81.4±3.1)%, (74.2±2.2)%, (62.4±1.7)% and (48.9±1.6)%, those in embryonic neurons of day-14 rats were (93.2±1.4)%, (74.3±1.9)%, (68.1±1.7)%, (56.1±1.4)% and (42.5±1.1)%, and those in embryonic neurons of day-21 rats were (91.2±1.2)%, (69.4±2.1)%, (60.3±2.2)%, (49.1±1.2)% and (35.5±1.9)%. There were significant differences among different concentrations (P < 0.05). ② Effects of indoxam on neuron survival: In case of sPLA2-Ⅴ 100 μg/L, the neuron survival ratios were (58.65±1.4)%, (69.34±1.1)%, (82.11±1.2)% and (95.28±0.9)% when indoxam was 1, 2.5, 5 and 10 μmol/L, respectively. There were significant differences among different concentrations (P < 0.05). CONCLUSION: ① The of neuronal death ratio is in a concentration-dependent manner with sPLA2-Ⅴ, and increases as the embryonic aging. ② Indoxam inhibits the proapoptotic effect of sPLA2-Ⅴ. | Fang Liu1,2, Shi Wang1, Yan Lin1, Runhui Li1, Li Ma1, Yanjun Li1, Qing Jin1, Xiao Gong1, Yuhua Chen3 1Department of Neurology, Fengtian Hospital of Shenyang Medical College, Shenyang 110024, Liaoning Province, China 2South Carolina University, SC, U.S.A 3Department of Development, China Medical University, Shenyang 110024, Liaoning Province, China | 2006 | Neural Regeneration Research2006，1，8： | 0 |
| 11 | Genome-wide identification of gene expression in the epididymis of infertile rat induced by alpha-chlorohydrin using oligonucleotide microarray显示文摘Objective To establish a rat model of sterility associated with epididymis and epididymal gene expression profiles relation to fertility by alpha-chlorohydrin.Methods Rats were treated with 10 mg·kg-1·d-1.alpha-chlorohydrin for 10 consecutive days.Sperm maturation and other fertility parameters were analyzed.The sperm motility and morphology were evaluated by computer-assisted sperm analysis(CASA);sperm survival rate was assessed by SYBR-14 and propidium iodide(PI)fluorescent staining;the weights of testes,epididymides,prostates and seminal vesicles were determined by electronic balance;histological examination of above tissues were evaluated by HE staining;and serumal dihydrotestosterone(DHT)and testosterone(T)of rats were detected by enzyme-labeled immunoassay.Each male rat was paired with 2 female rats in proestrus.Female rats were examined the next morning for the presence of sperm in vaginal smears and underwent a cesarean section on day 12 of gestation.Finally the reproductive indices were calculated as follows:copulation index(number of sperm positive females /number of pairings),pregnancy index(number of pregnancies /number of sperm positive females),and fertility index(number of pregnancies /number of pairings).After that we used Affymetrix Rat 230 2.0 oligo-microarray to identify epididymal special genes associated with fertility.Finally,we validated some of these genes by Real-Time quantitative polymerase chain reaction.Results The motility of spermatozoa from the cauda epididymidis of treated rats showed a significant decrease in percentage of motile,progressively motile sperm,and sperm survival rate.At the same time,the morphology of cauda epididymal spermatozoa was also adversely affected by the treatment.In addition,the serumal androgen levels of treated animals weren't changed compared with the control group.Accordingly,matings with treated males resulted in no successful pregnancy.Then,we classified general functions of the down or up regulated epididymal genes by chlorhydrin with the GeneSpring gene ontology(GO)analysis,which are involved in macromolecular metabolism and transport,primary metabolism process,cell metabolism,biological process regulation,immunology regulation,ion combination,hydratase and oxidoreductase activity.Among all the different expressed genes,we analyzed and screened the down-regulated genes associated with glucose,lipid,protein and other energy metabolism,which are considered as the major ACH action targets.Simultaneously,the up-regulated genes by chlorhydrin were detected and their characters of negative regulated sperm maturation and fertility analyzed,which are apoptosis and immune-related genes and not reported before.Conclusions We established male infertile rat model with ACH(10 mg·kg-1·d-1,po,10 days)through evaluating changes of sperm motility and morphology,mating index,fertility index and pregnancy index.Simultaneously,the ACH didn't affect the major androgen(T and DHT)metabolism and sexual ability,which is considered as the best way for male contraception.Then we determined the down-regulated epididymal genes relation to substance metabolism,which can affect the epididymal sperm maturation and presumed the major antifertility targets by ACH.Further more,we found and analyzed the epididymal up-regulated genes associated with apoptosis and immune functions,which maybe the new possible sites of action by ACH and other male antifertility agents. | XIE Shu-wu1,2,ZHU Yan1,2,MA Li1,2,LI Zhi-ling1,2,GUI You-lun1,2,LU Ying-ying3,ZHAO Zhi-fang1,2,CAO Lin1,2(1.Department of Reproductive Pharmacology,Shanghai Institute of Planned Parenthood Research 2.National population and family planning key laboratory of contraceptive drugs and devices,Shanghai 200032,China 3.Obstetrics and Gynecology Hospital of Fudan University,Shanghai 200011,China) | 2008 | 沈阳药科大学学报2008，25，S1： | 0 |
| 12 | Identification and analysis of differentially expressed genes involved in dark-induced photoperiod response and senescence of soybean leaves by suppression subtractive hybridization显示文摘A cDNA subtractive library enriched for dark-induced up-regulated ESTs was constructed by suppression subtractive hybridization(SSH) from leaf tissues of soybean cultivar DongNong L13 treated with short-day(8-h light/16-h dark) and long-day(16-h light/8-h dark) conditions.A total of 148 clones were sequenced,representing 76 unique ESTs which corresponded to about 20% of 738 clones from the cDNA library and showed a significant up-regulation of at least three fold verified by dot blot hybridization.The putative functions of ESTs were predicted by Blastn and Blastx.The 43 differentially expressed genes identified by subtractions were classified according to their putative functions generated by Blast analysis.Genetic functional analysis indicated that putative proteins encoded by these genes were related to diverse functions during organism development,which include biological regulation pathways such as transcription,signal transduction and programmed cell death,protein,nucleic acid and carbohydrate macromolecule degradation,the cell wall modification,primary and secondary metabolism and stress response.Two soybean transcription factors enhanced in SD conditions,GAMYB-binding protein and DNA binding protein RAV cDNAs that may be involved in SD soybean photoperiod response,had been isolated using 5'-and 3'-rapid amplification of cDNA ends(RACE)(Genbank Accession numbers DQ112540 and DQ147914). | ZHAO Lin1,LUO Qiu-lan1,HAN Ying-peng1,YANG Chun-liang2,LI Wen-bin1(1.Soybean Research Institute(Key Laboratory of Soybean Biology of Chinese Education Ministry),Northeast Agriculture University,Haerbin,China 150030 2.The Basic MedicalScience College,Harbin Medical University,Haerbin,China 150081) | 2007 | 湖南农业大学学报(自然科学版)2007，33，S1： | 0 |
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