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| 1 | MilkyWay-2 supercomputer: system and application显示文摘 | Xiangke LIAO Liquan XIAO Canqun YANG Yutong LU | 2014 | Frontiers of Computer Science2014，8，3： | 32 |
| 2 | Ni-based cathode materials for Na-ion batteries显示文摘Na-ion batteries(NIBs)have attracted significant attention owing to Na being an abundant resource that is uniformly distributed in the Earth's crust.Several 3d transition metal(TM)ions have been thoroughly investigated as charge compensators in single or multiple composition systems to enhance the electrochemical performance of cathodes for the practical applications.In this review,the composition-structure-property relationship of Ni-based cathodes has been reviewed as a design perspective for NIB'S cathodes.The typical Ni-based cathode materials have bee n systematically summarized and comparatively analyzed,and it is dem on strated that Ni io ns can be used to provide charge compensation.Moreover,Ni-based cathodes present high reversible capacity owing to the multi-electron redox reactions and suitable redox pote ntial of Ni-ions redox.However,con sidering the abundan ce,cost,and hygroscopic properties of Ni eleme nt,the content of 0.15-0.35 per formula can be optimal for enhancing the performance of cathodes.Lastly,further perspectives on designing Ni?containing cathodes,including Ni-rich layered cathodes,have been discussed,which could promote the practical applications of NIBs for grid-scale energy storage in future. | Chenglong Zhao Yaxiang Lu Liquan Chen Yong-Sheng Hu | 2019 | Nano Research2019，12，9： | 8 |
| 3 | High-temperature treatment induced carbon anode with ultrahigh Na storage capacity at low-voltage plateau显示文摘Sodium-ion batteries(NIBs) show great prospect on the energy storage applications benefiting from their low cost and the abundant Na resources despite the expected lower energy density compared with lithium-ion batteries(LIBs). To further enhance the competitive advantage, especially in energy density,developing the high-capacity carbon anode materials can be one of the effective approaches to realize this goal. Herein, we report a novel carbon anode made from charcoal with a high capacity of ~400 m Ah g^(-1), wherein about 85%(>330 mAh g^(-1)) of its total capacity is derived from the long plateau region below ~0.1 V, which differs from those of typical hard carbon materials(~300 m Ah g^(-1)) in NIBs but is similar to the graphite anode in LIBs. When coupled with air-stable Na_(0.9)Cu_(0.22)e_(0.30)Mn_(0.48)O_2 oxide cathode, a high-energy density of ~240 Wh kg^(-1) is achieved with good rate capability and cycling stability. The discovery of this promising carbon anode is expected to further improve the energy density of NIBs towards large-scale electrical energy storage. | Chenglong Zhao Qidi Wang Yaxiang Lu Baohua Li Liquan Chen Yong-Sheng Hu | 2018 | Science Bulletin2018，63，17： | 7 |
| 4 | Flexible Na batteries显示文摘Flexible energy storage devices have gained significant attention because of the increasing needs of bendable displays,wearable electronics,and flexible displays.Flexible Na-based rechargeable batteries are the promising power sources in such products due to their low cost and wide availability.In this review,we firstly introduce the structural superiority of flexible Na-based batteries and summarize their main components including cathodes,electrolytes,and anodes.Moreover,fabrication of their flexible components is discussed in detail,with specific emphasis on material selection,particularly for solid-state electrolytes.This is followed by an overview highlighting recent progress in the development of prototypes of flexible Na-ion batteries and beyond.Finally,perspectives on future challenges for the development of flexible Na batteries are proposed. | Chenglong Zhao Yaxiang Lu Liquan Chen Yong-Sheng Hu | 2020 | InfoMat2020，2，1： | 6 |
| 5 | Advanced Na metal anodes显示文摘Na metal anode, benefiting from its high theoretical capacity and lowest electrochemical potential, is one of the most favorable candidates for future Na-based batteries with high energy density. Dendrite growth, volume change and high reactivity are the formidable challenges in terms of good cycling performance and high Coulombic efficiency as well as an expected safety guarantee of Na metal anode for the practical application. Solid electrolyte interphase(SEI) layer as an indispensable component of a battery,its formation and stability play the critical role in the feasibility of Na metal anode. In this review, we first discuss the current consideration and challenges of Na metal anode, and then summarize several strategies to suppress dendrite growth and improve electrochemical performance, including interface engineering, electrolyte composition, electrode construction, and so on. Finally, the conclusion and future perspective of potential development on Na metal anode are proposed. | Chenglong Zhao Yaxiang Lu Jinming Yue Du Pan Yuruo Qi Yong-Sheng Hu Liquan Chen | 2018 | Journal of Energy Chemistry2018，27，6： | 5 |
| 6 | Progress on Integrated Control of Tobacco Black Shank显示文摘Tobacco black shank is one of the devastating diseases of tobacco. In recent years,this disease widely occurred in most tobacco-growing areas,which caused disastrous losses and has severely threatened the sustainable development of flue-cured tobacco. In order to lay a theoretical foundation for the better control of tobacco black shank,the occurrence characteristics and integrated control strategis of this disease were systematically discussed according to the aspects of agricultural control,chemical control,biological control,etc. | Yonghui XIE Yonggui ZHANG Liquan ZHU Daogui YOU Yao LU | 2015 | Agricultural Biotechnology2015，4，4： | 3 |
| 7 | Anthraquinone derivative as high-performance anode material for sodium-ion batteries using ether-based electrolytes显示文摘Organic materials, especially the carbonyl compounds, are promising anode materials for room temperature sodium-ion batteries owing to their high reversible capacity, structural diversity as well as eco-friendly synthesis from bio-mass. Herein, we report a novel anthraquinone derivative, C_(14)H_6 O_4 Na_2 composited with carbon nanotube(C_(14)H_6 O_4 Na_2-CNT), used as an anode material for sodium-ion batteries in etherbased electrolyte. The C_(14)H_6 O_4 Na_2-CNT electrode delivers a reversible capacity of 173 mAh g^(-1) and an ultra-high initial Coulombic efficiency of 98% at the rate of 0.1 C. The capacity retention is 82% after 50 cycles at 0.2 C and a good rate capability is displayed at 2 C.Furthermore, the average Na insertion voltage of 1.27 V vs. Na^+/Na makes it a unique and safety battery material, which would avoid Na plating and formation of solid electrolyte interface. Our contribution provides new insights for designing developed organic anode materials with high initial Coulombic efficiency and improved safety capability for sodium-ion batteries. | Linqin Mu Yaxiang Lu Xiaoyan Wu Yuejun Ding Yong-Sheng Hu Hong Li Liquan Chen Xuejie Huang | 2018 | Green Energy & Environment2018，3，1： | 2 |
| 8 | Low phosphorus promotes NSP1–NSP2 heterodimerization to enhance strigolactone biosynthesis and regulate shoot and root architecture in rice显示文摘Phosphorus is an essential macronutrient for plant development and metabolism,and plants have evolved ingenious mechanisms to overcome phosphate(Pi)starvation.However,the molecular mechanisms underlying the regulation of shoot and root architecture by low phosphorus conditions and the coordinated utilization of Pi and nitrogen remain largely unclear.Here,we show that Nodulation Signaling Pathway 1(NSP1)and NSP2 regulate rice tiller number by promoting the biosynthesis of strigolactones(SLs),a class of phytohormones with fundamental effects on plant architecture and environmental responses.We found that NSP1 and NSP2 are induced by Oryza sativa PHOSPHATE STARVATION RESPONSE2(OsPHR2)in response to low-Pi stress and form a complex to directly bind the promoters of SL biosynthesis genes,thus markedly increasing SL biosynthesis in rice.Interestingly,the NSP1/2–SL signaling module represses the expression of CROWN ROOTLESS 1(CRL1),a newly identified early SL-responsive gene in roots,to restrain lateral root density under Pi deficiency.We also demonstrated that GR24^(4DO) treatment under normal conditions inhibits the expression of OsNRTs and OsAMTs to suppress nitrogen absorption but enhances the expression of OsPTs to promote Pi absorption,thus facilitating the balance between nitrogen and phosphorus uptake in rice.Importantly,we found that NSP1p:NSP1 and NSP2p:NSP2 transgenic plants show improved agronomic traits and grain yield under low-and medium-phosphorus conditions.Taken together,these results revealed a novel regulatory mechanism of SL biosynthesis and signaling in response to Pi starvation,providing genetic resources for improving plant architecture and nutrient-use efficiency in low-Pi environments. | Kun Yuan Hao Zhang Chaoji Yu Nan Luo Jijun Yan Shuang Zheng Qingliang Hu Dahan Zhang Liquan Kou Xiangbing Meng Yanhui Jing Mingjiang Chen Xinwei Ban Zongyun Yan Zefu Lu Jian Wu Yu Zhao Yan Liang Yonghong Wang Guosheng Xiong Jinfang Chu Ertao Wang Jiayang Li Bing Wang | 2023 | Molecular Plant2023，16，11： | 2 |
| 9 | Large Scale One-Pot Synthesis of Monodispersed Na_(3)(VOPO_(4))_(2)F Cathode for Na-Ion Batteries显示文摘Na-ion batteries(NIBs)have received significant interest as potential candidates for large-scale energy storage owing to the widespread distribution of sodium and superior low-temperature performance.However,their commercial application is usually hindered by the high production cost and inadequate performance for electrode materials,particularly for cathodes.Na_(3)(VOPO_(4))_(2)F(NVOPF)has been recognized as one of the most promising cathodes for high-energy NIBs owing to the high working voltage and energy density.Here,we report a facile highly efficient room-temperature solution protocol for large-scale synthesis of NVOPF cathode for NIBs.By simply regulating pH,NVOPF can be obtained,which delivered a discharge capacity of 120.2 mAh g^(-1) at 0.1 C and 72%capacity retention over 8000 cycles at 25 C.Besides,the kilogram-level NVOPF products have been synthesized,and 26650 cylindrical cells were fabricated,which exhibit excellent cycling stabilities,remarkable lowtemperature performance with comparable safety features.We hope our findings could provide insights on the industrial application of NVOPF in NIBs. | Qiangqiang Zhang Xing Shen Quan Zhou Kaixuan Li Feixiang Ding Yaxiang Lu Junmei Zhao Liquan Chen Yong-Sheng Hu | 2022 | Energy Material Advances2022，，1： | 2 |
| 10 | Stable Ni-rich layered oxide cathode for sulfide-based all-solid-state lithium battery显示文摘Sulfide-based all-solid-state lithium-ion batteries(ASSLIBs)are one of the most promising energy storage technologies due to their high safety and ionic conductivity.To achieve greater energy density,a Ni-rich layered oxide LiNi_(x)Co_(y)M_(1-x-y)O_(2)(NCM,MMn/Al,x≥0.6)is desirable due to its relatively high voltage and large capacity.However,interfacial side reactions between the NCM and sulfide solid electrolytes lead to undesirable interfacial passivation layers and low ionic conductivity,thereby degrading the electrochemical performance of NCM sulfide all-solid-state batteries.Herein,a time-/cost-effective sulfidation strategy is exploited to sulfidize a Ni-rich NCM_(88) cathode in a mixed gas atmosphere of N_(2) and CS_(2).A new type of cathode(NCM88-S)with an ultrathin(∼2nm)surface layer is obtained,which significantly reduces the interfacial side reactions/resistance and improves the interfacial stability.The resulting NCM_(88)-S/Li_(6)PS_(5)Cl/Li_(4)Ti_(5)O_(12) ASSLIB exhibits superior performance,including a high discharge specific capacity(200.7 mAh g−1)close to that of liquid batteries,excellent cycling performance(a capacity retention of 87%after 500 cycles),and satisfactory rate performance(158.3 mAh g^(−1) at 1C). | Yue Wang Zhixuan Wang Dengxu Wu Quanhai Niu Pushun Lu Tenghuan Ma Yibo Su Liquan Chen Hong Li Fan Wu | 2022 | eScience2022，2，5： | 2 |
| 11 | Disordered carbon anodes for Na-ion batteries—quo vadis?显示文摘Na-ion batteries(NIBs)are gradually attracting much attention as an alternative to lead-acid batteries and supplement to Li-ion batteries(LIBs)owing to the abundant Na resources and excellent cost-effectiveness.Since the most commonly used graphite as an anode material in LIBs cannot be inherently used in NIBs,tremendous efforts have been made to advance the fundamental understanding and design of suitable anode materials for NIBs,including the improvement of Na storage capacity and the study on Na storage mechanisms.According to all these studies,disordered carbons are now the most promising anode candidates for NIBs.In this review,we discuss the current challenges and remaining problems to be solved in the area of disordered carbon anode materials for NIBs and provide future insights and research directions. | Fei Xie Zhen Xu Zhenyu Guo Yaxiang Lu Liquan Chen Maria-Magdalena Titirici Yong-Sheng Hu | 2021 | Science China Chemistry2021，64，10： | 2 |
| 12 | Contourlet Watermarking Algorithm Based on Arnold Scrambling and Singular Value Decomposition 显示文摘 | Chen Liquan Sun Xiaoyan Lu Miao | 2012 | Journal of Southeast University2012，28，4： | 1 |
| 13 | Lithium Storage in Li4Ti5O12 Spinel: The Full Static Picture from Electron Microscopy显示文摘 | Xia Lu Liang Zhao Xiaoqing He Ruijuan Xiao Lin Gu Yong‐Sheng Hu Hong Li Zhaoxiang Wang Xiaofeng Duan Liquan Chen Joachim Maier Yuichi Ikuhara | 2012 | Adv. Mater2012，，24： | 1 |
| 14 | Modification of NASICON Electrolyte and Its Application in Real Na-Ion Cells显示文摘The low ionic conductivity of solid-state electrolytes(SSEs)and the inferior interfacial reliability between SSEs and solid-state electrodes are two urgent challenges hindering the application of solid-state sodium batteries(SSSBs).Herein,sodium(Na)super ionic conductor(NASICON)-type SSEs with a nominal composition of Na_(3+2x)Zr_(2-x)MgxSi_(2)PO_(12) were synthesized using a facile two-step solid-state method,among which Na_(3.3)Zr_(1.85)Mg_(0.15)Si_(2)PO_(12)(x=0.15,NZSP-Mg_(0.15))showed the highest ionic conductivity of 3.54mS∙cm^(-1) at 25℃.By means of a thorough investigation,it was verified that the composition of the grain boundary plays a crucial role in determining the total ionic conductivity of NASICON.Furthermore,due to a lack of examination in the literature regarding whether NASICON can provide enough anodic electrochemical stability to enable high-voltage SSSBs,we first adopted a high-voltage Na_(3)(VOPO_(4))2F(NVOPF)cathode to verify its compatibility with the optimized NZSP-Mg_(0.15) SSE.By comparing the electrochemical performance of cells with different configurations(low-voltage cathode vs high-voltage cathode,liquid electrolytes vs SSEs),along with an X-ray photoelectron spectroscopy evaluation of the after-cycled NZSP-Mg_(0.15),it was demonstrated that the NASICON SSEs are not stable enough under high voltage,suggesting the importance of investigating the interface between the NASICON SSEs and high-voltage cathodes.Furthermore,by coating NZSP-Mg_(0.15) NASICON powder onto a polyethylene(PE)separator(PE@NASICON),a 2.42 A∙h non-aqueous Na-ion cell of carbon|PE@NASICON|NaNi_(2/9)Cu_(1/9)Fe_(1/3)Mn_(1/3)O_(2) was found to deliver an excellent cycling performance with an 88%capacity retention after 2000 cycles,thereby demonstrating the high reliability of SSEs with NASICON-coated separator. | Qiangqiang Zhang Quan Zhou Yaxiang Lu Yuanjun Shao Yuruo Qi Xingguo Qi Guiming Zhong Yong Yang Liquan Chen Yong-Sheng Hu | 2022 | Engineering2022，8，1： | 1 |
| 15 | Air Stability of Solid‑State Sulfide Batteries and Electrolytes显示文摘Sulfides have been widely acknowledged as one of the most promising solid electrolytes(SEs)for all-solid-state batteries(ASSBs)due to their superior ionic conductivity and favourable mechanical properties.However,the extremely poor air stability of sulfide SEs leads to destroyed structure/performance and release of toxic H_(2)S gas,which greatly limits mass-production/practical application of sulfide SEs and ASSBs.This review is designed to serve as an all-inclusive handbook for studying this critical issue.First,the research history and milestone breakthroughs of this field are reviewed,and this is followed by an in-depth elaboration of the theoretical paradigms that have been developed thus far,including the random network theory of glasses,hard and soft acids and bases(HSAB)theory,thermodynamic analysis and kinetics of interfacial reactions.Moreover,the characterization of air stability is reviewed from the perspectives of H2S generation,morphology evolution,mass change,component/structure variations and electrochemical performance.Furthermore,effective strategies for improving the air stabilities of sulfide SEs are highlighted,including H_(2)S absorbents,elemental substitution,design of new materials,surface engineering and sulfide-polymer composite electrolytes.Finally,future research directions are proposed for benign development of air stability for sulfide SEs and ASSBs. | Pushun Lu Dengxu Wu Liquan Chen Hong Li Fan Wu | 2022 | Electrochemical Energy Reviews2022，5，3： | 1 |
| 16 | Hunting Sodium Dendrites in NASICON-BasedSolid-State Electrolytes显示文摘NASICON-(Na superionic conductor-)based solid-state electrolytes(SSEs)are believed to be attracting candidates for solid-state sodium batteries due to their high ionic conductivity and prospectively reliable stability.However,the poor interface compatibility and the formation of Na dendrites inhibit their practical application.Herein,we directly observed the propagation of Na dendrites through NASICON-based Na3.1Zr2Si2.1P0.9O12 SSE for the first time.Moreover,a fluorinated amorphous carbon(FAC)interfacial layer on the ceramic surface was simply developed by in situ carbonization of PVDF to improve the compatibility between Na metal and SSEs.Surprisingly,Na dendrites were effectively suppressed due to the formation of NaF in the interface when molten Na metal contacts with the FAC layer.Benefiting from the optimized interface,both the Na||Na symmetric cells and Na3V2(PO4)3||Na solidstate sodium batteries deliver remarkably electrochemical stability.These results offer benign reference to the maturation of NASICON-based solid-state sodium batteries. | Qiangqiang Zhang Yaxiang Lu Weichang Guo Yuanjun Shao Lilu Liu Jiaze Lu Xiaohui Rong Xiaogang Han Hong Li Liquan Chen Yong-Sheng Hu | 2021 | Energy Material Advances2021，，1： | 1 |
| 17 | Influences of permeation of vanadium ions through PVDF-g-PSSA membranes on performances of vanadium redox flow batteries显示文摘 | Luo Xuanli Lu Zhengzhong Xi Jingyu Wu Zenghua Zhu Wentao Chen Liquan Qiu Xinping | 2005 | The Journal of Physical Chemistry B2005，109，20： | 1 |
| 18 | A new Tin-based O3-Na_(0.9)[Ni_(0.45-x/2)Mn_xSn_(0.55-x/2)]O_2 as sodium-ion battery cathode显示文摘Recently,sodium-ion batteries(SIBs),regarded as promising supplements for lithium-ion batteries(LIBs),especially in the large-scale energy storage field,are attracting more and more attention.However,the limited suitable cathode materials hinder the wide commercialization of SIBs.Given this aspect,in this work,a new layered oxide with 4d metal Tin was synthesized and investigated as cathode material for SIBs.Two optimized sodium-deficient O3-Na_(0.9)Ni_(0.45)Sn_(0.55)O_2and O3-Na_(0.9)Ni_(0.4)Mn_(0.1)Sn_(0.5)O_2were selected for comprehensive investigation,both of which exhibited high operating voltage of around 3.45 V with smooth charge/discharge curves.In comparison,O3-Na_(0.9)Ni_(0.4)Mn_(0.1)Sn_(0.5)O_2shows a higher reversible capacity(65 m A h/g,0.1 C),better rate capability and cycling stability than that of O3-Na_(0.9)Ni_(0.45)Sn_(0.55)O_2(50 mA h/g,0.1 C),indicating that a small amount of Mn-substitution can improve the electrochemical performance.This work presents a new possibility of discovering potential cathode candidates by exploring the Tin-based layered oxides. | Xiaohui Rong Xingguo Qi Yaxiang Lu Yuesheng Wang Yunming Li Liwei Jiang Kai Yang Fei Gao Xuejie Huang Liquan Chen Yong-Sheng Hu | 2019 | Journal of Energy Chemistry2019，28，4： | 0 |
| 19 | A One-Time Pad Encryption Scheme Based on Efficient Physical-Layer Secret Key Generation for Intelligent IoT System显示文摘The one-time pad(OTP)is an applicationlayer encryption technique to achieve the informationtheoretic security,and the physical-layer secret key generation(SKG)technique is a promising candidate to provide the random keys for OTP.In this paper,we propose a joint SKG and OTP encryption scheme with the aid of a reconfigurable intelligent surface(RIS)to boost secret key rate.To maximize the efficiency of secure communication,we divide the process of secure transmission into two stages:SKG and then encrypted packet transmission.Meanwhile,we design an optimal algorithm for allocating time slots for SKG to maximize SKG efficiency without security risk.Furthermore,we design a key updating protocol based on our SKG scheme for OTP encryption.Simulation results verify that our scheme can generate keys securely and efficiently,and significantly improve the secure communication performance in an intelligent IoT system. | Liquan Chen Kailin Cao Tianyu Lu Yi Lu Aiqun Hu | 2022 | China Communications2022，19，7： | 0 |
| 20 | Triple effects of Sn-substitution on Na0.67Ni0.33Mn0.67O2显示文摘Layered oxides are one of the most prom ising cathode materials for sodium ion batteries (NIBs), however, the relatively low working voltage hinders the increase of energy density thus limiting the application scenarios of NIBs. Here we prepared and investigated a series of Sn^4+ substituted NaO.67NiO.33M na67-xSnxO2 (x = 0.10, 0.20, 0.30, 0.33) and found that Sn-substitution can induce three effects: promoting O3-stack formation, sm oothing the voltage profile and increasing the working voltage to -3.6 V. This study would enrich the knowledge of Sn-substitution and give guide to the better design of high-voltage cathode materials for NIBs. | Xiaohui Rong Fei Gao Feixiang Ding Yaxiang Lu Kai Yang Hong Li Xuejie Huang Liquan Chen Yong-Sheng Hu | 2019 | Journal of Materials Science & Technology2019，35，7： | 0 |
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