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| 1 | 二氧化硅担载Preyssler杂多酸上苯和1-癸烯的烷基化反应:利用表面响应方法进行统计设计(英文)显示文摘The response surface method (RSM) was applied to study the liquid phase alkylation of benzene with 1-decene catalyzed by means of silica supported Preyssler heteropoly acid. A three step experimental design was developed based on the central composite design (CCD). Catalyst loading, catalyst mass percent, and benzene to 1-decene molar ratio were used to optimize 1-decene conversion and linear alkylbenzene (LAB) yield. The results indicated that the quadratic model was significant for these two responses. The experimental results revealed that all variables had positive effect on 1-decene conversion. While increasing the catalyst loading tends to decrease LAB yield. Benzene to 1-decene molar ratio was found to be the most important factor that influenced LAB yield with a positive effect. Design expert software suggested several optimized solutions, among them the best choice was to use 31% catalyst loading, benzene to 1-decene molar ratio of 13, and catalyst percent of 3.6 wt% for obtaining 100% conversion and 88% LAB production yield. | A. HAFIZI A. AHMADPOUP M. M. HERAVI F. F. BAMOHARRAM M. KHOSROSHAHI | 2012 | 催化学报2012,33,3: | 6 |
| 2 | 纳米SiO_2负载Preyssler杂多酸催化剂对水杨酸与苄醇或脂肪醇酯化反应的催化性能(英文)显示文摘An efficient and environmentally benign procedure for the catalytic esterification of salicylic acid with aliphatic alcohols, CnH2n+1OH(n=1-5)and benzylic alcohols,RC6H4CH2OH(R=H,NO2,OCH3,Br,Cl,Me)was developed using nano-SiO2-supported Preyssler heteropolyacid both under thermal conditions and microwave irradiation.Silica nanostructures were obtained through a sol-gel method and were characterized by transmission electron microscopy and powder X-ray diffraction.The effects of various parameters such as solvent type,molar ratio of substrates,Preyssler heteropolyacid loading on silica,catalyst amount,temperature,and reaction time were studied and the optimum conditions were obtained.It has been found that the catalyst with 30 wt%loading is highly active and shows high yields in esterification reactions.The use of nano-SiO2-supported Preyssler heteropolyacid coupled with microwave irradiation allows a solvent-free,rapid(3 min),and high-yielding reaction.This catalyst can be easily recovered and reused for many times without a significant loss in its activity. | Fatemeh F. BAMOHARRAM Majid M. HERAVI Javad EBRAHIMI Ali AHMADPOUR Mojtaba ZEBARJAD | 2011 | 催化学报2011,32,5: | 6 |
| 3 | Morpholine Catalyzed One-pot Multicomponent Synthesis of Compounds Containing Chromene Core in Water显示文摘一系列 dihydropyrano [c ] chromene 在 morpholine 催化,,的水里经由醛, malononitrile 和 4-hydroxycoumarin 的冷凝作用被获得一个壶反应。我们的调查结果的意义联系到减少器官的溶剂,潜在地有毒、危险的材料,以及它的简洁的使用,好收益,温和条件,和更低的费用。 | Heravi, Majid M. Zakeri, Masoumeh Mohammadi, Narges | 2011 | Chinese Journal of Chemistry2011,29,6: | 5 |
| 4 | 查看详情显示文摘 | Oskooie H. A Heravi M. M Tahershamsi L Sadjadi S Ta- jbakhsh M | | 0,,: | 1 |
| 5 | Regioselective and high-yielding bromination of aromatic compounds using hexamethylenetetramine–bromine显示文摘 | Majid M. Heravi Nafiseh Abdolhosseini Hossein A. Oskooie | 2005 | Tetrahedron Letters2005,,51: | 1 |
| 6 | 查看详情显示文摘 | Heravi M. M Bakhtiri K Javadi N. M Bamoharram F.F Saeedi M Oskooi H.A | | 0,,: | 1 |
| 7 | N-Methylpiperidinium Chlorochromate Adsorbed on Alumina: A New Deoximation Reagent显示文摘 | Mahmood Tajbakhsh Majid M. Heravi Farajollah Mohanazadeh Siavosh Sarabi Mitra Ghassemzadeh | 2001 | Monatshefte fuer Chemie / Chemical Monthly2001,,10: | 1 |
| 8 | 查看详情显示文摘 | Heravi M. M Derikvand F Bamoharram F. F | | 0,,: | 1 |
| 9 | A three component one-pot procedure for the synthesis of [1,2,4]triazolo/benzimidazolo-quinazolinone derivatives in the presence of H6P2W18O62?·?18H2O as a green and reusable catalyst显示文摘 | Majid M. Heravi Leila Ranjbar Fatemeh Derikvand Behnoush Alimadadi Hossien A. Oskooie Fatemeh F. Bamoharram | 2008 | Molecular Diversity (-)2008,,3: | 1 |
| 10 | Three-component one-pot synthesis of 4,6-diarylpyrimidin- 2(1H)-ones under solvent-free conditions in the presence of sulfamic acid as a green and reusable catalyst显示文摘 | Majid M. Heravi Leila Ranjbar Fatemeh Derikvand Behnoush Alimadadi | 2008 | Molecular Diversity (-)2008,,3: | 1 |
| 11 | One-pot Green Procedure for Synthesis of Tetrahydrobenzo[a]- xanthene-11-one Catalyzed by Bronsted Ionic Liquids under Solvent-free Conditions显示文摘 | Zakeri, Masoumeh Heravi, Majid M. Saeedi, Mina Karimi, Narges Oskooie, Hossein A. Tavakoli-Hoseini, Niloofar | 2011 | Chinese Journal of Chemistry2011,29,7: | 0 |