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| 1 | Sample maturation calculated using Raman spectroscopic parameters for solid organics: Methodology and geological applications显示文摘The shape and shift of Raman peak of solid organics prove to be capable of revealing atomic and molecular level vibration information of aromatic ring structure and its relationship with sample maturation. Raman 'D' peaks and 'G' peaks of a series of continuously maturated coal samples were measured, and the inter-peak intervals (G-D) and peak height ratios (Dh/Gh) were derived and correlated with the vitrinite reflectance (vRo%) of standard coal samples. As a result, two formulae were established by using the two Raman indices for calculation of Raman reflectance (RmcRo%), which is equivalent to vitrinite reflectance. The formula for calculating Raman reflectance indicative of organic maturation using Raman shift inter-peak interval (G-D) is RmcRo%=0.0537d(G-D)-11.21, which is mainly applicable to matured to highly matured carbonized samples of solid organics; The formula for calculating Raman reflectance indicative of organic maturation using Raman peak height ratio (Dh/Gh) is RmcRo%=1.1659h (Dh/Gh)+2.7588, which is mainly applicable to carbonized samples of solid organics that are over matured or going to be turned into granulated graphite. Preliminary applications indicate that Raman reflectance 'RmcRo%' calculated based on results of Raman spectral analysis of solid organics can be used to characterize sample maturation at molecular level, so enjoying extensive prospects in geological applications. | LIU DeHan XIAO XianMing TIAN Hui MIN YuShun ZHOU Qin CHENG Peng SHEN JiaGui | 2013 | Chinese Science Bulletin2013，58，11： | 30 |
| 2 | Sorption and desorption of 1,4-dichlorobenzene on peat显示文摘Sorption and desorption of 1,4-dichlorobenzene (DCB) on peat (>92% organic matter) display large-scale hysteresis and nonlinearity. The magnitude of desorption hysteresis decreases in the order: untreated Pahokee peat (P)> acid treated peat (FP)> humin (TP). The desorption percentages are lower than 28% of the sorbed 1, 4-DCB after desorbing for 6 days. The sorption and desorption isotherms are well fitted to Freundlich equation, whose parameter 1/n ranges from 0.055 to 0.527. Moreover, the parameter 1/n of the desorption isotherm is significantly lower than that of the sorption isotherm, but the parameter logK increases on contrary to 1/n. The desorption isotherms are very well fitted to Langmuir equation, whose Qm decreases in the order: TP>FP> P. The apparent partition coefficients (Kp) increase with increasing sorption time or decreasing aqueous equilibrium concentration of DCB. And Kp of P is significantly higher than that of FP or TP. | RAN Yong LIN Zheng WANG Xili MIN Yushun SHENG Guoying FU Jiamo | 2000 | Chinese Science Bulletin2000，45，S1： | 1 |
| 3 | Time trend of BHCs and DDTs in a sedimentary core in Macao Estuary,Southern China显示文摘 | Zhang Gan Min Yushun Mai Bixian | 1999 | Mar Pollut Bull1999，39，： | 1 |
| 4 | High-resolution sedimentary records of heavy metals in Guangzhou section of the Pearl River, South China显示文摘The sedimentary feature and variation of heavy metals in ca. 100 years, especially in the last three decades, in the riverbed of Guangzhou section of the Pearl River were revealed by the sedimentary heavy metal fluxes and total organic carbon (TOC) in a 210Pb-dated sedimentary core. It is suggested that the historical changes of heavy metal contamination can be recorded by pollutant sedimentary fluxes rather than by their concentrations. The heavy metal contamination in the river section was divided into 6 sedimentary historical stages of 3 groups, which correspond to the economic development and regional urbanization process. | MIN Yushun QI Shihua ZHANG Gan | 2000 | Chinese Science Bulletin2000，45，S1： | 1 |
| 5 | Time trend of BHCs and DDTs in a sedimentary core in macao estuary, southern china 显示文摘 | Zhang Gan Min Yushun Mai Bixian | 1999 | Marine Pollution Bulletin1999，39，： | 1 |
| 6 | Characteristics and possible origins of atmospheric monoterpenes from nonliving plants in Guangzhou显示文摘Monoterpenes in ambient air were determined in various sites in Guangzhou, and it was revealed that monoterpene concentrations in some special sites, like landfills, were even higher than those in locations with much more vegetation. On the average, monoterpene contents in samples from streets and highways were 1.9 μg/m3; from gardens, plantations and wooded lands, 2.2 μg/m3; from farmlands, 1.5 μg/m3; but from landfills, 4.1 μg/m3. So other sources like landfills, apart from living plants, might also contribute to the biogenic non-methane hydrocarbons (NMHCs) in the atmospheric environment. On the other hand, the composition pattern of monoterpenes in air samples from landfills were obviously different compared with those from living plants, this might result from the different synthesis pathways of monoterpenes, the oxygen-depleted environment and the microbiogenic process might affect the synthesis in landfills. | Xinming Wang Guoying Sheng Jiamo Fu Yushun Min Ping’an Peng | 1999 | Chinese Science Bulletin1999，44，8： | 1 |
| 7 | Time trend of BHCs and DDTs in a sedimentary core in Macao Estuary, Southern China显示文摘 | Zhang Gan Min Yushun Mai Bixian | 1999 | Marine Pollution Bulletin1999，39，： | 1 |
| 8 | Organochlorinated Compounds in Waters of the Pearl River Delta Region显示文摘 | Yang Yanhong Sheng Guoying Fu Jimo Min Yushun | 1997 | Environmental Monitoring and Assessment (-)1997，，1： | 1 |
| 9 | Inclusion Complex of Podophyllotoxin with y-Cyclodextrin Preparation, Characterization, Anticancer Activity, Water-Solubility and Toxicity显示文摘有 γ-cyclodextrin (γ-CD ) 的 podophyllotoxin (PPT ) 的包括建筑群被准备。包括建筑群的行为,描述,和水溶解度小心地经由荧光光谱学, thermogravimetry,微分扫描热量测定, X 光检查衍射分析,和 1 H 和 2D 原子磁性的回声光谱学。而且,到在老鼠的人的癌症线和毒性的 antitumor 活动被学习。结果证明包括建筑群与可观的明显的稳定性常数 K s (4245.5 L·mol −1) 。水溶解度更加被改进。另外,包括建筑群的 anticancer 活动比 cis 铂的好(DDP,积极控制) 。最重要地, podophyllotoxin 包括建筑群的毒性把更多的安全归结并且变得为将是大贵重物品作为一种 antitumor 药研究它的应用到人在的老鼠进一步。 | Yafei Guo Yushun Zhang Jiuling Li Fen Zhao Yang Liu Min Su Yubo Jiang Yuqi Liu Jihong Zhang Bo Yang Rui Yang | 2016 | Chinese Journal of Chemistry2016，34，4： | 0 |
| 10 | Determination of linear alkylbenzenesulfonates in modern sediments from core Zhu-9 and its significance显示文摘High performance liquid chromatography (HPLC) has the advantages of rapid analysis and high sensitivity. In the present study a suitable analytical condition has been established for HPLC, and the LAS in modern sediments from core Zhu-9 at the Pearl River mouth has been determined by HPLC. The concentrations of C12-LAS homologues are the highest. The sedimentation flux of C12-LAS was correlated with the average flow of the Xijiang and Beijiang rivers: the higher the flow rate, the larger the C12-LAS sedimentation flux. This shows that the more rapidly the river flows, the shorter the LAS will stay in freshwater, the less the extent of biodegradation, the larger the C12-LAS sedimentation flux in the core Zhu-9. | Jianfang Hu Ping’an Peng Yushun Min Guoying Sheng Jiamo Fu | 2000 | Chinese Science Bulletin2000，45，S1： | 0 |
| 11 | High-resolution sedimentary record of hydrocarbon contaminants in a core from the major reaches of the Pearl River, China显示文摘The concentrations and compositions of hydrocarbon contaminants, and molecular marker indices in modern sediments from a core in the major reaches of the Pearl River were investigated. The sedimentary record of hydrocarbons in the core, in combination with 210Pb-dating, was used to reconstruct the pollution history of hydrocarbon pollutants in the Pearl River in the past 100 years. | MAI Bixian SHENG Guoying LIN Zheng ZHANG Gan MIN Yushun FU Jiamo | 2000 | Chinese Science Bulletin2000，45，S1： | 0 |
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