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| 1 | ANIONIC SYNTHESIS OF A “CLICKABLE” MIDDLE-CHAIN AZIDE-FUNCTIONALIZED POLYSTYRENE AND ITS APPLICATION IN SHAPE AMPHIPHILES显示文摘'Click chemistry' is, by definition, a general functionalization methodology (GFM) and its marriage with living anionic polymerization is particularly powerful in precise macromolecular synthesis. This paper reports the synthesis of a 'clickable' middle-chain azide-functionalized polystyrene (mPS-N3 ) by anionic polymerization and its application in the preparation of novel shape amphiphiles based on polyhedral oligomeric silsesquioxane (POSS). The mPS-N3 was synthesized by coupling living poly(styryl)lithium chains (PSLi) with 3-chloropropylmethyldichlorosilane and subsequent nucleophilic substitution of the chloro group in the presence of sodium azide. Excess PSLi was end-capped with ethylene oxide to facilitate its removal by flash chromatography. The mPS-N3 was then derived into a giant lipid-like shape amphiphile in two steps following a sequential 'click' strategy. The copper(I)-catalyzed azide-alkyne cycloaddition between mPS-N3 and alkyne-functionalized vinyl-substituted POSS derivative (VPOSS-alkyne) ensured quantitative ligation to give polystyrene with VPOSS tethered at the middle of the chain (mPS-VPOSS). The thiol-ene reaction with 1-thioglycerol transforms the vinyl groups on the POSS periphery to hydroxyls, resulting in an amphiphilic shape amphiphile, mPS-DPOSS. This synthetic approach is highly efficient and modular. It demonstrates the 'click' philosophy of facile complex molecule construction from a library of simple building blocks and also suggests that mPS-N3 can be used as a versatile 'clickable' motif in polymer science for the precise synthesis of complex macromolecules. | Kan Yue Jinlin He Chang Liu Mingjun Huang Xue-Hui Dong Kai Guo Peihong Ni Chrys Wesdemiotis Roderic P. Quirk Stephen Z. D. Cheng Wen-Bin Zhang | 2013 | Chinese Journal of Polymer Science2013，31，1： | 1 |
| 2 | A numerical study of segmented cooling-stream injection in supersonic film cooling显示文摘The present study proposes a segmented cooling-stream injection structure based on a certain coolant mass flow rate,and numerically investigates the effect of segmented cooling-stream injection on supersonic film cooling.The results indicate that without shock-wave impingement and with helium as the coolant,segmented cooling-stream injection can reduce the mixing between the mainstream and the cooling stream to produce better cooling performance than single injection,especially at larger coolant Mach numbers.However,with nitrogen as the coolant,the cooling effect of the segmented-injection system is very close to that of the single-injection system.Mixing at the impinging region is enhanced significantly when there is an incident shock wave.When the shock wave impinges between the two coolant inlets,segmented cooling-stream injection improves film cooling effectiveness in the midstream and downstream regions more than single injection because only part of the cooling stream undergoes the enhanced mixing effect of the shock wave.The advantage of segmented injection is reduced when the impinging region is behind the second coolant inlet.The further downstream the impinging region,the smaller the associated advantage. | Hang NI Mingjun WANG Peixue JIANG Wei PENG Yinhai ZHU | 2022 | Chinese Journal of Aeronautics2022，35，6： | 1 |
| 3 | Short-term serum deprivation causes no significant mitochondrial DNA mutation in vascular smooth muscle cells revealed by a new next generation sequencing technology显示文摘线粒体提供许多精力因为在线粒体的房间和混乱能几乎影响任何织物[1 ] 。mitochondrial DNA (mtDNA ) 盖住 16,569 bp,由在人的 37 基因和 1 个 D 环区域组成。线粒体在拥有他们被采用 multiprotein 机械组织成 mitochondrial nucleoids 的自己的染色体是唯一的,并且能执行基因复制,抄写,和修理的功能[2 ] 。尽管它让几乎所有已知的原子 DNA 修理小径,保护的 histones 的缺乏可以导致特别危险性到压力和 DNA 损坏事件[3 ] 。确实, mtDNA 让一个很高的变化评价[4 ] 。自从它的发现, mtDNA 变化被知道了普通并且包括糖尿病,心血管的疾病,癌症,神经与肌的混乱,和老化作为人的疾病的一个重要原因出现了,在 4300 人口影响 1 [5,6 ] 。因此,在压力和疾病识别 mtDNA 变化现在是一个热研究区域。 | Xiangqi Li Lianyong Liu Qian Xi Xuemei Zhao iingshuang Fang Junhua Ma ZhaohuiZhu Xing Wang Chao Shi Jingnan Wang Hongling Zhu Jichen Zhang Chaobao Zhang Shuanggang Hu Minjie Ni Mingjun Gu | 2016 | Acta Biochimica et Biophysica Sinica2016，48，9： | 0 |
| 4 | High-speed train cooperativecontrol based on fractional-ordersliding mode adaptive algorithm显示文摘Purpose–This study aims to propose an adaptive fractional-order sliding mode controller to solve the problem of train speed tracking control and position interval control under disturbance environment in moving block system,so as to improve the tracking efficiency and collision avoidance performance.Design/methodology/approach–The mathematical model of information interaction between trains is established based on algebraic graph theory,so that the train can obtain the state information of adjacent trains,and then realize the distributed cooperative control of each train.In the controller design,the sliding mode control and fractional calculus are combined to avoid the discontinuous switching phenomenon,so as to suppress the chattering of sliding mode control,and a parameter adaptive law is constructed to approximate the time-varying operating resistance coefficient.Findings–The simulation results show that compared with proportional integral derivative(PID)control and ordinary sliding mode control,the control accuracy of the proposed algorithm in terms of speed is,respectively,improved by 25%and 75%.The error frequency and fluctuation range of the proposed algorithm are reduced in the position error control,the error value tends to 0,and the operation trend tends to be consistent.Therefore,the control method can improve the control accuracy of the system and prove that it has strong immunity.Originality/value–The algorithm can reduce the influence of external interference in the actual operating environment,realize efficient and stable tracking of trains,and ensure the safety of train control. | Junting Lin Mingjun Ni Huadian Liang | 2023 | Railway Sciences2023，2，1： | 0 |
| 5 | Thin-interbedded reservoirs prediction based on seismic sedimentology显示文摘Interference of thin-interbedded layers in seismic reflections has great negative impact on thin-interbedded reservoirs prediction.To deal with this,two novel methods are proposed that can predict the thin-interbedded reservoirs distribution through strata slices by suppressing the interference of adjacent layer with the help of seismic sedimentology.The plane distribution of single sand bodies in thin-interbedded reservoirs can be clarified.(1)The minimum interference frequency slicing method,uses the amplitude-frequency attribute estimated by wavelet transform to find a constant seismic frequency with the minimum influence on the stratal slice of target layer,and then an optimal slice corresponding the constant frequency mentioned above can be obtained.(2)The superimposed slicing method can calculate multiple interference coefficients of reservoir and adjacent layers of target geological body,and obtain superimposed slice by weighted stacking the multiple stratal slices of neighboring layers and target layer.The two proposed methods were used to predict the distribution of the target oil layers of 6 m thick in three sets of thin-interbedded reservoirs of Triassic Kelamayi Formation in the Fengnan area of Junggar Basin,Northwestern China.A comparison with drilling data and conventional stratal slices shows that the two methods can predict the distribution of single sand bodies in thin-interbedded reservoirs more accurately. | NI Changkuan SU Mingjun YUAN Cheng LIU Huaqing CUI Xiangli | 2022 | Petroleum Exploration and Development2022，49，4： | 0 |
| 6 | Safety Evaluation of Tongchui Baihua Capsule显示文摘[Objectives]The study aimed to evaluate the safety of Tongchui Baihua capsule.[Methods]Long-term toxicology experiment was adopted,the rats were randomly divided into control group and administration group according to the gender of male and female;the drug administration group was given different doses of Tongchui Baihua capsules,and the drug was administered by continuous gavage for 13 weeks;the general conditions,haematological indexes,blood biochemical indexes and visceral coefficients of the rats were detected at the 13th week and 4 weeks after the drug withdrawal respectively,and the toxic symptoms were observed.[Results]The rats were given Tongchui Baihua capsule in different doses by gavage for 13 weeks,and no obvious toxicity was observed in weight,haematological indexes,blood biochemical indexes and histopathology.[Conclusions]Under the condition of long-term toxicity experiment,Tongchui Baihua capsule was safe for rats. | Kaicong FU Mingjun CUI Jian LUO Lihong FU Kai NI Min GAO | 2020 | Medicinal Plant2020，11，6： | 0 |
| 7 | Normalization of Indexed Differentials by Extending Grobner Basis Theory显示文摘It is a fundamental problem to determine the equivalence of indexed differential polynomials in both computer algebra and differential geometry.However,in the literature,there are no general computational theories for this problem.The main reasons are that the ideal generated by the basic syzygies cannot be finitely generated,and it involves eliminations of dummy indices and functions.This paper solves the problem by extending Grobner basis theory.The authors first present a division of the set of elementary indexed differential monomials E■ into disjoint subsets,by defining an equivalence relation on E■ based on Leibniz expansions of monomials.The equivalence relation on E■also induces a division of a Grobner basis of basic syzygies into disjoint subsets.Furthermore,the authors prove that the dummy index numbers of the sim-monomials of the elements in each equivalence class of E■ have upper bounds,and use the upper bounds to construct fundamental restricted rings.Finally,the canonical form of an indexed differential polynomial proves to be the normal form with respect to a subset of the Grobner basis in the fundamental restricted ring. | LIU Jiang NI Feng SONG Shihang DU Mingjun | 2022 | Journal of Systems Science & Complexity2022，35，5： | 0 |
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