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3篇 您的检索式:作者名="Mingyou Hu"
    题名 作者 年代 出处 被引量
1Copper-Mediated Deuterotrifluoromethylation of α-Diazo Esters显示文摘α 的调停铜的 deuterotrifluoromethylation ? 在重氢氧化物的提升下面的重氮基的酉旨(D 2 O ) 为标记重氢的 trifluoromethyl 混合物的合成被开发了。这 deuterotrifluoromethylation 反应具有宽广范围并且能负担得起 deuterated 产品与比 99% 同位素的纯净高。而且,这调查的结果也提供一些试验性的证据支持我们的以前建议的 trifluoromethylation 机制。Mingyou Hu Qiqiang Xie Xinjin Li Chuanfa Ni Jinbo Hu 2016Chinese Journal of Chemistry2016,34,5:0
2Water-promoted regio-selective trifluoromethylation of vinyl conjugated diazoacetates显示文摘An efficient trifluoromethylation reaction of vinyldiazoacetates under mild reaction conditions was depicted.Pre-generated CuCF_(3) was used as a trifluoromethylation reagent and water acted as both a promoter and proton source.The reaction is compatible with a broad scope of functional groups and easy to scale-up.The wide functional group tolerance of the reaction enables further synthetic manipulation of the products.Xinxin Han Xin Liu Yueyun Bao Hunahuan Song Yu-Rou Zhao Xiaoying Wang Junjie Zhang Le Liu Xin-Hua Duan Jinbo Hu Mingyou Hu 2022Organic Chemistry Frontiers2022,9,1:0
3Oxidative thiocyanation of allylic alcohols:an easy access to allylic thiocyanates with K_(2)S_(2)O_(8) and NH_(4)SCN显示文摘A practical method for the synthesis of allylic thioacyanates from allylic alcohols was disclosed employing K_(2)S_(2)O_(8) as the oxidant and NH_(4)SCN as the thiocyanate source.Without introducing a leaving group in advance,a series of disubstituted and monosubstituted allylic thiocyanate compounds were obtained in moderate to good yields.This transition metal-free method features mild reaction conditions,broad sub-strate scope and operational simplicity.The potential application of this method was demonstrated by some derivatization reactions of the product and mechanistic investigation indicated that a radical process is involved.Keyuan Zhang Tianbing Liang Yulong Wang Chonglong He Mingyou Hu Xin-Hua Duan Le Liu 2022Organic Chemistry Frontiers2022,9,4:0
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