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	题名	作者	年代	出处	被引量
1	Systematic variation of the sodium/sulfur promoter content on carbon-supported iron catalysts for the Fischer–Tropsch to olefins reaction显示文摘The Fischer–Tropsch to olefins(FTO) process is a method for the direct conversion of synthesis gas to lower C_2–C_4olefins. Carbon-supported iron carbide nanoparticles are attractive catalysts for this reaction.The catalytic activity can be improved and undesired formation of alkanes can be suppressed by the addition of sodium and sulfur as promoters but the influence of their content and ratio remains poorly understood and the promoted catalysts often suffer from rapid deactivation due to particle growth. A series of carbon black-supported iron catalysts with similar iron content and nominal sodium/sulfur loadings of 1–30/0.5–5 wt% with respect to iron are prepared and characterized under FTO conditions at 1and 10 bar syngas pressure to illuminate the influence of the promoter level on the catalytic properties.Iron particles and promoters undergo significant reorganization during FTO operation under industrially relevant conditions. Low sodium content(1–3 wt%) leads to a delay in iron carbide formation. Sodium contents of 15–30 wt% lead to rapid loss of catalytic activity due to the covering of the iron surface with promoters during particle growth under FTO operation. Higher activity and slower loss of activity are observed at low promoter contents(1–3 wt% sodium and 0.5–1 wt% sulfur) but a minimum amount of alkali is required to effectively suppress methane and C_2–C_4paraffin formation. A reference catalyst support(carbide-derived carbon aerogel) shows that the optimum promoter level depends on iron particle size and support pore structure.	Martin Oschatz Nynke Krans Jingxiu Xie Krijn P.de Jong	2016	Journal of Energy Chemistry2016，25，6：	2
2	Valsartan-induced improvement in insulin sensitivity is not paralleled by changes in microvascular function in individuals with impaired glucose metabolism显示文摘	Nynke J. van der Zijl Erik H. Serné Gijs H. Goossens Chantalle C.M. Moors Richard G. IJzerman Ellen E. Blaak Michaela Diamant	2011	Journal of Hypertension2011，，10：	1
3	Impairedactivity of the bile canalicular organic anion transporter is not the main cause of Ethirylestradiol-induced cholestasis in the rat显示文摘	Koopen Henk	1998	Hepatology1998，27，：	1
4	Longitudinal brain volume m easurement in multiple sclerosis : rate of brain atrophy is independent of the disease subtype显示文摘	Nynke F Kalkers N Ameziane J	2002	Arch Neurol2002，59，10：	1
5	Linking warehouse complexity to warehouse planning and control structure显示文摘	Nynke Faber Rene(Marinus) B M de koster SteefL van de Velde	2002	International Journal of Physical Distribution & Logistics Management2002，32，5：	1
6	Valsartan-induced improvement in insulin sensitivity is not paralleled by changes in microvascular function in individuals with impaired glucose metabolism显示文摘	Nynke J. van der Zijl Erik H. Serné Gijs H. Goossens Chantalle C.M. Moors Richard G. IJzerman Ellen E. Blaak Michaela Diamant	2011	Journal of Hypertension2011，，10：	1
7	Linking warehouse complexity to warehouse planning and control structure显示文摘	Nynke Faber Rene(Marinus) B M de koster SteefL van de Velde	2002	International Journal of Physical Distribution & Logistics Management2002，32，5：	1
8	Immunodiagnosis of Taenia solium taeniosis/cysticercosis显示文摘	Nynke Deckers Pierre Dorny	2010	Trends in Parasitology2010，，3：	1
9	Anemfa in pregnancy in developing countries显示文摘	Nynke	1998	Br J Obestet Gnecol1998，105，：	1
10	S -Adenosylhomocysteine induces apoptosis and phosphatidylserine exposure in endothelial cells independent of homocysteine显示文摘	Jessica A. Sipkens Nynke E. Hahn Henk J. Blom Sinéad M. Lougheed Coen D.A. Stehouwer Jan A. Rauwerda Paul A.J. Krijnen Victor W.M. van Hinsbergh Hans W.M. Niessen	2011	Atherosclerosis2011，，1：	1
11	Longitudinal brain volume measurement in multiple sclerosis:rate of brain atrophy is independent of the disease subtype显示文摘	Nynke F Kalkers N Ameziane J	2002	Arch Neurol2002，59，10：	1
12	Trimestral varia- tions of C-reactive protein,interleukin-6 and tumour necrosis factor-α are similarly associated with survival in haemodialysis patients 显示文摘	Meuwese CL Sunna S Nynke H	2011	Nephrology Dialysis Trans- plantation2011，26，4：	1
13	S-Adenosyl homocysteine induces apoptosis and phosphtidy 显示文摘	JESSICA A SIPKENSA H NYNKE E	2011	Atheroselerosis2011，221，：	1
14	De- sign for Socially Responsible Behavior:A Classification of Influence Based on Intended User Experience显示文摘	Nynke Tromp Paul Hekkert Peter-Paul Verbeek	2011	Mas- sachusetts Institute of Technology2011，27，3：	1
15	Effectiveness of exercise therapy: A best-evidence summary of systematic reviews显示文摘	Nynke Smidt Henrica C.W. de Vet Lex M. Bouter Joost Dekker	2005	Australian Journal of Physiotherapy2005，，2：	1
16	Yield of Molecular and Clinical Testing for Arrhythmia Syndromes: Report of 15 Years’ Experience显示文摘	Nynke Hofman Hanno L. Tan Mari?lle Alders Iris Kolder Simone de Haij Marcel M.A.M. Mannens Maria Paola Lombardi Ronald H. Lekanne dit Deprez Irene van Langen Arthur A.M. Wilde	2013	Circulation2013，，14：	1
17	Dispersions of rhodamine-labeled silica spheres:Synthesis,characterization,and fluorescence confocal scanning laser microscopy显示文摘	Nynke A M Verhaegh van Blaaderen Alfons	1994	Langmuir1994，10，5：	1
18	Hemodynamic effects of leg crossing and skeletal muscle tensing during free standing in patients with vasovagal syncope显示文摘	Nynke van Dijk Ivar GJM de Bruin Janneke Gisolf	2005	J Appl Physiol2005，98，2：	1
19	Modification of the fluorescein diacetate assay for screening of antifungal agents against Candida albicans : Comparison with the NCCLS methods显示文摘	Nynke Brouwer James Kohen Joanne Jamie Subramanyam Vemulpad	2005	Journal of Microbiological Methods2005，，2：	1
20	Longitudinal brain volume measurement in multiple sclerosis:rate of brain atrophy is independent of the disease subtype显示文摘	Nynke F Kalkers Najim Ameziane	2002	Arch Neurol2002，59，10：	1

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