|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Au core-PtAu alloy shell nanowires for formic acid electrolysis显示文摘Inefficient electrocatalysts and high-power consumption are two thorny problems for electrochemical hydrogen(H2)production from acidic water electrolysis.Herein we report the one-pot precise synthesis of ultrafine Au core-Pt Au alloy shell nanowires(Au@PtxAu UFNWs).Among them,Au@Pt_(0.077) Au UFNWs exhibit the best performance for formic acid oxidation reaction(FAOR)and hydrogen evolution reaction(HER),which only require applied potentials of 0.29 V and-22.6 m V to achieve a current density of 10 m A cm^(-2),respectively.The corresponding formic acid electrolyzer realizes the electrochemical H2 production at a voltage of only 0.51 V with 10 m A cm^(-2) current density.Density functional theory(DFT)calculations reveal that the Au-riched Pt Au alloy structure can facilitates the direct oxidation pathway of FAOR and consequently elevates the FAOR activity of Au@Pt_(0.077) Au UFNWs.This work provides meaningful insights into the electrochemical H_(2) production from both the construction of advanced bifunctional electrocatalysts and the replacement of OER. | Qi Xue Xin-Yu Bai Yue Zhao Ya-Nan Li Tian-Jiao Wang Hui-Ying Sun Fu-Min Li Pei Chen Pujun Jin Shi-Bin Yin Yu Chen | 2022 | Journal of Energy Chemistry2022，31，2： | 5 |
| 2 | Tenofovir disoproxil fumarate therapy in patients with chronic hepatitis B and advanced fibrosis or compensated cirrhosis显示文摘Background and aims:Tenofovir disoproxil fumarate(TDF)is the first-line therapy for chronic hepatitis B.This interim analysis presents the efficacy and safety data for TDF at Week 144 in patients with chronic hepatitis B and advanced fibrosis or compensated cirrhosis from China.Methods:Patients were assessed for incidence of newly diagnosed hepatocellular carcinoma(HCC)and disease progression,liver stiffness measurement(LSM),virological suppression(serum hepatitis B virus DNA<20 IU/mL),alanine aminotransferase normalization,hepatitis B e antigen(HBeAg)loss and seroconversion,histological liver fibrosis score,and safety at Week 144.Results:Overall,197 patients were enrolled.At Week 144,the incidence of newly diagnosed HCC was observed in 2.1%patients,and the incidence of disease progression was observed in 3.6%patients.The mean(standard deviation)change in LSM from baseline was5.1(5.85)kPa.Serum hepatitis B virus DNA<20 IU/mL was observed in 94.1%patients,alanine aminotransferase normalization in 33.5%patients,HBeAg loss in 35.6%patients,and HBeAg seroconversion in 14.4%patients.Among patients with stage F3 or F4 fibrosis at baseline by LSM,38.3%patients regressed to stage F0/1,and 22.0%of patients regressed to stage F2 at Week 144.Overall,67.7%patients experienced≥1 adverse events,13.8%patients experienced TDF-related adverse events,and 16.4%patients experienced serious(none were TDF-related).Conclusions:At Week 144 of TDF treatment,low incidence of HCC and disease progression were reported.Virological suppression was observed in 94.1%patients,which was associated with fibrosis regression.No new safety events were identified. | Huiying Rao Jia Shang Qing Xie Jianqi Lian Pujun Gao Junping Shi Xinyue Chen Jiefei Wang Min Xu Liaoyun Zhang Yingren Zhao QingMao Maorong Wang Wei Zhao Zong Zhang Jidong Jia Hong Tang Jiming Zhang Xin Zheng Chang Liu Lai Wei | 2022 | iLIVER2022，1，3： | 1 |
| 3 | Effects of seasonal climatic variability on several toxic contaminants in urban lakes: Implications for the impacts of climate change显示文摘Climate change is supposed to have influences on water quality and ecosystem.However,only few studies have assessed the effect of climate change on environmental toxic contaminants in urban lakes.In this research,response of several toxic contaminants in twelve urban lakes in Beijing,China,to the seasonal variations in climatic factors was studied.Fluorides,volatile phenols,arsenic,selenium,and other water quality parameters were analyzed monthly from2009 to 2012.Multivariate statistical methods including principle component analysis,cluster analysis,and multiple regression analysis were performed to study the relationship between contaminants and climatic factors including temperature,precipitation,wind speed,and sunshine duration.Fluoride and arsenic concentrations in most urban lakes exhibited a significant positive correlation with temperature/precipitation,which is mainly caused by rainfall induced diffuse pollution.A negative correlation was observed between volatile phenols and temperature/precipitation,and this could be explained by their enhanced volatilization and biodegradation rates caused by higher temperature.Selenium did not show a significant response to climatic factor variations,which was attributed to low selenium contents in the lakes and soils.Moreover,the response degrees of contaminants to climatic variations differ among lakes with different contamination levels.On average,temperature/precipitation contributed to 8%,15%,and 12%of the variations in volatile phenols,arsenic,and fluorides,respectively.Beijing is undergoing increased temperature and heavy rainfall frequency during the past five decades.This study suggests that water quality related to fluoride and arsenic concentrations of most urban lakes in Beijing is becoming worse under this climate change trend. | Qiong Wu Xinghui Xia Xinli Mou Baotong Zhu Pujun Zhao Haiyang Dong | 2014 | Journal of Environmental Sciences2014，26，12： | 1 |
| 4 | One-dimensional Rhodium-nickel Alloy Assemblies with Nano-dendrite Subunits for Alkaline Methanol Oxidation显示文摘The noble metal rhodium(Rh)nanostructures have wide applications in catalysis and electrocatalysis.In this work,a series of Rh Ni alloy nanostructures with different Rh/Ni atomic ratios can be synthesized by one-step wet chemical method.By adjusting Rh^(Ⅲ)/Ni^(iⅡ)feed ratio,high-quality one-dimensional Rh_(1)Ni_(1)alloy nanodendrite assemblies(Rh_(1)Ni_(1)-NDs-As)can be synthesized selectively.Electrochemical measurements show that the introduction of Ni can enhance the electroactivity of Rh nanomaterials for methanol oxidation reaction(MOR)in alkaline media.For potential practical application,Rh_(1)Ni_(1)-NDs-As reveals improved electroactivity and durability for MOR compared to commercial Rh nanoparticle due to the particular morphology,Ni-doping,high electrochemical active area,and excellent anti-poison ability.Considering the facial synthesis and high electroactivity/durability,Rh_(1)Ni_(1)-NDs-As may be promising anode catalysts in direct methanol fuel cells. | Yue Zhao Yachong Liu Boqiang Miao Yu Ding Pujun Jin Yu Chen | 2022 | Chinese Journal of Structural Chemistry2022，41，4： | 1 |
| 5 | Tectonic Evolution and Key Geological Issues of the ProtoSouth China Sea显示文摘There are numerous controversies surrounding the tectonic properties and evolution of the Proto-South China Sea(PSCS).By combining data from previously published works with our geological and paleontological observations of the South China Sea(SCS),we propose that the PSCS should be analyzed within two separate contexts:its paleogeographic location and the history of its oceanic crust.With respect to its paleogeographic location,the tectonic properties of the PSCS vary widely from the Triassic to the mid-Late Cretaceous.In the Triassic,the Paleo-Tethys and the Paleo-Pacific Oceans were the major causes of tectonic changes in the SCS,while the PCSC may have been a remnant sea residing upon Tethys or Paleo-Pacific oceanic crust.In the Jurassic,the Meso-Tethys and the Paleo-Pacific oceans joined,creating a PSCS back-arc basin consisting of Meso-Tethys and/or Paleo-Pacific oceanic crust.From the Early Cretaceous to the midLate Cretaceous,the Paleo-Pacific Ocean was the main tectonic body affecting the SCS;the PSCS may have been a marginal sea or a back-arc basin with Paleo-Pacific oceanic crust.With respect to its oceanic crust,due to the subduction and retreat of the Paleo-Pacific plate in Southeast Asia at the end of the Late Cretaceous,the SCS probably produced new oceanic crust,which allowed the PSCS to formally emerge.At this time,the PSCS was most likely a combination of a new marginal sea and a remnant sea;its oceanic crust,which eventually subducted and became extinct,consisted of both new oceanic crust and remnant oceanic crust from the Paleo-Pacific Ocean.In the present day,the remnant PSCS oceanic crust is located in the southwestern Nansha Trough. | TIAN Zhiwen TANG Wu WANG Pujun ZHAO Zhigang SUN Xiaomeng TANG Huafeng | 2021 | Acta Geologica Sinica(English Edition)2021，95，1： | 1 |
| 6 | Characteristics of the Density and Magnetic Susceptibility of Rocks in Northern Borneo and their Constraints on the Lithologic Identification of the Mesozoic Rocks in the Southern South China Sea显示文摘Based on the volume magnetic susceptibility and specific gravity measurements and mineral and lithologic identification results for 540 samples,the rock type,density,and magnetic susceptibility of rocks from northern Borneo were analyzed,and the applicability of gravity and magnetic data to the lithologic identification of the Mesozoic strata in the southern South China Sea was assessed accordingly.The results show that there are 3 types and 25 subtypes of rocks in northern Borneo,mainly intermediate-mafic igneous rocks and exogenous clastic sedimentary rocks,with small amounts of endogenous sedimentary rocks,felsic igneous rocks,and metamorphic rocks.The rocks that are very strongly-strongly magnetic and have high-medium densities are mostly igneous rocks,tuffaceous sandstones,and their metamorphic equivalents.The rocks that are weakly magnetic-non-magnetic and have medium-very low densities are mostly conglomerates,sandstones,siltstones,mudstones,and coal.The rocks that are weakly magnetic-diamagnetic and have highmedium densities are mostly limestones and siliceous rocks.The Cenozoic rocks are characterized by low densities and medium susceptibilities;the Mesozoic rocks are characterized by medium densities and medium-high susceptibilities;and the pre-Mesozoic rocks are characterized by high densities and low magnetism.Based on these results and the distribution characteristics of the various rock types,it was found that the pre-Mesozoic rocks produce weak regional gravity anomalies;the Mesozoic sedimentary rocks produce negative regional gravity anomalies;whereas the Mesozoic igneous rocks produce positive regional gravity anomalies;and the Cenozoic igneous rocks produce positive regional gravity anomalies.The regional high magnetic anomalies in the southern part of the South China Sea originate from the Mesozoic mafic igneous rocks and their metamorphic equivalents;and the regional medium magnetic anomalies may be produced by the felsic igneous rocks and their metamorphic equivalents.Accordingly,the identification of the Mesozoic lithology in the southern South China Sea shows that the Mesozoic sedimentary rocks are distributed over a large area of the southern South China Sea.Thus,it is concluded that the Mesozoic strata in this area have the potential for oil and gas exploration. | TANG Huafeng ZHAO Zhigang TIAN Zhiwen LU Baoliang TANG Wu HE Kailun ZHU Chenxi WANG Pujun | 2021 | Acta Geologica Sinica(English Edition)2021，95，1： | 1 |
| 7 | U-Pb zircon ages and petrogeochemistry and tectonic implications of gabbro and granite in southwest Lahad Datu area of Sabah, Malaysia显示文摘The southwest Lahad Datu felsic rocks were previously thought to have formed in the late Triassic as part of the microcontinental crystalline basement.Based on U-Pb ages,geochemistry,and the Hfisotopes of zircon from the southeastern Sabah gabbro and granite,in this study,the tectonic properties of the Sabah area during the Triassic were investigated.The weighted average U-Pb zircon ages of the gabbro and granite samples were determined to be(230.9±2.5)Ma and(207.1±3.3)Ma,respectively.The granite had SiO_(2) contents of 66.54%-79.47%,low TiO_(2) contents of 0.08%-0.3%,Al_(2)O_(3) contents of 10.97%-16.22%,Na_(2)O contents of 5.91 %-6.39%,and low K_(2)O contents of 0.15%-0.65%.The chondrite-normalized rare earth element(REE) patterns exhibit light REE enrichment,with right-sloping curves.The primitive mantle-normalized trace element spider diagrams exhibit Th,U,La,Sr,and Zr enrichment and Nb,Ta,P and Ti depletions,i.e.,the geochemical characteristics of typical island arc igneous rocks.The tectonic discriminant diagram indicates that the granite is a volcanic arc granite.The Hf isotopic an alysis of gabbro zircon revealed that the zircons have ε_(Hf)(t)values of 12.08-16.24(mean of 14.32) and two-stage model ages(t_(DM2)) of 223-491 Ma(mean of 347 Ma).This indicates that the diagenetic magma of the gabbro was mainly derived from melting of newly formed crustal materials.The ophiolite in southeast Sabah has existed since the early Late Triassic.The crystalline basement granite in southeastern S abah was emplaced lasted from late Triassic to early Cretaceous.Based on previous studies and global plate reconstruction models,it is speculated that the southeastern Sabah granite may have been formed in an island arc setting,i.e.,where the oceanic crust of the Paleo-Tethys Ocean collided with the oceanic crust of the Panthalassa Ocean. | Zhigang Zhao Wu Tang Shixiang Liu Huafeng Tang Pujun Wang Zhiwen Tian | 2024 | Acta Oceanologica Sinica2024，43，2： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员