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您的检索式：作者名="Rabia Khatoon"
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| 1 | Carbonized waste milk powders as cathodes for stable lithium-sulfur batteries with ultra-large capacity and high initial coulombic efficiency显示文摘To explore the natural resources as sustainable precursors offers a family of green materials.The use of bio-waste precursors especially the remaining from food processing is a scalable,highly abundant,and cost-effective strategy.Exploring waste materials is highly important especially for new materials discovery in emerging energy storage technologies such as lithium sulfur batteries(LSBs).Herein,waste milk powder is carbonized and constructed as the sulfur host with the hollow micro-/mesoporous framework,and the resulting carbonized milk powder and sulfur(CMP/S) composites are employed as cathodes for LSBs.It is revealed that the hollow micro-/mesoporous CMP/S framework can not only accommodate the volume expansion but also endow smooth pathways for the fast diffusion of electrons and Li-ions,leading to both high capacity and long cycling stability.The CMP/S composite electrode with 56 wt% loaded sulfur exhibits a remarkable initial capacity of 1596 mAh g^(-1) at 0.1 C,corresponding to 95% of the theoretical capacity.Even at a rate of 1 C,it maintains a high capacity of 730 mAh g^(-1) with a capacity retention of 72.6% after 500 cycles,demonstrating a very low capacity fading of only 0.05% per cycle.Importantly,the Coulombic efficiency is always higher than 96%during all the cycles.The only used source material is expired waste milk powders in our proposal.We believe that this 'trash to treasure' approach will open up a new way for the utilization of waste material as environmentally safe and high performance electrodes for advanced LSBs. | Rabia Khatoon Sanam Attique Rumin Liu Sajid Rauf Nasir Ali Luhong Zhang Yu-Jia Zeng Yichuan Guo Yusuf Valentino Kaneti Jongbeom Na Haichao Tang Hongwen Chen Yang Tian Jianguo Lu | 2022 | Green Energy & Environment2022，7，5： | 0 |
| 2 | Regulating adsorption ability toward polysulfides in a porous carbon/Cu_(3)P hybrid for an ultrastable high-temperature lithium-sulfur battery显示文摘Lithium-sulfur batteries(LSBs)can work at high temperatures,but they suffer from poor cycle life stability due to the“shuttle effect”of polysulfides.In this study,pollen-derived porous carbon/cuprous phosphide(PC/Cu_(3)P)hybrids were rationally synthesized using a one-step carbonization method using pollen as the source material,acting as the sulfur host for LSBs.In the hybrid,polar Cu_(3)P can markedly inhibit the“shuttle effect”by regulating the adsorption ability toward polysulfides,as confirmed by theoretical calculations and experimental tests.As an example,the camellia pollen porous carbon(CPC)/Cu_(3)P/S electrode shows a high capacity of 1205.6 mAh g^(−1) at 0.1 C,an ultralow capacity decay rate of 0.038%per cycle after 1000 cycles at 1 C,and a rather high initial Coulombic efficiency of 98.5%.The CPC/Cu_(3)P LSBs can work well at high temperatures,having a high capacity of 545.9 mAh g^(−1) at 1 C even at 150℃.The strategy of the PC/Cu_(3)P hybrid proposed in this study is expected to be an ideal cathode for ultrastable high-temperature LSBs.We believe that this strategy is universal and worthy of in-depth development for the next generation energy storage devices. | Yichuan Guo Rabia Khatoon Jianguo Lu Qinggang He Xiang Gao Xiaopeng Yang Xun Hu Yang Wu Jiale Lian Zhoupeng Li Zhizhen Ye | 2021 | Carbon Energy2021，3，6： | 0 |
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