| 1 | Sulfide@hydroxide core–shell nanostructure via a facile heating-electrodeposition method for enhanced electrochemical and photoelectrochemical water oxidation显示文摘Designing low-cost,easy-fabricated,highly stable and active electrocatalysts for oxygen evolution reaction(OER) is crucial for electrochemical(EC) and solar-driven photoelectrochemical(PEC) water splitting.By using a facile heating-electrodeposition method,here we fabricated a porous but crystalline Fe-doped Ni3 S2.A thin porous surface NiFe hydroxide layer(~10 nm) is then formed through OER-running.By virtue of the core Fe-doped Ni3 S2 with good conductivity and the shell NiFe hydroxide surface with good electrocatalytic activity,the core-shell nanostructure on Ni foam exhibits excellent OER activity in 1 M NaOH,needing only 195 and 230 mV to deliver 10 and 100 mA/cm^(2),respectively,much more superior to those of 216 and 259 mV for the sample deposited under normal temperature.The enhanced photo-response of the sulfide@hydroxide core-shell structure was also demonstrated,due to the efficient transfer of photo-generated carriers on the core/shell interface.More interestingly,it shows a good compatibility with Si based photoanode,which exhibits an excellent PEC performance with an onset potential of 0.86 V vs.reversible hydrogen electrode,an applied bias photon-to-current efficiency of 5.5% and a durability for over 120 h under AM 1.5 G 1 sun illumination,outperforming the state-of-the-art Si based photoanodes. | Yao Lu Huijuan Yu Cong Chen Ronglei Fan Mingrong Shen | 2021 | Journal of Energy Chemistry2021，30，7： | 1 |
| 2 | EduASAC:A Blockchain-Based Education Archive Sharing and Access Control System显示文摘In the education archive sharing system,when performing homomorphic ciphertext retrieval on the storage server,there are problems such as low security of shared data,confusing parameter management,and weak access control.This paper proposes an Education Archives Sharing and Access Control(EduASAC)system to solve these problems.The system research goal is to realize the sharing of security parameters,the execution of access control,and the recording of system behaviors based on the blockchain network,ensuring the legitimacy of shared membership and the security of education archives.At the same time,the system can be combined with most homomorphic ciphertext retrieval schemes running on the storage server,making the homomorphic ciphertext retrieval mechanism controllable.This paper focuses on the blockchain access control framework and specifically designs smart contracts that conform to the business logic of the EduASAC system.The former adopts a dual-mode access control mechanism combining Discretionary Access Control(DAC)and Mandatory Access Control(MAC)and improves the tagging mode after user permission verification based on the Authentication and Authorization for Constrained Environments(ACE)authorization framework of Open Authorization(OAuth)2.0;the latter is used in the system to vote on nodes to join requests,define access control policies,execute permission verification processes,store,and share system parameters,and standardize the behavior of member nodes.Finally,the EduASAC system realizes the encryption,storage,retrieval,sharing,and access control processes of education archives.To verify the performance of the system,simulation experiments were conducted.The results show that the EduASAC system can meet the high security needs of education archive sharing and ensure the system’s high throughput,low latency,fast decision-making,and fine-grained access control ability. | Ronglei Hu Chuce He Yaping Chi Xiaoyi Duan Xiaohong Fan Ping Xu Wenbin Gao | 2023 | Computers, Materials & Continua2023，77，12： | 0 |
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