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| 1 | Two competitive nucleation mechanisms of calcium carbonate biomineralization in response to surface functionality in low calcium ion concentration solution显示文摘Four self-assembled monolayer surfaces terminated with–COOH,–OH,–NH_(2)and–CH_(3)functional groups are used to direct the biomineralization processes of calcium carbonate(CaCO_(3))in low Ca^(2+)concentration,and the mechanism of nucleation and initial crystallization within 12 h was further explored.On-COOH surface,nucleation occurs mainly via ion aggregation mechanism while prenucleation ions clusters may be also involved.On-OH and-NH_(2)surfaces,however,nucleation forms via calcium carbonate clusters,which aggregate in solution and then are adsorbed onto surfaces following with nucleation of amorphous calcium carbonate(ACC).Furthermore,strongly negative-charged-COOH surface facilitates the direct formation of calcites,and the-OH and-NH_(2)surfaces determine the formation of vaterites with preferred crystalline orientations.Neither ACC nor crystalline CaCO_(3)is observed on-CH_(3)surface.Our findings present a valuable model to understand the CaCO_(3)biomineralization pathway in natural system where functional groups composition plays a determining role during calcium carbonate crystallization. | Hua Deng Shuo Wang Xiumei Wang Chang Du Xingcan Shen Yingjun Wang Fuzhai Cui | 2015 | Regenerative Biomaterials2015，2，3： | 3 |
| 2 | Hysteresis effects of the interaction between serum albumins and silver nanoparticles显示文摘 | Xingcan Shen Qi Yuan Hong Liang Haigang Yan Xiwen He | 2003 | Science in China Series B: Chemistry2003，，4： | 1 |
| 3 | Hot-injection synthesis of highly luminescent and monodisperse CdS nanocrystals using thioacetamide and cadmium source with proper reactivity显示文摘 | ZHANG Laijun SHEN Xingcan LIANG Hong | 2010 | Journal of Colloid and Interface Science2010，342，2： | 1 |
| 4 | Studies on the biomimetic membrane interaction between liposome and realgar nanoparticles显示文摘The liposome of small unilamellar vesicles (SUV) made from phosphatidylcholine-cholesterol mixtures was used as a simple model for biomimetic membranes. The studies on the interaction between the liposome and realgar nanoparticles (NPs) demonstrate that the phospholipid is one of the key targeted molecules of realgar NPs, used by surface plasmon resonance (SPR) technology, fluorescence polarization, Raman spectroscopy, nuclear magnetic resonance (NMR) and atom force microscope (AFM). It was observed that the relative viscosity (ηr) of the membrane increased and the membrane fluidity decreased as realgar NPs bound to SUV. Calculations of Raman intensity ratios detected the increase of longitudinal order parameters (Strans) and lateral order parameters (Slat) of the lipid bilayer, indicating a rise in the proportion of trans conformations of alkyl chains, and the decrease of membrane’s fluidity attributed to the interaction of realgar NPs. Results of Raman spectra and 31P NMR suggest that the polar headgroup of phospholipid is the interacted target site of realgar NPs. Moreover, time-lapse AFM images show that realgar NPs compromise the phospholipid membrane integrity to result in the formation of 'pore' or 'hole'. | SHEN XingCan JIN Tao XIE Jun LIANG Hong YAN Yu | 2009 | Science China Chemistry2009，52，9： | 1 |
| 5 | Synthesis and characterization of 3-aminopropyltriethoxysilane-modified superparamagnetic magnetite nanoparticles显示文摘 | SHEN Xingcan FANG Xiuzhong ZHOU Yinghua | 2004 | Chem Lett2004，33，： | 1 |
| 6 | Binding equilibrium of I? to serum albumin with resonance Rayleigh scattering显示文摘 | Hong Liang Xingcan Shen Zhiliang Jiang Xiwen He Panwen Shen | 2000 | Science in China Series B: Chemistry2000，，6： | 1 |
| 7 | 显示文摘 | Shen Xingcan Fang Xiuzhong Zhou Yinghua | 2004 | Chemistry Letters2004，33，： | 1 |
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