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| 1 | Cobalt(Ⅱ) coordination polymers built on isomeric dipyridyl triazole ligands with pyromellitic acid:Synthesis,characterization and their effects on the thermal decomposition of ammonium perchlorate显示文摘Three new cobalt(Ⅱ) coordination compounds,[Co(3,3'-Hbpt)2(H2pm)(H2O)2]·2H2O(1),[Co(4,4'-Hbpt)(pm)0.5(H2O)]·3H2O (2) and [Co(3,4'-Hbpt)(pm) 0.5 (H2O)3]·2H2O(3)(3,3'-Hbpt=3,5-bis(3-pyridyl)-1H-1,2,4-triazole;4,4'-bpt=3,5-bis(4-pyridyl)1H-1,2,4-triazole,3,4'-Hbpt=3-(3-pyridyl)-5-(4'-pyridyl)-1H-1,2,4-triazole and H4pm=pyromellitic acid) have been synthesized by hydrothermal reactions.Single-crystal X-ray diffraction reveals that compound 1 has a one-dimensional (1D) chain network,2 exhibits a four-connected three-dimensional (3D) structure with 1D open channels encapsulated by water molecules,while 3 displays a regular two-dimensional (2D) architecture connected through 1D metal helical chains.In addition,the efficacy of compounds 1-3 as additives to promote the thermal decomposition of ammonium perchlorate (AP) is explored by differential scanning calorimetry (DSC). | XIE Gang LI Bing CHEN SanPing YANG Qi WEI Wei GAO ShengLi | 2012 | Science China Chemistry2012,55,3: | 5 |
| 2 | A New Material of Lindera (Lauraceae) of the Late Pliocene from Tengchong, Yunnan and the Genus' Biogeography Significance显示文摘Lindera is a large genus of graceful, pleasantly scented and common native trees and shrubs of southern China and neighboring regions of SE Asia. There is a well-documented Cenozoic fossil record not only in these regions but also from elsewhere. A new fossil leaf record has been found in diatomite beds from the Upper Pliocene Mangbang Formation of Tuantian, Tengchong County, Yunnan. The leaves are identified and assigned to Lindera acuminatissima K. Q. Dao et B. N. Sun sp. nov., by comparing their leaf architecture and epidermal characteristics with those of 51 extant Lauraceae species and with 15 known fossil Lindera taxa. The specimens have well-preserved cuticles, with typical leaf architecture and epidermal characteristics of the Lauraceae, including entire leaf margin, intramarginal veins, basal ternate acrodromous primary veins, one-cell trichome base, paracytic stomatal apparatus, sunken guard cells, subsidiary hardly staining cells and presence of oil cells. These characteristics are consistent with Lindera sect. Daphnidium but are different from reported fossil and extant species of Lindera. The cuticles of Lindera are fragile and delicate with only three Lindera fossils reported based on this tissue. In terms of paleobiogeography, the fossil record indicates that Lindera is distributed in high- to mid-latitude regions of the Late Cretaceous to Paleocene northern hemisphere. Coincidentally, the records of Lindera located on both sides of the Bering Land Bridge possibly support the hypothesis that ancient plants extended via transcontinental exchanges through the Bering Corridor. In the Eocene, ancient Lindera spread to Europe through the Northern Degeer Route and the Southern Thulian Route. At the same time, ancient Lindera spread into Central Asia. Climatic changes and tectonization since the Neogene prevented the propagation of Lindera throughout Asia, North America and Europe, and hence the distribution areas have just regressed to the low-latitude regions in Asia and North America. From the Paleogene to the Neogene, Lindera has changed its distribution by surviving extreme climate changes. Quaternary glaciations ultimately led to Lindera becoming extinct in Europe. The new record from Tengchong, Yunnan, with its lower latitude located in tropical and subtropical regions, indicates that Lindera has lived in those regions since the late Pliocene. | DAO Kequn CHEN Junlin JIN Peihong DONG Chong YANG Yi XU Xiaohui WU Jingyu XIE Sanping LIN Zhicheng SUN Bainian | 2013 | Acta Geologica Sinica(English Edition)2013,87,3: | 4 |
| 3 | Hydrothermal Synthesis, Structure and Property of Transition Metal(Mn, Zn, Cd or Pb) Coordination Frameworks Using Quinoline-8-oxy-acetate Acid and Dicarboxylic Acid as Ligands显示文摘 | ZHANG Guochun QIAO Chengfang LIANG Jiehui WEI Qing XIA Zhengqiang CHEN Sanping | 2015 | Chemical Research in Chinese Universities2015,31,4: | 2 |
| 4 | Synthesis and structural investigation of two metal-organic frame- works constructed from alkaline earth metal cations and organic ligand 5-nitroisophthalic acid (5-NO2-H2BDC) 显示文摘 | Shuai Qi Chen Sanping Gao Shengli | 2007 | Structural Chemistry2007,18,5: | 1 |
| 5 | Synthesis and characterization of new M-Triazole complexes(M=Co, Cu, Zn) 显示文摘 | ZHANG Yinli CHEN Sanping GAO Shengli | 2009 | J Inorg General Chem2009,635,3: | 1 |
| 6 | A het- eropolymetallic coordination polymer containing alka- line-earth(A@ cation, lanthanide(Ln) cation and alkali A) cation 显示文摘 | Shuai Qi Chen Sanping Geng Huiting eta | 2011 | Inorganica Chimica Acta2011,379,1: | 1 |
| 7 | Vectorial boundary-based sub-pixel mapping method for remote-sensing imagery显示文摘 | Ge Yong Chen Xuedong Li Sanping | 2014 | International Journal of Remote Sensing2014,35,5: | 1 |
| 8 | A new high-nitrogen compound ·2H2O : Synthesis and characterization 显示文摘 | Baojuan Jiao Sanping Chen Fengqi Zhao | 2007 | Journal of Hazardous Materials2007,142,: | 1 |
| 9 | Construction of A Rotating-Bomb Combustion Calorimeter and Measurement of Thermal Effects显示文摘 | Yang Xuwu Chen Sanping Gao Shengli | 2002 | Instrumentation Science & Technology2002,30,3: | 1 |
| 10 | Enthalpies of dilution of aqueous Li 2 B 4 O 7 solutions at 298.15<ce:hsp sp='0.25'/>K and application of ion-interaction model显示文摘 | Guoyin Yin Yan Yao Baojuan Jiao Sanping Chen Shengli Gao | 2005 | Thermochimica Acta2005,,2: | 1 |
| 11 | Vectorial boundary-based sub-pixel mapping method for remote-sensing imagery 显示文摘 | Ge Yong Chen Xuedong Li Sanping | 2014 | International Journal of Remote Sensing2014,35,5: | 1 |
| 12 | A heterometallic microporous MOF exhibiting high hydrogen uptake显示文摘 | Wei Wei Zhengqiang Xia Qing Wei Gang Xie a Sanping Chen Chengfang Qiao Guochun Zhang Chunsheng Zhou | | 0,,: | 1 |
| 13 | A binary Markov process model for random testing显示文摘 | Chen Sanping Mills S | 1996 | IEEE Trans on Software Engineering1996,22,3: | 1 |
| 14 | Syntheses and characterization of energetic compounds constructed from alkaline earth metal cations(Sr and Ba)and 1,2-bis(tetrazol-5-yl)ethane显示文摘 | Xia Zhengqiang Chen Sanping Wei Qing | 2011 | Journal of Solid State Chemistry2011,184,7: | 1 |
| 15 | A new high-nitrogen compound ·2H2O: Synthesis and characterization显示文摘 | Jiao Baojuan Chen Sanping Zhao Fengqi | 2007 | J Hazard Mater2007,142,: | 1 |
| 16 | Syntheses and characterization of lead( Ⅱ ) N, N-bis amine compounds and effects on thermal decomposition of ammonium perchlorate 显示文摘 | Wang Weitao Chen Sanping Gao Shengli | 2009 | Eur J Inorg Chem2009,23,: | 1 |
| 17 | Thermokinetics on the reaction of formation of Dy[(C_(5)H_(8)NS_(2))_(3)(C_(12)H_(8)N_(2))]显示文摘The enthalpy change of formation of the reaction of hydrous dysprosium chloride meter. Thermodynamic parameters (the activation enthalpy, the activation entropy and the activation free energy), rate constant and kinetics parameters (the apparent activation energy, the pre-exponential constant and the reaction order) of the reaction have also been calculated. The enthalpy change of the solid-phase reaction at 298.15 K has been obtained as (53.59 ± 0.29)liquid-phase and solid-phase reaction indicated that the complex could only be synthesized in liquid-phase reaction. | GAO Shengli CHEN Sanping JIAO Baojuan SHUAI Qi SHI Qizhen | 2005 | Science China Chemistry2005,48,z1: | 1 |
| 18 | Determination of combustion energies and the standard enthalpies of formation for the complexes of RE(Et_(2)dtc)_(3)(phen)显示文摘Solid complexes, RE(Et2dtc)3(phen) (RE=La, Pr, Nd, Sm-Lu), were synthesized hydrated lanthanide chlorides in absolute ethanol. The constant-volume combustion energies of complexes, △cU, were determined by a precise rotating-bomb calorimeter at 298.15 K. The standard enthalpies of combustion, AcHmθ, and standard enthalpies of formation, AfHmθ, were calculated for these complexes, respectively. The experiment results showed the 'tripartite effect'of rare earth. | YANG Xuwu ZHU Li CHEN Sanping GAO Shengli SHI Qizhen | 2005 | Science China Chemistry2005,48,z1: | 1 |
| 19 | A new high-nitrogen compound ·2H2O:Synthesis and characterization显示文摘 | Baojuan Jiao Sanping Chen Fengqi Zhan | 2007 | J Hazard Mater2007,142,: | 1 |
| 20 | Syntheses and Characterization of Lead(Ⅱ)N,N-Bis amine Compounds and Effects on Thermal Decomposition of Ammonium Perchlorate显示文摘 | Weitao Wang Sanping Chen Shengli Gao | 2009 | EurJ Inorg Chem2009,,: | 1 |