| 2 | Pillar[6]arenes: From preparation, host-guest property to self-assembly and applications显示文摘Pillar[n]arenes primarily comprise pillar[5]arenes and pillar[6]arenes, which belong to the new class of supramolecular macrocyclic hosts. Pillar[n]arenes have aroused wide attention because of their highly rigid and symmetrical architectures, controllable cavity size, and wide applications in a wide variety of areas. Although pillar[6]arene is difficult to synthesize, numerous studies have been conducted on it. In this review, the strategies to synthesize and functionalize pillar[6]arenes are investigated systematically.In addition, their host-guest properties in organic solvents and in aqueous solution are described. Moreover, pillar[6]arenes applied in different fields(e.g., molecular recognition, drug release, cancer therapy,and gas separation) are clarified. Hopefully, this study is capable of arousing more attention from increasing scientists to study large-cavity pillar[n]arenes. | Ruowen Tang Yanpeng Ye Shajun Zhu Yang Wang Bing Lu Yong Yao | 2023 | Chinese Chemical Letters2023，34，3： | 1 |
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