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您的检索式：作者名="Sujitra Wongkasemjit"
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| 1 | Effect of synthesis time on morphology of CeO2 nanoparticles and Au/CeO2 and their activity in oxidative steam reforming of methanol显示文摘Ceria(CeO2)supports,synthesized by hydrothermal treatment with different synthesis time(CeO2-X h,where X is the synthesis time in h)in the presence of the surfactant cetyltrimethyl ammonium bromide,were used as supports for gold(Au)catalysts.The synthesis time significantly affects the morphological structure and crystallite size of CeO2,where CeO2-2 h has the smallest crystallite size with coexisting nanorods and nanoparticles.Transmission electron microscopy analysis confirms the morphology of CeO2 with distinctive(110),(100)and(111)planes,in agreement with interplanar spacings of 0.19,0,27 and 0.31,respectively.However,the morphology of CeO2-8 h and CeO2-48 h is mainly a truncated octahedral with crystal planes(111)and(100)accompanied by an interplanar spacing of 0.31 and0.27 nm,respectively.The CeO2-X h supports and those with a 3 wt%Au loading(Au/CeO2-X h)were investigated in the oxidative steam reforming of methanol at temperatures between 200 and 400℃.The Au/CeO2-2 h gave the highest methanol conversion level and hydrogen yield at a low temperature of 250℃.This superior catalytic performance results from the good interaction between the metal and support and the well-distributed Au species on the CeO2 support. | Srisin Eaimsumang Sujitra Wongkasemjit Sangobtip Pongstabodee Siwaporn Meejoo Smith Sukritthira Ratanawilai Nuwong Chollacoop Apanee Luengnaruemitchai | 2019 | Journal of Rare Earths2019，37，8： | 6 |
| 2 | Facile preparation of polybenzoxazine-based carbon microspheres with nitrogen functionalities:effects of mixed solvents on pore structure and supercapacitive performance显示文摘In this study,polybenzoxazine(PBZ)-based carbon microspheres were prepared via a facile method using a mixture of formaldehyde(F)and dimethylformamide(DMF)as the solvent.The PBZ microspheres were successfully obtained at the F/DMF weight ratios of 0.4 and 0.6.These microspheres exhibited high nitrogen contents after carbonization.The microstructures of all the samples showed an amorphous phase and a partial graphitic phase.The porous carbon with the F/DMF ratio of 0.4 showed significantly higher specific capacitance(275.1 F·g^-1)than the reference carbon(198.9 F·g^-1)at 0.05 A-g This can be attributed to the synergistic electrical double-layer capacitor and pseudo-capacitor behaviors of the porous carbon with the F/DMF ratio of 0.4.The presence of nitrogen/oxygen functionalities induced pseudo-capacitance in the microspheres,and hence increased their total specific capacitance.After activation with CO2,the specific surface area of the carbon microspheres with the F/DMF ratio of 0.4 increased from 349 to 859 m^2•g^-1 and the specific capacitance increased to 424.7 F·g^-1 This value is approximately two times higher than that of the reference carbon.The results indicated that the F/DMF ratio of 0.4 was suitable for preparing carbon microspheres with good supercapacitive performance.The nitrogen/oxygen functionalities and high specific surface area of the microspheres were responsible for their high capacitance. | Uthen Thubsuang Suphawadee Chotirut Apisit Thongnok Archw Promraksa Mudtorlep Nisoa Nicharat Manmuanpom Sujitra Wongkasemjit Thanyalak Chaisuwan | 2020 | Frontiers of Chemical Science and Engineering2020，14，6： | 0 |
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