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    题名 作者 年代 出处 被引量
1Interaction of pH and temperature affect infection and symptom development of Plasmodiophora brassicae in canola显示文摘BruceD. Gossen Hema Kasinathan Tiesen Cao VictorP. Manolii StephenE. Strelkov Sheau-Fang Hwang MaryRuth McDonald 2013Canadian Journal of Plant Pathology2013,,3:2
2Mesoporogen-free synthesis of hierarchical sodalite as a solid base catalyst from sub-molten salt-activated aluminosilicate显示文摘A rapid and environmentally friendly approach to synthesize hierarchical sodalite from natural aluminosilicate mineral without the involvement of any mesoporogen or post-synthesis treatment was developed.This strategy involves three important steps:the first is the depolymerization of an aluminosilicate mineral into highly reactive silicon and aluminum species with ideal meso-scale structures through activation of a sub-molten salt.The second step is the hydrolysis and condensation of the activated aluminosilicate mineral into zeolitic precursors that also have a meso-scale structure.The third is the rapid zeolitization of the zeolitic precursors through the reversed crystal growth route at room temperature and ambient pressure to form hierarchical sodalite.The physicochemical properties of the as-synthesized sodalite were systematically characterized,and the formation mechanism of the hierarchical pore structure was discussed.When used as a solid base catalyst for Knoevenagel condensation,the as-synthesized sodalite and its potassium ion-exchanged product with hierarchical micro-meso-macroporous structure both exhibited high catalytic activity and product selectivity.Jinbiao Yang Tiesen Li Xiaojun Bao Yuanyuan Yue Haiyan Liu 2020Particuology2020,18,1:1
3Characterization of the fungi associated with ascochyta blight of field pea in Alberta, Canada显示文摘Jianfeng Liu Tiesen Cao Jie Feng Kan-Fa Chang Sheau-Fang Hwang Stephen E. Strelkov 2013Crop Protection2013,,:1
4OSDA-free synthesis of FeZSM-22 zeolite from natural minerals for n-octane hydroisomerization显示文摘A seed-directed approach to synthesizing Fe ZSM-22 zeolite without organic structure directing agent(OSDA)was developed by using Fe-rich diatomite as all aluminum and iron sources.The Fe ZSM-22zeolite with optimal crystallinity and purity can be obtained by systematically adjusting feed composition and synthesis conditions.Characterizations show that Fe ZSM-22 zeolite synthesized with OSDA-free owns high crystallinity,obvious thin needle-shaped morphology and high Bronsted/Lewis acid ratio.Significantly,when used for n-octane hydroisomerization reaction,its derived catalyst exhibits the best catalytic performance reflected by the highest selectivity to C_(8)isomers compared to the two reference catalysts prepared based on a Fe-containing and a Fe-free ZSM-22 synthesized through an OSDA-directed route from natural diatomite and conventional chemicals,respectively.This work provides an alternative route to sustainably synthesizing heteroatomic zeolites with high performance.Tiesen Li Ting Chen Yinghui Ye Peng Dong TinghaiWang Qingyan Cui Chan Wang Yuanyuan Yue 2024Chinese Journal of Chemical Engineering2024,66,2:0
5Facile synthesis of hierarchical NaX zeolite from natural kaolinite for efficient Knoevenagel condensation显示文摘Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficiency.Herein,we explore an economic and environmentally friendly method for synthesizing hierarchical NaX zeolite that exhibits improved catalytic performance in the Knoevenagel condensation reaction for producing the useful fine chemical 2-cyano-3-phenylacrylate.The synthesis was achieved via a low-temperature activation of kaolinite and subsequent in-situ transformation strategy without any template or seed.Systematic characterizations reveal that the synthesized NaX zeolite has both intercrystalline and intra-crystalline mesopores,smaller crystal size,and larger external specific surface area compared to commercial NaX zeolite.Detailed mechanism investigations show that the inter-crystalline mesopores are generated by stacking smaller crystals formed from in-situ crystallization of the depolymerized kaolinite,and the intra-crystalline mesopores are inherited from the pores in the depolymerized kaolinite.This synthesis strategy provides an energy-saving and effective way to construct hierarchical zeolites,which may gain wide applications in fine chemical manufacturing.Wen Xiao Peng Dong Chan Wang Jingdong Xu Tiesen Li Haibo Zhu Tinghai Wang Renwei Xu Yuanyuan Yue 2024Chinese Journal of Chemical Engineering2024,65,1:0
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