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| 1 | Preparation of MnO2 decorated Co3Fe1Ox powder/monolithic catalyst with improved catalytic activity for toluene oxidation显示文摘In this paper, KMnO4 was used to pre-treat Co3 Fe-layered double hydroxides(LDH) precursor to prepare MnO2 decorated Co3Fe1Ox catalyst. The toluene oxidation performance of the catalyst was investigated systematically. The optimized 0.1 Mn CF-LDO catalyst exhibited the best catalytic performance, and the temperatures of 50% and 90% toluene conversion( T50 and T90) were 218 and 243 ℃, respectively. The apparent activation energy( Ea) was 31.6 k J/mol. The characterization results showed that the pre-redox reaction by KMnO4 could increase the specific surface area, Co^3+ species amount and oxygen defect concentration of the catalyst, which are the main reason of the improved toluene catalytic activity. Besides, this method was also applied to enhance toluene oxidation of iron mesh based monolithic catalyst. The 0.1 Mn CF-LDO/Iron mesh(IM) catalyst showed a 90% toluene conversion at around 316 ℃ which was much lower than that of without MnO2 addition(359 ℃). In addition, the water resistant of all the catalysts was studied as well, all the samples showed relatively good water resistance. The toluene conversion still remained to be over > 80% even in the presence of 10 vol.% water vapor. | Tianshan xue Renna Li Zhang Zhang Yanshan Gao Qiang Wang | 2020 | Journal of Environmental Sciences2020，32，10： | 2 |
| 2 | Soil respiration in a mixed urban forest in China in relation to soil temperature and water content显示文摘 | Wenjing Chen Xin Jia Tianshan Zha Bin Wu Yuqing Zhang Chunyi Li Xiaoping Wang Guimei He Haiqun Yu Guopeng Chen | 2013 | European Journal of Soil Biology2013，，： | 1 |
| 3 | Analgesic and antiinflanmmatory properties of brucine and brucine N-oxide extracted from seeds of Strychnos nux-vomica显示文摘 | YIN Wu WANG Tianshan YIN Fangzhou | 2003 | Ethnophamacol2003，88，23： | 1 |
| 4 | Total and Component Carbon Fluxes of a Scots Pine Ecosystem from Chamber Measurements and Eddy Covariance显示文摘 | Tianshan Zha Zisheng Xing Kai-Yun Wang | 2007 | Annals of Botany2007，99，： | 1 |
| 5 | Annual and seasonal variation of sap flow and conductance of pine trees grown in elevated carbon dioxide and temperature显示文摘 | WANG K Y SEPPO K TIANSHAN Z | 2005 | Journal of Experimental Botany2005，56，409： | 1 |
| 6 | Seasonal variation in energy and water fluxes in a pine forest: an analysis based on eddy covariance and an integrated model显示文摘 | Wang Kaiyun Kellomaki S Zha Tianshan | 2004 | Ecological Modelling2004，179，： | 1 |
| 7 | Recent advances in intermediate-temperature CO_(2) capture: Materials,technologies and applications显示文摘Carbon capture,utilization and storage(CCUS) is widely recognized as a vital strategy for mitigating the impact of human induced climate change.Among various CO_(2) adsorbents,intermediate-temperature solid adsorbents have garnered significant attention due to their potential applications in hydrogen utilization,specifically in the water gas shift,steam reforming and gasification processes.These processes are crucial for achieving carbon neutrality.While laboratory-level studies have showcased the high adsorption capacity of these materials via various synthesis and modification methods,their practical application in complex industrial environments remains challenging,impeding the commercialization process.This review aims to critically summarize the recent research progress made in intermediatetemperature(200-400℃) solid CO_(2) adsorbents,particularly focusing on indicators such as cyclability,gas selectivity,and formability,which play vital roles in industrial application scenarios.Additionally,we provide an overview of laboratory-level advanced technologies specifically tailored for industrial applications.Furthermore,we highlight several industrial-ready advanced technologies that can pave the way for overcoming the challenges associated with large-scale implementation.The insights provided by this review aim to assist researchers in identifying the most relevant research directions for industrial applications.By promoting advances in the application of solid adsorbents,we strive to facilitate the ultimate goal of achieving carbon neutrality. | Chengbo Zhao Leiming Wang Liang Huang Nicholas M.Musyoka Tianshan Xue Jabor Rabeah Qiang Wang | 2024 | Journal of Energy Chemistry2024，90，3： | 0 |
| 8 | Synergy of phosphorus vacancies and build-in electric field into NiCo/NiCoP Mott-Schottky integrated electrode for enhanced water splitting performance显示文摘Vacancy engineering and Mott-Schottky heterostructure can accelerate charge transfer,regulate adsorption energy of reaction intermediates,and provide additional active sites,which are regarded as valid means for improving catalytic activity.However,the underlying mechanism of synergistic regulation of interfacial charge transfer and optimization of electrocatalytic activity by combining vacancy and Mott-Schottky junction remains unclear.Herein,the growth of a bifunctional NiCo/NiCoP Mott-Schottky electrode with abundant phosphorus vacancies on foam nickel(NF)has been synthesized through continuous phosphating and reduction processes.The obtained NiCo/NiCoP heterojunctions show remarkable OER and HER activities,and the overpotentials for OER and HER are as low as 117 and 60 mV at 10 mA/cm^(2) in 1 mol/L KOH,respectively.Moreover,as both the cathode and anode of overall water splitting,the voltage of the bifunctional NiCo/NiCoP electrocatalyst is 1.44 V at 10 mA/cm^(2),which are far exceeding the benchmark commercial electrodes.DFT theoretical calculation results confirm that the phosphorus vacancies and build-in electric field can effectively accelerate ion and electron transfer between NiCo alloy and NiCoP semiconductor,tailor the electronic structure of the metal centers and lower the Gibbs free energy of the intermediates.Furthermore,the unique self-supported integrated structure is beneficial to facilitate the exposure of the active site,avoid catalyst shedding,thus improving the activity and structural stability of NiCo/NiCoP.This study provides an avenue for the controllable synthesis and performance optimization of Mott-Schottky electrocatalysts. | Xiaochen Zhang Hui Xue Jing Sun Niankun Guo Tianshan Song Jiawen Sun Yi-Ru Hao Qin Wang | 2024 | Chinese Chemical Letters2024，35，2： | 0 |
| 9 | Interfacial charge redistribution to promote the catalytic activity of Vs-CoP-CoS_(2)/C n-n heterojunction for oxygen evolution显示文摘Modulating surface charge redistribution based on interface and defect engineering has been considered as a resultful means to boost electrocatalytic activity.However,the mechanism of synergistic regulation of heterojunction and vacancy defects remains unclear.Herein,a Vs-CoP-CoS_(2)/C n-n heterojunction with sulfur vacancies is successfully constructed,which manifests superior electrocatalytic activity for oxygen evolution,as demonstrated by a low overpotential of 170 mV to reach 10 mA/cm^(2).The experimental results and density functional theory calculations testify that the outstanding OER performance of Vs-CoP-CoS_(2)/C heterojunction is owed to the synergistic effect of sulfur vacancies and built-in electric field at n-n heterogeneous interface,which accelerates the electron transfer,induces the charge redistribution,and regulates the adsorption energy of active intermediates during the reaction.This study affords a promising means to regulate the electrocatalytic performance by the construction of heterogeneous interfaces and defects,and in-depth explores the synergistic mechanisms of n-n heterojunction and vacancies. | Jiawen Sun Hui Xue Jing Sun Niankun Guo Tianshan Song Yi-Ru Hao Qin Wang | 2024 | Chinese Chemical Letters2024，35，2： | 0 |
| 10 | Co-Construction of Sulfur Vacancies and Heterogeneous Interface into Ni_(3)S_(2)/MoS_(2) Catalysts to Achieve Highly Efficient Overall Water Splitting显示文摘Integrating the advantages of anion vacancies and heterostructures into the catalytic materials may increase the binding affinities to intermediates, provide more active sites, and significantly promote the activity of overall water splitting. However, the successful assembly of anion vacancies and heterostructures for high-efficiency water splitting performance is still challenging. In this work, we ingeniously present the co-construction of sulfur vacancies and heterogeneous interface into Ni_(3)S_(2)/MoS_(2) catalysts on nickel foam(NF). The introduction of sulfur vacancies and Ni_(3)S_(2)/MoS_(2) heterostructures can significantly improve electron and ion transport, effectively improve structural stability, and enhance overall water splitting activity. The obtained VSNi_(3)S_(2)/MoS_(2) catalysts(VS stands for sulfur vacancies) exhibit superior OER and HER activities,and the overpotentials for OER and HER are 180 and 71 mV at 10 mA·cm^(-2), respectively. Furthermore, a low water splitting voltage of 1.46 V is required at 10 mA·cm^(-2) for the VS-Ni_(3)S_(2)/MoS_(2) catalysts, which is considerably lower than most that of water splitting electrocatalysts currently reported. This work offers an effective mean for the preparation of catalysts with both anion vacancies and heterostructures for achieving high-performance alkaline overall water splitting. | Zhaoyang An Hui Xue Jing Sun Niankun Guo Tianshan Song Jiawen Sun Yi-Ru Hao Qin Wang | 2022 | Chinese Journal of Structural Chemistry2022，41，8： | 0 |
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