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1篇 您的检索式:作者名="Wenbin Que"
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1Non-noble-metal electrocatalysts for oxygen evolution reaction toward seawater splitting: A review显示文摘The direct electrolytic splitting of abundant seawater instead of scarce freshwater is an ideal strategy for producing clean and renewable hydrogen(H 2)fuels.The oxygen evolution reaction(OER)is a vital half-reaction that occurs during electrochemical seawater splitting.However,OER suffers from sluggish four-electron transfer kinetics and competitive chlorine evolution reactions in seawater.Noble metal-based catalysts such as IrO_(2) and RuO_(2) are considered to have state-of-the-art OER electrocatalytic activity,but the low reserves and high prices of these noble metals significantly limit their large-scale application.Recently,efforts have been made to explore efficient,robust,and anti-chlorine-corrosion non-noble-metal OER electrocatalysts for seawater splitting such as oxides,hydroxides,phosphides,nitrides,chalcogenides,alloys,and composites.An in-depth understanding of the fundamentals of seawater electrolysis and the design principle of electrode materials is important for promoting seawater-splitting technology.In this review,we first introduce fundamental reactions in seawater electrolytes.Subsequently,construction strategies for OER electrocatalysts for seawater splitting are introduced.Finally,present challenges and perspectives regarding non-noble-metal OER electrocatalysts for commercial H 2 production by seawater splitting are discussed.Zhengguang Qin Wenxian Liu Wenbin Que Jinxiu Feng Wenhui Shi Fangfang Wu Xiehong Cao 2023ChemPhysMater2023,2,3:0
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