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| 1 | Facile Access to Uranium and Thorium Phosphaethynolate Complexes Supported by Tren: Experimental and Theoretical Study显示文摘The issue of covale nee of acti nide complexes remai ns con troversial to date.The in troducti on of 2-phosphaethy nolate anion into acti・nide complexes is expected to in vestigate the reaction mode and the bon ding property.Herei n,we describe the function alizatio n of An(Tren^(TIPS))CI(1:An=U;2:An=Th)precursors with NaOCP(dioxane)_(2.5) through salt-elimination method leading to the formation of the corresponding uranium and thorium phosphaethynolate species:[U(Tren^(TIPS))(OCP)]⑶and[Th(Tren^(TIPS))(OCP)](4). | Jipan Yu Kang Liu Qunyan Wu Bin Li Xianghe Kong Kongqiu Hu Lei Mei Liyong Yuan Zhifang Chai Weiqun Shi | 2021 | Chinese Journal of Chemistry2021，39，8： | 1 |
| 2 | Different Burial-Cooling History of Triassic Strata between the Western Weibei Uplift and the Northwestern Weihe Basin in Northwest China显示文摘Analysis of tectonothermal history of the Yanchang Formation in the western Weibei Uplift and in the northwestern Weihe Basin can reconstruct the cooling history of the southwest most remained Upper Triassic source rock of the North China Plate. Apatite fission-track(AFT) and(U-ThSm)/He(AHe) analysis were used to recover the cooling and uplift history of the Upper Triassic here. Ten sandstones from the Middle–Upper Triassic strata yield AFT ages between 179.8 ± 7.4 and 127.6 ± 8.1 Ma. AHe ages of two sandstones have the value of 37.7 ± 2.3–131.1 ± 8.1 and 45.7 ± 2.8–83.5 ± 5.2 Ma. Time-temperature modeling results showed that tectonothermal history of the Yanchang Formation was initially different in time-space relationships but then became almost identical through time followed by different cooling rate. Modeling results of the Triassic strata in the Qianyang area and the Yaojiagou area revealed three different uplift-cooling stages commencing in the Late Jurassic at ~165 Ma and in Early Cretaceous at ~110 Ma, respectively, both followed by first similar cooling histories to the Early Miocene at ~20 – 23 Ma and then different since the Late Miocene. Uplift-cooling rate since the Late Miocene at ~8 Ma were different between the Western Weibei Uplift and the Northwestern Weihe Basin. The timing, cooling-uplift rates of the Yaojiagou area, which was mainly controlled by movements related to the Liupanshan Mountains, the Qinling Orogens and the Weibei Uplift, had the earliest onset of uplift-cooling for the Upper Triassic series compared to other regions within the Weibei Uplift. Cooling paths for the Upper Triassic series became uniform regionally in the Early Cretaceous marking a key time for the tectonothermal evolutionary history of Upper Triassic series in the southwestern North China Plate. | Qiang Yu Zhanli Ren Rongxi Li Chung Ling Tao Ni Wanshan Lei Baojiang Wang Xiaoli Wu Xiaoli Qin Xianghe Lei | 2023 | Journal of Earth Science2023，34，5： | 0 |
| 3 | Exhumation and Preservation of the Jinchuan Ni-Cu-PGE Deposit under the East Longshou Mountain Thermal Evolution,Revealed by Apatite Fission Track Thermochronology显示文摘Uplift and exhumation are important factors affecting the preservation of deposits.The anatomy of uplift-cooling evolution and exhumation in the East Longshou Mountain is of significant research value in understanding changes in the Jinchuan Ni-Cu-PGE deposit since its formation.This study uses apatite fission track(AFT)thermochronology to reconstruct the thermal history of the East Longshou Mountain,including the Jinchuan mine,revealing the uplift and exhumation history of the East Longshou Mountain and elucidating the preservation status of the Jinchuan deposit.The AFT ages in the East Longshou Mountain are distributed from 62.3±3.0 Ma to 214.7±14 Ma,with significant differences in ages in distinct areas,the central and pooled ages being consistent within the margin of error.Inverse thermal history models reveal two rapid cooling events associated with exhumation from the Early Jurassic to the Early Cretaceous(200–100 Ma)and since the Miocene(15–0 Ma),the former attributable to the far-afield response to the closure of the PaleoTethys Ocean and plate assembly at the southern margin of Eurasia,the latter associated with the initial India-Eurasia plate collision.A slow cooling event from the Early Cretaceous to the Miocene(100–15 Ma)is thought to be related to the arid environment in northwest China since the Cretaceous.These cooling events have diverse responses and cooling rates in different blocks of the East Longshou Mountain:the southwest and centre of which are mainly cooled over 200–120 Ma and 120–0 Ma,with cooling rates of~0.25 and~0.33°C/Ma(~1.25 and~0.33°C/Ma in the centre);the Jinchuan mine primarily cooled over 160–100 Ma,100–15 Ma and 15–0 Ma,with cooling rates of~1.33,~0.25 and~2.00°C/Ma.These differentiated coolings imply that the uplift of the East Longshou Mountain before the Miocene(~15 Ma)was integral.Strong uplift then occurred in the vicinity of the mining area,which is a critical period for the uplift of the Jinchuan deposit to the surface,meaning that the Jinchuan deposit was exposed no earlier than the Miocene(~15 Ma).Based on mineralization depth information obtained by previous researchers,in conjunction with the calculation and simulation results of this study,it can be seen that the bulk of the Jinchuan intrusion may still be preserved at depth. | LEI Xianghe YU Qiang JIAO Jiangang LIU Jian SUN Xianyao HE Lijuan YANG Qike | 2023 | Acta Geologica Sinica(English Edition)2023，97，2： | 0 |
| 4 | Characteristics and evolution of faults in the north-central Yin’e Basin and the effects on the coal-seam in the Cretaceous strata显示文摘Research on the characteristics of faults and their evolutionary history since the Cretaceous in the Suhongtu-Dagu depressions can provide a theoretical basis for geological evaluation of the coal seams in the Suhongtu Formation in the northern-central region of the Yin’e Basin.Using 3-D seismic-logging inversion techniques,seismic stratigraphic calibration,stratigraphic sequence delineation,and thickness calculations on the Suhongtu-Dagu depressions were carried out to clarify the planar and profile distributions of the faults,as well as the evolutionary history of these faults and the tectonic history of the depressions.The results of this study revealed that the distribution of the faults in the Suhongtu-Dagu depressions in the northern part of the Yin’e Basin varies with region,and the fault system was multi-period,orthotropic,north-east-trending,and north-north-east-trending,with a certain degree of inheritance in terms of the geological setting.Three types of faults were identified:Y-shaped fractures,reverse Y-shaped fractures,and parallel fractures,which can be classified as Paleozoic-Cenozoic continuous syncline faults and intra-depression faults from the top of the Permian to the Upper Cretaceous series and inter-stratigraphic adjustment faults within the Cretaceous System,respectively.The evolution of these faults can be divided into three phases:the controlling faults were the faults that existed before the Early Cretaceous and had been active since then;synclinal faults that formed during the Early Cretaceous;and modified faults that formed since the Early Cretaceous.The development and modification of the coal seams in the Cretaceous Suhongtu Formation in the Hari,Kuanzihu,and Babei sags were strongly controlled and influenced by a multi-phase complex fault system. | Qiang YU Baojiang WANG Zhanli REN Xianyao SUN Xianghe LEI Ahmed KHALED Qike YANG | 2023 | Frontiers of Earth Science2023，17，1： | 0 |
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