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| 1 | High-precision measurement of mercury isotope ratios of atmospheric deposition over the past 150 years recorded in a peat core taken from Hongyuan, Sichuan Province, China显示文摘High-precision 210Pb dating technology was applied to a peat core with a time span of about 150 years that was taken from Hongyuan, Sichuan Province, China. The concentrations of total mercury (Hg) and stable isotope compositions of mercury in the peat core were measured using a LUMEX 915 instrument and multi-collector inductively coupled plasma mass spectrometer, respectively. Total mercury (Hg) concentrations in the peat core had a clearly increasing trend from the bottom to top of the core while δ 202Hg values (relative to NIST 3133) of peat had a decreasing trend. The total mercury (Hg) concentration varied from 16.7 to 101.3 ng/g and the δ 202Hg values ranged from –0.44‰± 0.14‰ to –1.45‰± 0.22‰. We clearly show that the study area experienced mercury pollution after the industrial revolution, and the mercury emitted from natural sources and anthropogenic sources had different Hg isotope signatures. | SHI WenFang FENG XinBin ZHANG Gan MING LiLi YIN RunSheng ZHAO ZhiQi WANG Jing | 2011 | Chinese Science Bulletin2011，56，9： | 7 |
| 2 | RuCl_3 anchored onto post-synthetic modification MIL-101(Cr)-NH_2 as heterogeneous catalyst for hydrogenation of CO_2 to formic acid显示文摘A series of efficient ruthenium chloride (RuCl_3)-anchored MOF catalysts,such as RuCl_3@MIL-101 (Cr)-Sal,and RuCl_3@MIL-101 (Cr)-DPPB, have been successfully synthesized by post-synthetic modification (PSM)of the terminal amino of MIL-101(Cr)-NH_2 with salicylaldehyde, 2-diphenylphosphinobenzaldehyde (DPPBde) and anchoring of Ru (Ⅲ) ions. The stronger coordination electron donor interaction between Ru (Ⅲ) ions and chelating groups in the RuCl_3@MIL-101 (Cr)-DPPB enhances its catalytic performance for CO_2 hydrogenation to formic acid. The turnover number (TON) of formic acid was up to 831 in reaction time of 2 h with dimethyl sulfoxide (DMSO) and water (H_2O) as mixed solvent, trimethylamine (Et_3N) as organic base, and PPh_3 as electronic additive. | Shengping Wang Shihui Hou Chao Wu Yujun Zhao Xinbin Ma | 2019 | Chinese Chemical Letters2019，30，2： | 5 |
| 3 | Interface tuning of Cu+/CuO by zirconia for dimethyl oxalate hydrogenation to ethylene glycol over Cu/SiO2 catalyst显示文摘An efficient ZrO2-doped Cu/SiO2 catalyst was fabricated through hydrolysis precipitation method(HP)and used to produce ethylene glycol(EG)through dimethyl oxalate(DMO)hydrogenation.The states for zirconia on copper catalyst and roles in DMO hydrogenation were investigated through various characterization tools,including N2 physical adsorption,XRD,H2-TPR,Methyl glycolate-TPD-MS,XPS,XAES as well.Compared with common ammonia evaporation and co-precipitation methods used in catalyst preparation,this HP method is found to effectively suppress the agglomeration and further size growth of copper nanoparticles by enhancing the interactions between copper and zirconia species.More importantly,uniform distribution of ZrO2 dopant is achieved due to the pseudo-homogeneous reactions in the mixing step of catalyst preparation.A proper amount of zirconium dopant helps achieve the desirable proportion of Cu+/(Cu++CuO)for surface copper species,especially promotes the production of Cu+species originated from Cu-ZrO2 species at the interface of copper and zirconia particles.In comparison with Cu+species formed from copper phyllosilicates reduction,the Cu+sites derived from Cu-ZrO2 species show higher adsorption ability of MG,an important intermediate species in ethylene glycol production.These adsorbed MG molecules further react with atomic hydrogen shifted from adjacent metallic copper surface,leading to a higher catalytic behavior.For the EG production via DMO hydrogenation,the turnover frequency(TOF)normalized by CuO species on CuZr/SiO2 catalyst is 1.8 times than that of traditional Cu/SiO2 counterpart.Due to the enhanced synergy effect between Cu+and Cuo active sites,a lower activation energy of ester hydrogenation on this ZrO2-doped Cu/SiO2 catalyst is believed to be responsible for the significant improvement. | Yujun Zhao Huanhuan Zhang Yuxi Xu Shengnian Wang Yan Xu Shengping Wang Xinbin Ma | 2020 | Journal of Energy Chemistry2020，29，10： | 5 |
| 4 | Comparison of in vitro digestion methods for determining bioaccessibility of Hg in rice of China显示文摘Rice consumption can be a major pathway for mercury(Hg) exposure, which can cause health hazards to Chinese residents. To accurately assess the potential health risks, the bioaccessibility of Hg in rice samples collected at background and Hg-contamination sites was examined using four in vitro methods. The results showed that < 50% of the total mercury(THg) was bioaccessible in the studied rice samples. The THg bioaccessibility in the rice samples collected at the Hg-contaminated site was higher than that observed at the background area. The bioaccessibility of arsenic(As) and cadmium(Cd) was also evaluated for comparison of the four in vitro methods used in this study. The Physiologically Based Extraction Test was found to be the most accurate method based on the consistency of the results compared to those reported in previous studies. The estimated daily intakes of THg via rice consumption using the bioaccessibility data were found to meet the recommendation value set by the JECFA and the WHO in both sites. However, the potential health risk was not negligible at the Hg-contaminated sites, due to the high THg concentration and bioaccessibility in the rice samples. | Ze Wu Xinbin Feng Ping Li Che-Jen Lin Guangle Qiu Xun Wang Huifang Zhao Hui Dong | 2018 | Journal of Environmental Sciences2018，30，6： | 3 |
| 5 | New ZnCe catalyst encapsulated in SBA-15 in the production of 1,3-butadiene from ethanol显示文摘ZnO-CeO2/SBA-15 catalysts were prepared by two kinds of solid-state grinding method and used for the production of 1,3-butadiene(1,3-BD) from ethanol.A mixture of SBA-15(with or without organic template) and metal precursors were ground in solid-state.The obtained catalysts were characterized by TG,N2 adsorption-desorption,TEM,XRD,Py-FTIR and NH_3-TPD techniques.Superior dispersion of metal oxides and more exposed acid sites were achieved on the catalyst lOZn_1Ce_5-AS with the presence of organic template in SBA-15 during the solid-state grinding process.The catalytic performance was evaluated in a fixed-bed reactor and a 1,3-butadiene selectivity of as high as 45% is achieved.This is attributed to the coupling effect of Zn and Ce species in the mesopores of SBA-15,in which Zn promotes ethanol dehydrogenation and Ce enhances aldol-condensation,respectively.Additionally,solvent-free method inspires new catalyst synthesis strategy for the production of 1,3-butadiene from ethanol. | Yujun Zhao Sijia Li Zheng Wang Shengnian Wang Shengping Wang Xinbin Ma | 2020 | Chinese Chemical Letters2020，31，2： | 3 |
| 6 | Pd-Fe/a-AI203/cordierite monolithic catalysts for the synthesis of dimethyl oxalate: effects of calcination and structure显示文摘 | Shengping WANG Xin ZHANG Yujun ZHAO Yadong GE Jing LV Baowei WANG Xinbin MA | 2012 | Frontiers of Chemical Science and Engineering2012，6，3： | 3 |
| 7 | Influence of crystalline phase of Li-AI-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate synthesis显示文摘 | Yadong GE Yuanyuan DONG Shengping WANG Yujun ZHAO Jing LV Xinbin MA | 2012 | Frontiers of Chemical Science and Engineering2012，6，4： | 3 |
| 8 | Effect of thermal pretreatment on the surface structure of PtSn/SiO2 catalyst and its performance in acetic acid hydrogenation显示文摘活跃地点和在醋酸(AcOH ) 的 PtSn/SiO 2 催化剂的催化表演上的热预告的处理的效果加氢在这篇文章被调查。催化剂被 N 2 描绘物理吸附, X 光检查衍射,传播电子显微镜学, pyridine Fourier 变换红外线的系列,和它的物理化学的性质上的 H 2-O2 滴定。结果证明那磅种首先在水晶的结构被形成,没有 PtSn x 合金被观察。与热预告的处理温度的增长,同时,磅分散由于磅粒子的聚集显示出一个减少的趋势。同时,路易斯酸地点的数量被拥有到 Sn 种类的作为结果的物理化学的性质变化的如此的热预告的处理显著地影响。有趣地,催化活动与路易斯酸地点的显示出类似的变化趋势,证实在 AcOH 加氢的路易斯酸地点的重要角色。而且,在暴露的磅和路易斯酸地点之间的平衡效果被获得,在 AcOH 加氢导致优异催化表演。 | Guozhen Xu Jian Zhang Shengping Wang Yujun Zhao Xinbin Ma | 2016 | Frontiers of Chemical Science and Engineering2016，10，3： | 2 |
| 9 | Controllable Fe/HCS catalysts in the Fischer-Tropsch synthesis: Effects of crystallization time显示文摘The Fischer--Tropsch synthesis(FTS)con-tinues to be an attractive alternative for producing a broad range of fuels and chemicals through the conversion of syngas(H2 and CO),which can be derived from various sources,such as coal,natural gas,and biomass.Among iron carbides,Fe2C,as an active phase,has barely been studied due to its thermodynamic instability.Here,we fabricated a series of Fe2C embedded in hollow carbon sphere(HCS)catalysts.By varying the crystallization time,the shell thickness of the HCS was manipulated,which significantly influenced the catalytic performance in the FTS.To investigate the relationship between the geometric structure of the HCS and the physic-chemical properties of Fe species,transmission electron microscopy,X-ray diffraction,N2 physical adsorption,X-ray photo-electron spectroscopy,hydrogen temperature-programmed reduction,Raman spectroscopy,and Mossbauer spectro-scopy techniques were employed to characterize the catalysts before and after the reaction.Evidently,a suitable thickness of the carbon layer was beneficial for enhancing the catalytic activity in the FTS due to its high porosity,appropriate electronic environment,and relatively high Fe2C content. | Yifei Wang Shouying Huang Xinsheng Teng Hongyu Wang Jian Wang Qiao Zhao Yue Wang Xinbin Ma | 2020 | Frontiers of Chemical Science and Engineering2020，14，5： | 2 |
| 10 | Efficient MgO-doped CaO sorbent pellets for high temperature CO_(2) capture显示文摘Novel MgO-doped CaO sorbent pellets were prepared by gel-casting and wet impregnation.The effect of Na^(+) and MgO on the structure and CO_(2) adsorption performance of CaO sorbent pellets was elucidated.MgOdoped CaO sorbent pellets with the diameter range of 0.5-1.5 mm exhibited an excellent capacity for CO_(2) adsorption and adsorption rate due to the homogeneous dispersion of MgO in the sorbent pellets and its effects on the physical structure of sorbents.The results show that MgO can effectively inhibit the sintering of CaO and retain the adsorption capacity of sorbents during multiple adsorption-desorption cycles.The presence of mesopores and macropores resulted in appreciable change of volume from CaO(16.7 cm^(3)·mol^(-1))to CaCO3(36.9 cm^(3)·mol^(-1))over repeated operation cycles.Ca2Mg1 sorbent pellets exhibited favorable CO_(2) capture capacity(9.49 mmol·g^(-1)),average adsorption rate(0.32 mmol·g^(-1)·min^(-1)) and conversion rate of CaO(74.83%) after 30 cycles. | Zhihong Xu Tao Jiang Hao Zhang Yujun Zhao Xinbin Ma Shengping Wang | 2021 | Frontiers of Chemical Science and Engineering2021，15，3： | 2 |
| 11 | Enforced expression ofmiR -101 inhibits prostate cancer cell growth by modulating the COX-2 pathway in vivo cancer显示文摘 | Yubin Hao Xinbin Gu Yuan Zhao | 2011 | Med Oncol2011，4，7： | 1 |
| 12 | Enhanced CO2 adsorption capacity and stability using CaO‐based adsorbents treated by hydration显示文摘 | Shengping Wang Hui Shen Shasha Fan Yujun Zhao Xinbin Ma Jinlong Gong | 2013 | AIChE J2013，，10： | 1 |
| 13 | Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability显示文摘 | Hairong Yue Yujun Zhao Li Zhao Jing Lv Shengping Wang Jinlong Gong Xinbin Ma | 2011 | AIChE J2011，，9： | 1 |
| 14 | Ethylene glycol: properties, synthesis, and applications 显示文摘 | Hairong Yue Yujun Zhao Xinbin Ma and Jinlong Gong | 2012 | Royal Society of Chemistry2012，，： | 1 |
| 15 | Hydrogenation of dimethyl oxalate to ethylene glycol over mesoporous Cu ‐ MCM ‐41 catalysts显示文摘 | Xinbin Ma Hanwen Chi Hairong Yue Yujun Zhao Yan Xu Jing Lv Shengping Wang Jinlong Gong | 2013 | AIChE J2013，，7： | 1 |
| 16 | In situ synthesis and properties of carbon-coated LiFe- PO4/as Li-ion battery cathodes 显示文摘 | Mi Changhuan Zhao Xinbin Cao Gaoshao | 2005 | J Eleetroehem Soc2005，152，3： | 1 |
| 17 | 2020 update on human coronaviruses:One health,one world显示文摘Since human coronavirus(HCoVs)was first described in the 1960s,seven strains of respiratory human coronaviruses have emerged and caused human infections.After the emergence of severe acute respiratory syndrome coronavirus(SARS-CoV)and Middle East respiratory syndrome coronavirus(MERS-CoV),a pneumonia outbreak of coronavirus disease 2019(COVID-19)caused by a novel coronavirus(SARS-CoV-2)has represented a pandemic threat to global public health in the 21st century.Without effectively prophylactic and therapeutic strategies including vaccines and antiviral drugs,these three coronaviruses have caused severe respiratory syndrome and high case-fatality rates around the world.In this review,we detail the emergence event,origin and reservoirs of all HCoVs,compare the differences with regard to structure and receptor usage,and summarize therapeutic strategies for COVID-19 that cause severe pneumonia and global pandemic. | Xinbin Zhao Yuecheng Ding Jing Du Yubo Fan | 2020 | Medicine in Novel Technology and Devices2020，，4： | 1 |
| 18 | Ethylene Glycol:Properties,Synthesis,and Applications显示文摘 | Yue Hairong Zhao Yujun Ma Xinbin | 2012 | Chem Soc Rev2012，41，11： | 1 |
| 19 | Partitioning of rare earth elements and yttrium(REY)in five coal-fired power plants in Guizhou,Southwest China显示文摘As indispensable strategic materials for high-tech industries,rare earth elements and yttrium(REY)have become particularly important in recent years,raising the demand of developing new approaches for reclamation of REY from REY-rich materials such as coal combustion products(CCPs).In this study,five coal-fired power plants(CFPPs)in Guizhou of southwest China were selected for investigating REY concentrations of solid samples,atmospheric emissions,and recovery potentials.REY concentrations of feed fuels are higher in this study(147.2-468.6 mg/kg)than what have been reported previously for coals in China and the world.REY atmospheric emissions are extremely low(38.70-180.11 mg REY/t coal).REY are enriched in bottom ash and fly ash,with average of 658±296 mg/kg and maximum of 1257 mg/kg from the five CFPPs.Relative enrichment factors(REF)of REY in bottom ash and fly ash compared with the feed fuel are 0.86-1.02 and 0.91-1.04,respectively.REY concentrations in desulfurized gypsum are very low(6-17 mg/kg),and that is mostly inherited from limestone.Critical REY(Nd,Eu,Tb,Dy,Y,and Er)in bottom/fly ash account for 34%-39%of the total REY and the outlook coefficients(Cout1)are in the range of 0.89-1.11.This study indicates a promising prospect to reclaim REY from REYrich CCPs(bottom and fly ash)in CFPPs in Guizhou,especially in the central-north Guizhou,although such practices require further technology advancement. | Zhonggen Li Xinyu Li Leiming Zhang Shan Li Ji Chen Xinbin Feng Dongbo Zhao Qingfeng Wang Zhixi Gao Bailian Xiong | 2020 | Journal of Rare Earths2020，38，11： | 1 |
| 20 | Ethylene glycol: properties, synthesis, and applications 显示文摘 | Hairong Yue Yujun Zhao Xinbin Ma Jinlong Gong | 2012 | Royal Society of Chemistry2012，41，11： | 1 |
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