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| 1 | A chromosome-level genome of electric catfish(Malapterurus electricus)provided new insights into order Siluriformes evolution显示文摘The electric catfish(Malapterurus electricus),belonging to the family Malapteruridae,order Siluriformes(Actinopterygii:Ostariophysi),is one of the six branches that has independently evolved electrical organs.We assembled a 796.75 Mb M.electricus genome and anchored 88.72%sequences into 28 chromosomes.Gene family analysis revealed 295 expanded gene families that were enriched on functions related to glutamate receptors.Convergent evolutionary analyses of electric organs among different lineage of electric fishes further revealed that the coding gene of rho guanine nucleotide exchange factor 4-like(arhgef4),which is associated with G-protein coupled receptor(GPCR)signaling pathway,underwent adaptive parallel evolution.Gene identification suggests visual degradation in catfishes,and an important role for taste in environmental adaptation.Our findings fill in the genomic data for a branch of electric fish and provide a relevant genetic basis for the adaptive evolution of Siluriformes. | Meiru Liu Yue Song Suyu Zhang Lili Yu Zengbao Yuan Hengjia Yang Mengqi Zhang Zhuocheng Zhou Inge Seim Shanshan Liu Guangyi Fan Huanming Yang | 2024 | Marine Life Science & Technology2024,6,1: | 0 |
| 2 | Single-element amorphous palladium nanoparticles formed via phase separation显示文摘Physically vitrifying amorphous single-element metal requires ultrahigh cooling rates,which are still unachievable for most of the closest-packed metals.Here,we report a facile chemical synthetic strategy for single-element amorphous palladium nanoparticles with a purity of 99.35 at.%±0.23 at.%from palladium–silicon liquid droplets.In-situ transmission electron microscopy directly detected the solidification of palladium and the separation of silicon.Further hydrogen absorption experiment showed that the amorphous palladium expanded little upon hydrogen uptake,exhibiting a great potential application for hydrogen separation.Our results provide insight into the formation of amorphous metal at nanoscale. | Dong Sheng He Yi Huang Benjamin D.Myers Dieter Isheim Xinyu Fan Guang-Jie Xia Yunsheng Deng Lin Xie Shaobo Han Yang Qiu Yang-Gang Wang Junhua Luan Zengbao Jiao Li Huang Vinayak P.Dravid Jiaqing He | 2022 | Nano Research2022,15,6: | 0 |
| 3 | Transition-metal-free [3+3] annulation reaction of sulfoxonium ylides with cyclopropenones for the synthesis of 2-pyrones显示文摘An efficient and practical synthetic approach was developed for the tandem synthesis of trisubstituted 2-pyrone derivatives from sulfoxonium ylides and cyclopropenones.This[3+3]annulation reaction was carried out under transition-metal-free conditions.A broad range of functional groups were tolerant under mild conditions,and a variety of 2-pyrones were obtained in moderate to good yields. | Maoyao He Yuncan Chen Yi Luo Jianglian Li Ruizhi Lai Zengbao Yang Yuerong Wang Yong Wu | 2020 | Green Synthesis and Catalysis2020,1,2: | 0 |
| 4 | Design of FeSiBPCu soft magnetic alloys with good amorphous forming ability and ultra-wide crystallization window显示文摘The Fe_(81.3)Si_(4)B_(13–x)PxCu_(1.7) soft magnetic alloys with high Cu and proper P elements addition were synthesized with the aim of ensuring the amorphous forming ability(AFA)while expanding the crystallization window(CW).It is found that the atomic ratio of P/Cu of∼3 is advantageous for AFA whereas a small amount of P addition promotes the precipitation ofα-Fe grains and excessive P addition induces surface crystallization behavior of the present alloys.High Cu concentration can expand the annealing temperature(Ta)window whereas proper P addition effectively expands the annealing time(ta)window.The Fe_(81.3)Si_(4)B_(13-x)PxCu_(1.7) soft magnetic alloy was successfully synthesized with a large Ta window of up to 130°C and ta window of 90 min,which is a breakthrough for nanocrystalline alloys with high saturation magnetization.Microstructure analysis reveals that the ultra-wide CW is related to the unique nucleation mechanism,that is,theα-Fe grains are precipitated attaching to the Cu or CuP clusters and enveloping the Cu clusters,resulting in the high number density ofα-Fe nanocrystals.The ultra-wide CW promises the potential material in flexibly choosing the annealing process according to the performance. | Xingdu Fan Tao Zhang Weiming Yang Junhua Luan Zengbao Jiao Hui Li | 2023 | Journal of Materials Science & Technology2023,,16: | 0 |
| 5 | Simultaneously improving mechanical properties and oxidation resistance of Ti-bearing high-entropy superalloys at intermediate temperature via silicon addition显示文摘Ti-bearing high-entropy superalloys(HESAs)often suffer from severe intergranular embrittlement and terrible oxidation degradation at intermediate temperatures.Here we showcase that minor Si addition can effectively mitigate the intergranular embrittlement and improve the oxidation resistance of the a(Ni_(2)Co_(2)FeCr)_(92) Ti_(4)Al_(4) HESA at 700℃ simultaneously.Experimental analysis revealed that the intergranu-lar G phase induced by 2 at%Si addition can effectively suppress the inward diffusion of oxygen along grain boundaries at 700℃,thus enhancing the tensile ductility of the alloy from∼8.3%to∼13.4%.Be-sides,the 2 at%Si addition facilitated the formation of a continuous Al_(2)O_(3) layer during oxidation,con-tributing to a remarkable reduction in the growth rate of the oxide scale to a quarter of the Si-free HESA.Our results demonstrate that Si can be a favorable alloying element to design advanced HESAs with syn-ergistically improved thermal-mechanical performance. | Shaofei Liu Weicheng Xiao Bo Xiao Jiang Ju Yinghao Zhou Yilu Zhao Zengbao Jiao Junhua Luan Qian Li Jinxiong Hou Ji-jung Kai Tao Yang | 2023 | Journal of Materials Science & Technology2023,,26: | 0 |
| 6 | Effect of Pre-deformation on Nanoscale Precipitation and Hardness of a Maraging Stainless Steel显示文摘The effect of pre-deformation on nanoscale precipitates and hardness of a maraging stainless steel strengthened by the coprecipitation of Ni_(3)Ti,Mo-enriched and Cr-enriched precipitates was systematically studied using electron back scattered diffraction,transmission electron microscopy and atom probe tomography(APT).Hardness measurements showed that the hardness of specimen with a deformation ratio of 90%peaked at HV 718 aged for 24 h,which is higher than that in the undeformed specimen(HV 603)aged for 72 h at 480℃.APT characterization revealed that pre-deformation could shorten the incubation time of the Mo-enriched and Cr-enriched precipitates.At the early-aged stage,pre-deformation increased the stain energy that inhibited the nucleation of Ni_(3)Ti precipitates,but accelerated the rejection of Mo from Ni-Ti clusters.Besides,the strengthening model indicated that strain hardening(43%)makes a larger contribution to the hardness at the early-aged condition,while precipitation hardening(58%)has most contribution to the hardness at the peak-aged conditition. | Xinlei Zhou Bin Wang Tianyi Zeng Wei Yan Junhua Luan Wei Wang Ke Yang Zengbao Jiao | 2022 | Acta Metallurgica Sinica(English Letters)2022,35,12: | 0 |
| 7 | Simultaneous enhancement of strength and ductility via microband formation and nanotwinning in an L1_(2)-strengthened alloy显示文摘Metallic alloys with high strength and large ductility are required for extreme structural applications.However,the achievement of ultrahigh strength often results in a substantially decreased ductility.Here,we report a strategy to achieve the strength-ductility synergy by tailoring the alloy composition to control the local stacking fault energy(SFE)of the face-centered-cubic(fcc)matrix in an L1_(2)-strengthened superlattice alloy.As a proof of concept,based on the thermodynamic calculations,we developed a non-equiatomic CoCrNi_(2)(Al_(0.2)Nb_(0.2))alloy using phase separation to create a near-equiatomic low SFE disordered CoCrNi medium-entropy alloy matrix with in situ formed high-content coherent Ni_(3)(Al,Nb)-type ordered nanoprecipitates(∼12 nm).The alloy achieves a high tensile strength up to 1.6 GPa and a uniform ductility of 33%.The low SFE of the fcc matrix promotes the formation of nanotwins and parallel microbands during plastic deformation which could remarkably enhance the strain hardening capacity.This work provides a strategy for developing ultrahigh-strength alloys with large uniform ductility. | Lu Yang Dingshan Liang Zhuo Cheng Ranxi Duan Chuanxin Zhong Junhua Luan Zengbao Jiao Fuzeng Ren | 2024 | Fundamental Research2024,4,1: | 0 |