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| 1 | Bridging from the Sequence to Architecture: Graft Copolymers Engineering via Successive Latent Monomer and Grafting-from Strategies显示文摘The on-demand building copolymer structures,from sequence to architecture,is crucial in understanding the relation between pol-ymer structure and property,meanwhile motivating the innovation of polymer hierarchy.However,the challenge is conspicuous for,complicated polymer structures from inherently intricate polymerization.In this work,copolymers with tailored grafting density and distributions were achieved using successive latent monomer and grafting-from strategies.The hydroxyl group functionalized fu-ran/maleimide adduct(FMOH)was selected as the latent monomer for RAFT polymerization of an array of copolymers with tailored localization of hydroxyl group along the main chain.The hydroxyI group further initiated the ring opening polymerization(ROP)of L-lactide or ε-caprolactone,resulting in a library of multicomponent copolymers via grafting-from strategy.The initiating efficiency reached to-100% with variable molecular weight(21300-58600 Da)and narrow distributions(Ð_(M)<1.25),indicating that such graft copolymers possessed controlled density and distribution of side chains as its linear template.The investigation on thermal properties of the well-defined graft copolymers implied that the precise tailoring over copolymer structures at the molecule level could lead to tunable chemical/physical properties.This work bridged polymer from sequence to architecture,unveiled a new meth-od in creating graft copolymers with programmable structures and provided the insight into the structure/property relationship. | Yajie Zhang Xiaohuan Cao Yang Gao Yujie Xie Zhihao Huang Zhengbiao Zhang Xiulin Zhu | 2021 | Chinese Journal of Chemistry2021，39，5： | 2 |
| 2 | A dual-frequency orthogonal-bi-polarization laser cavity based on a photonic crystal显示文摘 | Ouyang Zhengbiao Cao Enwen Li Chengkuan | 2011 | Journal of Shenzhen University Science and Engineering2011，28，4： | 1 |
| 3 | Morphology of modified starches prepared by different methods显示文摘 | YAN H ZHENGBIAO G U | 2010 | Food Research International2010，43，3： | 1 |
| 4 | Preparation,characterization and properlies of starch-based wood adhesive 显示文摘 | WANG Zhenjiong LI Zhaofeng GU Zhengbiao | 2012 | Carbohydrate Polymers2012，88，2： | 1 |
| 5 | Experimental study on drop formation in liquid-liquid fluidized bed 显示文摘 | PENG Zhengbiao YUAN Zhulin WU Xuan | 2009 | Chemical Engineering Science2009，64，6： | 1 |
| 6 | Preparation, characterization and properties of starch-based wood adhesive 显示文摘 | Wang Zhenjiong Li Zhaofeng Gu Zhengbiao | 2012 | Carbohydrate Polymers2012，88，2： | 1 |
| 7 | Preparation and characterization of novel main-chain azobenzene polymers via step-growth polymerization based on click chemistry显示文摘 | Xiaoqiang Xue Jian Zhu Wei Zhang Zhengbiao Zhang Xiulin Zhu | 2009 | Polymer2009，50，： | 1 |
| 8 | Preparation, characterization and properties of starch-based wood adhesive显示文摘 | Zhenjiong Wang Zhaofeng Li Zhengbiao Gu Yan Hong Li Cheng | 2012 | Carbohydrate Polymers2012，，2： | 1 |
| 9 | Experimental study on drop formation in liquid - liquid fluidized bed 显示文摘 | Peng Zhengbiao Yuan Zhulin Wu Xuan | 2009 | Chemical Engineering Science2009，64，6： | 1 |
| 10 | Nonlinear analysis of a large-orbit coaxial-waveguide cyclotron autoresonance maser amplifier显示文摘 | Ouyang Zhengbiao Zhang Shichang | 2007 | JAppl Phys2007，102，07： | 1 |
| 11 | The effect of electrostatic interactions on pasting properties of potato starch/xanthan gum combinations 显示文摘 | Xuran Cai Yan Hong Zhengbiao Gu | 2011 | Food Research International2011，，10： | 1 |
| 12 | Mechanism study and molecular design in controlled/“living” radical polymerization显示文摘This tutorial review summarizes recent progress in the research field of controlled/'living' radical polymerization (CLRP) from Soochow University.The present paper gives a broad overview of the mechanism study and molecular design in CLRP.The mechanism study in CLRP aided by microwave,initiated by γ-radiation at low temperature,mediated by iron,in reversible addition-fragmentation chain transfer (RAFT) polymerization and the mechanism transfer between different CLRP processes are reviewed and summarized.The molecular design in CLRP,especially in RAFT polymerization for mechanism study,and in achieving tailor-made functional polymers is studied and discussed in the later part. | TU YingFeng,CHENG ZhenPing,ZHANG ZhengBiao,ZHU Jian,ZHANG Wei,ZHOU NianChen,NI PeiHong & ZHU XiuLin College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China | 2010 | Science China Chemistry2010，53，8： | 1 |
| 13 | The effect of electrostatic interactions on pasting properties of potato starch/xanthan gum combinations 显示文摘 | Xuran Cai Yan Hong Zhengbiao Gu | 2011 | Food Research International2011，44，： | 1 |
| 14 | Morphology of modified starches prepared by different methods显示文摘 | Hong Yan G U Zhengbiao | 2010 | Food Research International2010，43，： | 1 |
| 15 | Motion characteristics of binary solids in a liquid fluidised bed with inclined plates显示文摘 | Yanfeng Li Xiangqian Qi Ningbo Li Ai Wang Wenjun Zhang Rongtao Zhu Zhengbiao Peng | 2018 | Particuology2018，16，4： | 1 |
| 16 | Morphology of modified starches prepared by different methods 显示文摘 | Hong Yan G U Zhengbiao | 2010 | Food Research International2010，43，： | 1 |
| 17 | Recent advances in the synthesis of discrete oligomers and polymers: chemistry, strategy and technology显示文摘Nature creates a variety of biomacromolecules, such as DNA and proteins, with precisely defined chain lengths/molecular weights (MWs), monomer sequences, and topologies. In contrast, traditional synthetic polymers have an inhomogeneous composition, variation in chain length. | Yaodi Chen Zhihao Huang Zhengbiao Zhang | 2022 | Science China Chemistry2022，65，6： | 1 |
| 18 | Preparation,characterization and properties of starch-based wood adhesive显示文摘 | Wang Zhenjiong Li Zhaofeng Gu Zhengbiao | 2012 | Carbo Polym2012，88，2： | 1 |
| 19 | Morphology of modified starches prepared by different methods 显示文摘 | Yan H Zhengbiao G | 2009 | Food Research International2009，43，3： | 1 |
| 20 | Morphology of modified starches prepared by different methods 显示文摘 | Yah H Zhengbiao G U | 2010 | Food Research International2010，43，3： | 1 |
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