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| 1 | Recent advances in the precise control of isolated single-site catalysts by chemical methods显示文摘The search for constructing high-performance catalysts is an unfailing topic in chemical fields. Recently, we have witnessed many breakthroughs in the synthesis of single-atom catalysts(SACs) and their applications in catalytic systems. They have shown excellent activity, selectivity, stability, efficient atom utilization and can serve as an efficient bridge between homogeneous and heterogenous catalysis. Currently, most SACs are synthesized via a bottom-up strategy; however, drawbacks such as the difficulty in accessing high mass activity and controlling homogeneous coordination environments are inevitably encountered, restricting their potential use in the industrial area. In this regard, a novel top-down strategy has been recently developed to fabricate SACs to address these practical issues. The metal loading can be increased to 5% and the coordination environments can also be precisely controlled. This review highlights approaches to the chemical synthesis of SACs towards diverse chemical reactions, especially the recent advances in improving the mass activity and well-defined local structures of SACs. Also, challenges and opportunities for the SACs will be discussed in the later part. | Zhijun Li Dehua Wang Yuen Wu Yadong Li | 2018 | National Science Review2018，5，5： | 21 |
| 2 | Microwave-assisted catalytic oxidation of gaseous toluene with a Cu-Mn-Ce/cordierite honeycomb catalyst显示文摘A novel Cu-Mn-Ce/cordierite honeycomb catalyst was prepared by an incipient wetness method and the catalyst was characterized. The active ingredients were present as various spinel species of Cu, Mn and Ce oxides with different valences and they were unevenly dispersed over the surface of the catalyst. The catalytic oxidation of gaseous toluene was primarily investigated using a fixed bed reactor under microwave heating in the continuous flow mode. Under the optimal conditions of 6.7 wt-% loading of the active component, a bed temperature of 200℃, a flow rate of 0.12 m^3 · h^-1 and an initial concentration of toluene of 1000 mg·m^-3, the removal and mineralization efficiencies of toluene were 98% and 70%, respectively. Thus the use of the microwave effectively improved the oxidation of toluene and this is attributed to dipole polarization and hotspot effects. After four consecutive cycles (a total of 1980 min), the Cu-Mn- Ce/cordierite catalyst still exhibited excellent catalytic activity and structural stability, and the toluene removal was higher than 90%. This work demonstrates the possibility of treating volatile organic compounds in exhaust gases by microwave-assisted catalytic oxidation. | Longli Bo Shaoyuan Sun | 2019 | Frontiers of Chemical Science and Engineering2019，13，2： | 11 |
| 3 | A new class of rhodium complexes containing free donor atoms and their intramolecular substitution reaction显示文摘A new class of rhodium complexes with high catalytic activity as well as excellent stability,which was used as catalyst for carbonylation of methanol to acetic acid,is reported.It contains free donor (namely un-coordinated donor) atoms which enable to improve its stability by intramolecular substitution reaction.Its synthesis,characteristic and catalytic reaction were discussed here. | 蒋华 刁开盛 潘平来 张抒峰 袁国卿 | 2000 | Chinese Journal of Chemistry2000，18，5： | 11 |
| 4 | Study on Catalytic Wet Oxidation of H_2S into Sulfur on Fe/Cu Catalyst显示文摘在室温的湿催化氧化与为 H2S 移动包含 ferric, ferrous 和铜离子的答案被调查。实验在二个步过程被执行,并且结果获得了 H2S 的移动效率能总是在与四个筛盘子擦洗列的 300 公里百分之百到达的表演,并且在 200 公里泡罩塔的铁的离子的新生能在吸收匹配消费铁的种类。H2S 的移动,元素硫的生产和 ferric 的新生,铜离子都能同时被完成。除了 O2,没有原料在烟道气体或空气被消费,这个过程没有二次污染和催化剂降级和拥挤的没有问题。给词调音:湿式氧化;H2S;催化;硫;铁的离子;铁的离子; | Junfeng Zhang Zhiquan Tong | 2006 | Journal of Natural Gas Chemistry2006，15，1： | 11 |
| 5 | Hierarchical ZSM-11 with intergrowth structures:Synthesis,characterization and catalytic properties显示文摘Hierarchical ZSM-11 microspheres with intercrystalline mesoporous properties and rod-like crystals intergrowth morphology have been synthesized using a spot of tetrabutylammonium as a single template.XRD,FTIR,SEM,TEM and N2 adsorption analysis revealed that each individual particle was composed of nanosized rod crystals inserting each other and the intercrystalline voids existing among rods gave a significant mesopore size distribution.Steam treatment result demonstrated the excellent hydrothermal stability of samples.Various crystallization modes including constant temperature crystallization (one-stage crystallization) and two-stage temperature-varying crystallization with different 1st stage durations were investigated.The results suggested that the crystallization modes were mainly responsible for the adjustable particle size and textural properties of samples while the small amount of tetrabutylammonium bromide was mainly used to direct the formation of both ZSM-11 framework and its intergrowth morphology.Furthermore,the performance of optimal ZSM-11 as an active component for the catalytic pyrolysis of heavy oil was also investigated.Compared with the commercial pyrolysis catalyst,the hierarchical ZSM-11 catalyst exhibited a high selectivity to desired products(LPG+gasoline+diesel),as well as a much lower dry gas and coke yield,plus a high selectivity and yield of light olefins(C=3 C=4)and very poor selectivity to benzene.Therefore,fully open micropore-mesopore connectivity would make such hierarchically porous ZSM-11 zeolites very attractive for applications in clean petrochemical catalysis field. | Qingjun Yu Chaoyue Cui Qiang Zhang Jing Chen Yang Li Jinpeng Sun Chunyi Li Qiukai Cui Chaohe Yang Honghong Shan | 2013 | Journal of Energy Chemistry2013，22，5： | 10 |
| 6 | Catalytic effect of SrTiO_3 on the hydrogen storage behaviour of MgH_2显示文摘The effects of Sr TiO_3 on the hydrogen storage properties of MgH_2 have been studied for the first time.The onset dehydrogenation temperature of the MgH_2-10 wt% SrTiO_3 is found to be 275 ℃, which is 55 ℃ lower as compared to the as-milled MgH_2. The composite is able to absorb 4.3 wt% of hydrogen in 60 min instead of 1.1 wt% for the as-milled Mg H_2. Meanwhile, the composite is able to release 5.3 wt% of hydrogen in 17 min compared to 1.9 wt% by the as-milled Mg H_2 at 320 ℃. The calculated Eaof the Mg H_2-10 wt% SrTiO_3 is 109 k J/mol, which is 26.3 kJ/mol lower than the calculated Eaof the as-milled MgH_2. The Sr TiO_3 is not decomposed during the ball milling and the re/dehydrogenation processes. The catalytic effect shown by the SrTiO_3 is owing to its ability to change the physical structure of the MgH_2 particles during the ball milling process. | M.S.Yahya M.Ismail | 2019 | Journal of Energy Chemistry2019，28，1： | 10 |
| 7 | Effect of hierarchical ZSM-5zeolite crystal size on diffusion and catalytic performance of n-heptane cracking显示文摘Hierarchical ZSM-5zeolite aggregates with different sizes of nanocrystals were synthesized using different amounts of the mesoporogen 3-aminopropyl- triethoxysilane.The effect of the crystal size on the catalytic cracking of n-heptane was investigated and the Thiele modulus and effectiveness factor were used to determine the reaction rate-limiting step.The crystal size affected the textual properties of the catalysts but not the acidic properties of the catalysts.The reaction rate was first order with respect to the n-heptane concentration.Cracking over hierarchical zeolites with nanocrystal sizes larger than about 50nm took place under transition-limiting conditions,whereas the reaction over hierarchical zeolites with nanocrystal sizes of 15 or 30nm proceeded under reaction control conditions.Hierarchical ZSM-5 zeolite aggregates with smaller nanocrystals had better selectivity for light olefins which can be ascribed to the shorter diffusion path lengths and lower diffusion resistance in these catalysts. Furthermore,these catalysts had lower coking levels which can be attributed to the substantial number of mesopores which prevent the formation of coke precursors. | Shuman Xu Xiaoxiao Zhang Dangguo Cheng Fengqiu Chen Xiaohong Ren | 2018 | Frontiers of Chemical Science and Engineering2018，12，4： | 10 |
| 8 | Mn-Ce-Nb-O_x/P84 catalytic filters prepared by a novel method for simultaneous removal of particulates and NO显示文摘The Mn-Ce-Nb-O_x/P84 catalytic filter for removal of particulates and NO simultaneous was prepared by a novel method(foam coating method). The process parameters including the concentrations of PTFE emulsion, particle size of catalyst and calcination temperature for preparation of catalytic filters were analyzed. In addition, the physical properties and performance for removal of NO(NH_3-SCR) and particulates of Mn-Ce-Nb-O_x/P84 catalytic filter prepared under the optimized parameters, were also systematic studied. Results show that the process parameters had significant influences on stability and performance of catalytic filter, The Mn-Ce-Nb-O_x/P84 catalytic filter prepared by foam coating method under the optimized parameters, has satisfactory physical properties and catalytic performance for removal of NO and particulates at 140-220 ℃. The NO removal efficiency of catalytic filter can reach95.3% at 200 ℃ as the catalyst loading amount is 450 g/m^2, Moreover,the dust removal efficiency of MnGe-Nb-O_x/P84 catalytic filter reaches as high as 99.98%, and the PM2.5 removal efficiency also reaches99.98%. The anti-sulfur performance of Mn-Ce-Nb-O_x catalytic filter is also attractive, after injecting150 ppm SO_2, the NO removal efficiency still retains up to 85%. It is indicated that the foam coating method can not only make a bond of high strength between catalyst and filter, but also make the catalytic filter possessing an excellent and stable performance for removal of NO and particulates. | Bo Yang Qiong Huang Mindong Chen Yuesong Shen Shemin Zhu | 2019 | Journal of Rare Earths2019，37，3： | 10 |
| 9 | Dioxygen Affinities and Catalytic Epoxidation Performanceof Transition-Metal Hydroxamates显示文摘Hydroxamicacidsandtheirderivativesareeasilysynthesizedandhavebeenextensivelyusedasanalyticreagentsandmedicinesl'2.Besides,palladiumhydroxamateswereemployedtocatalyzeolefinspreparingunsaturatedestersbymeansofmolecularoxygen'.Hydroxamicacidcanformsquar... | Hua YANG Sheng Ying QIN Xiao Xia LU(Department of Chemistry, Sichuan University, Chengdu 610064) | 1999 | Chinese Chemical Letters1999，10，1： | 9 |
| 10 | Unlocking the door to highly efficient Ag-based nanoparticles catalysts for NaBH4-assisted nitrophenol reduction显示文摘Ag-based nano particles(NPs)catalysts have recently attracted in creasi ng atte ntion in NaBH4-assisted n itrophe nol reducti on,especially in 4?n itrophe nol(4?NP)reducti on.Moreover,Ag-based NPs catalysts are con sidered to be very promising for practical applicati ons because of their fascinating advantages,e.g.,easy preparation,relatively low cost and less toxicity,high activity and good stability.Basically,the size and shape of Ag NPs are well known as the key factors for achieving highly efficient catalytic reduction of 4-NP.In this review,three highly efficient Ag-based NPs catalysts(supported Ag NPs,anisotropic Ag NPs and bimetallic Ag NPs)are highlighted for the 4-NP reduction,in eluding the catalytic mecha nism and reactio n rate caused by their adjustments in size and shape.Although high catalytic activity has bee n demonstrated by several Ag-based NPs catalysts,further improvement in the catalytic performance is still desired.In terms of the most recent progress in Ag-based NPs catalysts for 4?NP reduction,this review provides a comprehensive assessment on the material selection,synthesis and catalytic characterizations of these catalysts.Moreover,this review aims to correlate the catalytic performance of Ag-based NPs catalysts with their size and shape,guiding the development of novel cost-effective and high-performance catalysts. | Guangfu Liao Yan Gong Liu Zhong Jiasheng Fang Li Zhang Zushun Xu Haiyang Gao Baizeng Fang | 2019 | Nano Research2019，12，10： | 9 |
| 11 | Preparation,characterization and catalytic oxidation property of CeO_2/Cu^(2+)-attapulgite (ATP) nanocomposites显示文摘Cerium oxide(CeO2) coated on copper modified attapulgite clay nanocomoposite(CeO2/Cu2+-ATP) was prepared by homogeneous deposition method.The microstructures of the as-prepared CeO2/Cu2+-ATP nanocomposites were characterized by X-ray diffraction(XRD),energy-dispersive spectrometer(EDS) and transmission electron microscopy(TEM).The results indicated that CeO2 particles with average size of about 5 nm were loaded onto the Cu2+-ATP and were widely dispersed.Comparing the catalytic activity of ATP/CeO2 and CeO2/Cu2+-ATP,the catalytic activity was improved when a small quantity of Cu2+ was introduced.The loading amount of CeO2 and reaction temperature had important effects on decolorization ratio of methyl orange(MO).When the loading amount and reaction temperature were 70% and 338 K,respectively,the decolorization ratio of MO reached over 99%,which showed excellent catalytic activity. | 游静 陈丰 赵晓兵 陈志刚 | 2010 | Journal of Rare Earths2010，28，S1： | 8 |
| 12 | Polarographic catalytic wave of hydrogen——Parallel catalytic hydrogen wave of bovine serum albumin in the presence of oxidants显示文摘A polarographic catalytic hydrogen wave of bovine serum albumin (BSA) at about -1.80 V (vs. SCE) in NH4Cl-NH3@H2O buffer is further catalyzed by such oxidants as iodate, persulfate and hydrogen peroxide, producing a kinetic wave. Studies show that the kinetic wave is a parallel catalytic wave of hydrogen, which resulted from that hydrogen ion is electrochemically reduced and chemically regenerated through oxidation of its reduction product, atomic hydrogen, by oxidants mentioned above. It is a new type of poralographic catalytic wave of protein, which is suggested to be named as a parallel catalytic hydrogen wave. | 过玮 刘利民 林洪 宋俊峰 | 2002 | Science China Chemistry2002，45，2： | 8 |
| 13 | A novel liquid system of catalytic hydrogenation显示文摘On the basis that endothermic aqueous-phase reforming of oxygenated hydrocarbons for H2 produc- tion and exothermic liquid phase hydrogenation of organic compounds are carried out under extremely close conditions of temperature and pressure over the same type of catalyst, a novel liquid system of catalytic hydrogenation has been proposed, in which hydrogen produced from aqueous-phase re- forming of oxygenated hydrocarbons is in situ used for liquid phase hydrogenation of organic com- pounds. The usage of active hydrogen generated from aqueous-phase reforming of oxygenated hy- drocarbons for liquid catalytic hydrogenation of organic compounds could lead to increasing the se- lectivity to H2 in the aqueous-phase reforming due to the prompt removal of hydrogen on the active centers of the catalyst. Meanwhile, this novel liquid system of catalytic hydrogenation might be a po- tential method to improve the selectivity to the desired product in liquid phase catalytic hydrogenation of organic compounds. On the other hand, for this novel liquid system of catalytic hydrogenation, some special facilities for H2 generation, storage and transportation in traditional liquid phase hydrogenation industry process are yet not needed. Thus, it would simplify the working process of liquid phase hy- drogenation and increase the energy usage and hydrogen productivity. | LI XiaoNian XIANG YiZhi | 2007 | Science China Chemistry2007，50，6： | 7 |
| 14 | Bimetallic nanostructures with magnetic and noble metals and their physicochemical applications显示文摘Bimetallic nanomaterials consisting of magnetic metals and noble metals have attracted much interest for their promising potentials in fields such as magnetic sensors, catalysts, optical detection and biomedical applications. Bimetallic nanomaterials synthesized by wet-chemical methods with different architectures including nanoparticles, nanowires or nanotubes and their assemblies are summarized in this review. The particular properties of bimetallic nanomaterials, especially their magnetic, catalytic and optical properties, are presented. The advance in electron microscopy makes it possible to understand the nanostructural materials at much higher level than before, which helps to disclose the relationship between the microstructures and properties qualitatively and quantitatively. | Sibin Duan Rongming Wang | 2013 | Progress in Natural Science:Materials International2013，23，2： | 7 |
| 15 | Recent progresses in application of functionalized graphene sheets显示文摘Graphene,a rapidly rising star on the horizon of material science,has a unique two-dimensional nanostructure as well as exceptional mechanical and electronic properties.Despite its short history,graphene has exhibited great potential in various applications.In order to implement the potential applications,functionalization of graphene is necessary to obtain uniform dispersions for good processability.Two kinds are dominant for functionalization such as covalent and non-covalent methods.The former is based on the formation of covalent bonds,and the latter the interaction among molecules.In this review,we summarized briefly the recent progress of functionalized graphene sheets (FGs) in different fields,such as optoelectronic materials,sensors,energy storage materials,catalytic,reinforcing components and so on,and also prospected the development trend of FGs in the future. | Lü Peng,FENG YiYu,ZHANG XueQuan,LI Yu & FENG Wei School of Materials Science and Engineering,Tianjin University,Tianjin 300072,China | 2010 | Science China(Technological Sciences)2010，53，9： | 7 |
| 16 | Catalytic performance of Zr-doped CuO-CeO2 oxides for CO selective oxidation in H2-rich stream显示文摘Zr-doped CuO-CeO2 catalysts for CO selective oxidation were designed and prepared by the hydrothermal method and coprecipitation. The experimental samples were characterized by means of N2 adsorption-desorption isotherms, powder X-ray diffraction, temperature-programmed reduction and Xray photoelectron spectroscopy. It is observed that the catalyst prepared by hydrothermal method exhibits larger specific surface area, smaller crystalline size and higher dispersion of active components compared with those of the catalyst obtained by coprecipitation. Meanwhile, redox properties of copper oxide are improved significantly and highly dispersed copper species providing CO oxidation sites are present on the surface. Furthermore, adsorptive centers of CO and active oxygen species increase on the copper-ceria interfaces. The Zr-doped CuO-CeO2 catalyst prepared by hydrothermal method possesses superior catalytic activity and selectivity for selective oxidation of CO at low temperature compared with those of the sample prepared by coprecipitation. The temperature corresponding to 50% CO conversion is only 73 ℃ and the temperature span of total CO conversion is expanded from 120 to 160 ℃. | Limin Shi Chuanlei Gao Fenghai Guo Yujing Wang Tiebang Zhang | 2019 | Journal of Rare Earths2019，37，7： | 7 |
| 17 | WO_3/ZrO_2 Strong Acid as a Catalyst for the Decomposition of Chlorofluorocarbon (CFC-12)显示文摘 | HUA Weiming ZHANG Feng MA Zhen TANG Yi GAO Zi | 2000 | Chemical Research in Chinese Universities2000，16，2： | 7 |
| 18 | 钙调磷酸酶催化亚基A基因(PPP3CA)在不同品种鸭发育早期肌肉中的表达及其与肌纤维特性的相关性显示文摘钙调磷酸酶催化亚基A(protein phosphatase 3 catalytic A,PPP3CA)是PPP3C在骨骼肌中的主要亚型,在肌纤维分化中起重要作用。为研究PPP3CA基因在不同品种鸭(Anas platyrhynchos domestica)发育早期肌肉中的表达规律及其与肌纤维特性的相关性,本研究选用生长速度差异较大的金定鸭和高邮鸭,采用实时荧光定量PCR检测鸭13、17、21、25和27胚龄及7日龄胸肌和腿肌中PPP3CA m RNA的表达水平。结果表明,两鸭种同一肌肉组织中PPP3CA m RNA的表达表现出显著的时间特异性,而品种和性别效应并不显著。两鸭品种胸肌和腿肌中PPP3CA m RNA的表达模式虽不同,但均是在13胚龄(13embryonic day,E13 d)时最高,且在出雏后7日龄时极显著高于27胚龄(出雏前)(P<0.01)。胸肌中PPP3CA m RNA在21胚龄时显著低于其他各胚龄或日龄(P<0.01);腿肌中PPP3CA m RNA在21胚龄时表达量较高,27胚龄时降到最低,且极显著低于其他各胚龄或日龄(P<0.01)。相关性分析结果显示,两鸭品种腿肌PPP3CA m RNA表达量与本研究前期检测的肌纤维类型、直径、面积和密度等肌纤维特性呈现不同程度的线性相关;两鸭品种胸肌和腿肌PPP3CA m RNA表达量与均与本研究前期检测的类胰岛素生长因子(insulin-like grow factor-Ⅰ,IGF-Ⅰ)m RNA表达量呈显著的正相关(P<0.05或P<0.01)。初步推测鸭发育早期骨骼肌中PPP3与肌纤维类型和肌纤维生长发育密切相关,与IGF-Ⅰ可能共同参与了对骨骼肌生长发育的调节。本研究结果将有助于了解PPP3在鸭肌肉早期发育中的作用,并为改良鸭肉品质提供理论依据。 | 单艳菊 宋迟 束婧婷 刘宏祥 徐文娟 陶志云 胡艳 李慧芳 | 2015 | 农业生物技术学报2015，23，2： | 7 |
| 19 | Research and Development of Novel Heavy Oil Catalytic Cracking Catalyst RCC-1显示文摘A novel heavy oil catalytic cracking catalyst RCC-1 was developed by using the ultra-stable zeolite, which was hydrothermally treated and modified through cleaning its pores to serve as the active component. The chemical composition and physicochemical properties of RCC-1 catalyst were studied by XRF, BET, pore volume analysis, attrition index analysis, and particle size distribution determination methods, and its catalytic cracking performance was also evaluated by a microreactor for light oil cracking and the ACE device. The test results showed that the new type of heavy oil catalytic cracking catalyst RCC-1 had good physicochemical properties and heavy oil cracking ability, strong anti-metallic contamination capability, good product distribution, good coke selectivity and gasoline selectivity, and excellent reduction of gasoline olefin content characteristics. | Zhang Jiexiao Zhou Yan Xu Yun Tian Huiping | 2014 | China Petroleum Processing & Petrochemical Technology2014，16，4： | 6 |
| 20 | Preparation and hydrogen storage properties of MgH2-trimesic acid-TM MOF(TM=Co,Fe) composites显示文摘Two kinds of metal-organic frameworks(MOFs) based on Co(Ⅱ) and Fe(Ⅱ) as metal ions and trimasic acid(TMA) as organic linker were synthesized. They were used to prepare corresponding Mg H2-TM MOF(TM = Co, Fe) composites via ball-milling. X-ray diffraction analyses show the formation of Mg2 Co and α-Fe phases in Mg H2-TMMOF composites after decomposition. Both of the well dispersed Mg2Co andα-Fe nanoparticles exhibit considerable catalytic efficiency in accelerating the sorption kinetics of Mg H2.The dehydrogenated MgH2-Fe MOF composite shows faster hydriding kinetics than the pure Mg H2 and Mg H2-CoMOF. Meanwhile, the apparent dehydrogenation activation energy(Ed) of the Mg H2-Co MOF and Mg H2-Fe MOF composites are 151.3 ± 9.4 and 142.3 ± 6.5 kJ/mol H2, both of which are lower than that of pure Mg H2(181.4 ± 9.2 kJ/mol H2). The improvement on the sorption kinetics of the Mg H2-TM MOF powders is mainly attributed to the catalytic effects of nano-sized Mg2 Co and α-Fe formed on the surface of Mg/Mg H2 particles. | Zhewen Ma Jianxin Zou Darvaish Khan Wen Zhu Chuanzhu Hu Xiaoqin Zeng Wenjiang Ding | 2019 | Journal of Materials Science & Technology2019，35，10： | 6 |
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