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| 1 | X-ray scintillation in lead-free double perovskite crystals显示文摘Metal halide perovskites have shown great performance for various applications,including solar cells,light emitting diodes,and radiation detectors,but they still suffer from the toxicity of lead and instability.Here we report the use of lanthanide series as trivalent metals to obtain low toxicity and highly stable double perovskites(Cs_2NaLnCl_6,Ln=Tb or Eu)with high scintillation light yield.The crystals exhibit typical f-f transitions of lanthanide cations,while Cs_2NaTbCl_6exhibits strong green photoluminescence,and Cs_2NaEuCl_6exhibits red photoluminescence.Under X-ray radiations,the light yield of Cs_2NaTbCl_6reaches46600 photons MeV^(-1),much higher than that of the commercially used(Lu,Y)_2SiO_5:Ce^(3+)crystals(LYSO,28500 photons MeV^(-1)),and previously reported lead-based perovskites(14000 photons MeV^(-1)).As a new member of lead-free perovskites,lanthanide-based double perovskites open up a new route toward radiation detections and potential medical imaging. | Qingsong Hu Zhenzhou Deng Manchen Hu Anjiang Zhao Yaqi Zhang Zhifang Tan Guangda Niu Haodi Wu Jiang Tang | 2018 | Science China Chemistry2018，61，12： | 7 |
| 2 | A CCCH zinc finger gene regulates doublesex alternative splicing and male development in Bombyx mori显示文摘Recent identification of a Piwi-interacting RNA(piRNA)-initiated sex determination cascade in the silkworm,Bombyx mori,provides novel insights into high diversity of insect sex determination pathways.In this system,the W-chromosome-derived Fem piRNA is the primary sex determination signal.A CCCH-type zinc finger gene Masculinizer(Masc),which is targeted by Fem piRNA-PIWI complex in female animals,is indispensable for male-specific splicing of B.mori doublesex(Bmdsx).Although many genes involved in this cascade have been identified,the regulatory mechanisms of silk-worm sex determination remain to be elucidated.Here we show that another CCCH-type zinc finger gene,Bmznf-2,is a masculinization factor in B.mori.Bmznf-2 shows testisabundant expression and loss of Bmznf-2 function via clustered regularly interspaced short palindromic repeats 1 single-guide RNA-mediated mutagenesis results in feminized differentiation and appearance of the female-specific splicing variants of Bmdsx transcripts in males.In contrast,there is no phenotypic consequence in mutant females.In mutant males,relative messenger RNA expression levels of female-dominant genes such as vitellogenin and sex-specific storage protein I are significantly clevated while several male-dominant genes are significantly down-regulated.Furthermore,male mutants show delayed developmental timing,smaller body sizes of larvae and malformation of moth wings.Our data thus reveal that Bmznf-2 plays an indispensable role in silkworm male sexual differentiation. | Fangying Yang Zhongjie Zhang Bo Hu Ye Yu Anjiang Tan | 2021 | Insect Science2021，28，5： | 1 |
| 3 | Two dehydroecdysone reductases act as fat body-specific 20E catalyzers in Bombyx mori显示文摘Periodic post-embryonic changes in insects, including growth, development and metamorphosis, are strictly controlled by many compounds, including steroid hormones. The biosynthesis and clearance of 20-hydroxyecdysone (20E), the major active form of the insect steroid hormone ecdysone, result in titer fluctuations that help control insect development. The inactivation of 20E in the silkworm Bombyx mori is highly tissue-specific, with CYP18A1 and ecdysone oxidase controlling 20E inactivation specifically in the mid-silk gland and midgut, respectively. Here, we characterized silkworm 3-dehydroecdysone 3α reductase (Bm3DE3α) and 3-dehydroecdysone 3β reductase (Bm3DE3β), two enzymes involved predominantly in the C-3-mediated catalysis of 20E in fat bodies. The ubiquitous and silk gland-specific overexpression of Bm3DE3α decreased the 20E titer, resulting in larval lethality and larval–pupal transition failure, respectively. In contrast, the ubiquitous and mid-silk gland-specific overexpression of Bm3DE3β increased the 20E titer, resulting in larval growth delays and lethality at the mid-fifth larval stage, respectively. Thus, Bm3DE3α and Bm3DE3β mediate fat body-specific steroid hormone metabolism in B. mori, indicating that highly diversified 20E metabolism-related mechanisms exist in different insect species. | Lang You Zhiqian Li Zhongjie Zhang Bo Hu Ye Yu Fangying Yang Anjiang Tan | 2022 | Insect Science2022，29，1： | 1 |
| 4 | Simple and convenient synthesis of 1,3,5-triarylbenzengs from ketones显示文摘 | Huanan Hu Anjiang Zhang Lisheng Ding Xinxiang Lei and Lixue Zhang | 2007 | Journal of chemical research2007，，： | 1 |
| 5 | The Most Comprehensive Database of Ionic Transport Characteristics to Date显示文摘(a)The architecture of the ionic transport characteristics database;(b)the flow chart of the combination of geometric analysis and BVSE method;(c)the architecture of high-throughput screening platform for solid electrolytes.The blue bidirectional lines indicate dataflow Transport characteristics of ionic conductors play a key role in the performance of electrochemical devices[1-2].Any optimization of the performance of the ionic compounds is inseparable from the understanding of the basic transport characteristics.It has been previously established that ion transport properties are defined by framework transport channel geometry,e.g.bottleneck size,and resulting migration energy[3-4]. | HE Bing MI Penghui ZHANG Liwen CHI Shuting YE Anjiang SHI Siqi | 2020 | 材料导报2020，34，20： | 1 |
| 6 | Characteristics and discovery significance of the Upper Triassic–Lower Jurassic marine shale oil in Qiangtang Basin,China显示文摘Mesozoic marine shale oil was found in the Qiangtang Basin by a large number of hydrocarbon geological surveys and shallow drilling sampling.Based on systematic observation and experimental analysis of outcrop and core samples,the deposition and development conditions and characteristics of marine shale are revealed,the geochemical and reservoir characteristics of marine shale are evaluated,and the layers of marine shale oil in the Mesozoic are determined.The following geological understandings are obtained.First,there are two sets of marine organic-rich shales,the Lower Jurassic Quse Formation and the Upper Triassic Bagong Formation,in the Qiangtang Basin.They are mainly composed of laminated shale with massive mudstone.The laminated organic-rich shale of the Quse Formation is located in the lower part of the stratum,with a thickness of 50–75 m,and mainly distributed in southern Qiangtang Basin and the central-west of northern Qiangtang Basin.The laminated organic-rich shale of the Bagong Formation is located in the middle of the stratum,with a thickness of 250–350 m,and distributed in both northern and southern Qiangtang Basin.Second,the two sets of laminated organic-rich shales develop foliation,and various types of micropores and microfractures.The average content of brittle minerals is 70%,implying a high fracturability.The average porosity is 5.89%,indicating good reservoir physical properties to the level of moderate–good shale oil reservoirs.Third,the organic-rich shale of the Quse Formation contains organic matters of types II1 and II2,with the average TOC of 8.34%,the average content of chloroform bitumen'A'of 0.66%,the average residual hydrocarbon generation potential(S1+S2)of 29.93 mg/g,and the Ro value of 0.9%–1.3%,meeting the standard of high-quality source rock.The organic-rich shale of the Bagong Formation contains mixed organic matters,with the TOC of 0.65%–3.10%and the Ro value of 1.17%–1.59%,meeting the standard of moderate source rock.Fourth,four shallow wells(depth of 50–250 m)with oil shows have been found in the organic shales at 50–90 m in the lower part of the Bagong Formation and 30–75 m in the middle part of the Quse Formation.The crude oil contains a high content of saturated hydrocarbon.Analysis and testing of outcrop and shallow well samples confirm the presence of marine shale oil in the Bagong Formation and the Quse Formation.Good shale oil intervals in the Bagong Formation are observed in layers 18–20 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 206.7 m thick,with the maximum and average(S0+S1)of 1.92 mg/g and 1.81 mg/g,respectively.Good shale oil intervals in the Quse Formation are found in layers 4–8 in the lower part of the section,where the shales with(S0+S1)higher than 1 mg/g are 58.8 m thick,with the maximum and average(S0+S1)of 6.46 mg/g and 2.23 mg/g,respectively. | SHEN Anjiang FU Xiaodong ZHANG Jianyong WEI Xuebin HU Anping WANG Jian XIONG Shaoyun FU Xiugen XIE Yuan LIU Siqi LI Xi WANG Xin HE Xunyun QIAO Zhanfeng ZHENG Jianfeng DUAN Junmao | 2023 | Petroleum Exploration and Development2023，50，5： | 0 |
| 7 | Genetic types and distinguished characteristics of dolomite and the origin of dolomite reservoirs显示文摘To find out the origin of dolomite, the precipitation of primary dolomite, and the formation of pores in dolomite, petrologic and geochemical characteristics of typical samples from Sichuan and Tarim Basin were analyzed based on the previous understandings, and three aspects of results were achieved.(1) A classification of dolomite origins based on petrologic features, forming environment, and time sequence was proposed, which shows clear boundaries of diagenetic and characteristic realms and evolved clues between different types of dolomite.(2) Petrographic and geochemical identification marks for different types of dolomite were presented, revealing that the orderly geochemical variation of different types of dolomite is the response to the change of forming environment of dolomite during continuous time sequence.(3) The contribution of dolomitization to the formation of porosity was re-evaluated, revealing that the porosity in dolomite was mostly attributed to the primary pores and supergene dissolution and burial dissolution, and early dolomitization was conducive to the preservation of primary pores. These understandings are of great theoretical significance for identifying the origins and types of dolomite, and can guide the prediction of dolomite reservoirs. | ZHAO Wenzhi SHEN Anjiang QIAO Zhanfeng PAN Liyin HU Anping ZHANG Jie | 2018 | Petroleum Exploration and Development2018，45，6： | 0 |
| 8 | Dolomitization evolution and its effects on hydrocarbon reservoir formation from penecontemporaneous to deep burial environment显示文摘Aiming at the scientific problem that only part of dolomite acts as dolomite reservoir,this paper takes the multiple dolomite-bearing formations in the Tarim and Ordos basins,NW China and Sichuan Basin,SW China as the study object,by means of mineral petrological analysis and geochemical methods including carbonate clumped isotope,U-Pb isotopic dating,etc.,to rebuild the dolomitization pathway and evaluate its effects on reservoir formation.On the basis of detailed rock thin section observation,five dolomitic structural components are identified,including original fabric-retained dolomite(microbial and/or micrite structure),buried metasomatic dolomite I(subhedral-euhedral fine,medium and coarse crystalline structure),buried metasomatic dolomite II(allotriomorphic-subhedral fine,medium and coarse crystalline structure),buried precipitation dolomite and coarse crystalline saddle dolomite.Among them,the first three exist in the form of rocks,the latter two occur as dolomite minerals filling in pores and fractures.The corresponding petrological and geochemical identification templates for them are established.Based on the identification of the five dolomitic structural components,six dolomitization pathways for three types of reservoirs(preserved dolomite,reworked dolomite and limestone buried dolomitization)are distinguished.The initial porosity of the original rock before dolomitization and the dolomitization pathway are the main factors controlling the development of dolomite reservoirs.The preserved dolomite and reworked dolomite types have the most favorable dolomitization pathway for reservoir formation,and are large scale and controlled by sedimentary facies in development and distribution,making them the first choices for oil and gas exploration in deep carbonate formations. | SHEN Anjiang LUO Xianying HU Anping QIAO Zhanfeng ZHANG Jie | 2022 | Petroleum Exploration and Development2022，49，4： | 0 |
| 9 | Revisiting the ionic diffusion mechanism in Li_(3)PS_(4) via the joint usage of geometrical analysis and bond valence method显示文摘Inorganic solid electrolytes have obvious advantages on safety and electrochemical stability compared to organic liquid electrolytes,but the advance on high ionic conductivity of typical electrolytes is still undergoing.Although the first-principles calculation in the ion migration simulation is an important strategy to develop high-performance solid electrolyte,the process is very time-consuming.Here,we propose an effective method by combining the geometrical analysis and bond valance sum calculation to obtain an approximate minimum energy path preliminarily,in parallel to pave the way for the interoperability of low-precision and high-precision ion transport calculation.Taking a promising electrolyte Li_(3)PS_(4) as an example,we revisit its Li-ionic transport behavior.Our calculated Li-ion pathways and the activation energies(the corresponding values:1.09 eV vs.0.88 eV vs.0.86 eV)in γ-,β- and α-Li_(3)PS_(4) are consistent with the ones obtained from the first-principles calculations.The variations of the position of P-ions lead the rearrangement of the host PS_(4) tetrahedron,affecting the diffusion positions of Li-ions and further enabling high Li^(+) conductivity in β-Li_(3)PS_(4). | Li Pan Liwen Zhang Anjiang Ye Shuting Chi Zheyi Zou Bing He Lanli Chen Qian Zhao Da Wang Siqi Shi | 2019 | Journal of Materiomics2019，5，4： | 0 |
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