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| 1 | The influence of substrate and atmosphere on the properties of FeSiB(Cu,Nb) alloy melts显示文摘The surface tensions and contact angles of Fe_(78)Si_9B_(13) and Fe_(73.5)Cu_1Nb_3Si_(13.5)B_9 alloy melts were studied as a function of temperature in various atmospheres(vacuum, Ar and N_2 gas) and on different substrates(Si C, Al_2O_3 and BN). It is indicated that Si_3N_4, NbN, Fe_2 Al B and B_(13)C_2 are generated as new phases at the interface between the melt and substrate, and reactive wetting behaviour exists during the heating process. The surface tensions of two alloy melts on BN substrate both firstly decrease and then increase along with increasing temperature, leading to V-shaped surface tension versus temperature, which results from atomic diffusion effects in the surface layer during the oxidation of BN and formation of C-rich layer. Comparably, the surface tensions on Al_2O_3 and Si C substrates decrease with increasing temperature throughout the entire temperature range. Among three substrates, BN exhibits the mildest wetting behaviour. The vacuum environment has the strongest protective effect on melt stability among the tested atmospheres. These findings enrich our knowledge about the effects of the substrate and atmosphere on Fe-based alloy melts at a high temperature, and provide theoretical reference for designing jet nozzles in melt-spinning techniques. | GAO Hui DONG BangShao ZHONG Ju LI ZongZhen XU Min ZHOU ShaoXiong | 2016 | Science China(Technological Sciences)2016，59，12： | 2 |
| 2 | Influence of clusters in melt on the subsequent glass-formation and crystallization of Fe–Si–B metallic glasses显示文摘The liquid structure of seven representative Fe–Si–B alloys has been investigated by ab initio molecular dynamics simulation focusing on the role of clusters in terms of glass-forming ability(GFA) and crystallization. It is demonstrated that the type of primary phase precipitated from amorphous state under heat treatment is determined by the relative fraction and role of various clusters in melt. The alloy melt shows higher stability and resultantly larger GFA when there is no dominant cluster or several clusters coexist, which explains the different GFAs and crystallization processes at various ratios of Si and B in the Fe–Si–B system. The close correlation among clusters, crystalline phase and GFA is also studied. | Shaoxiong Zhou Bangshao Dong Rui Xiang Guangqiang Zhang Jingyu Qin Xiufang Bian | 2015 | Progress in Natural Science:Materials International2015，25，2： | 1 |
| 3 | The influence of clusters in the melt of Fe_(80)Si_(10)B_(10) alloy on the subsequent glass-formation显示文摘The structure of Fe80Si10B10 alloy melt was investigated by ab initio molecular dynamic simulation from the local atomic environments. It presents that Fe80Si10B10 alloy can be considered as the combination of B-centered prism-like clusters and bcc-like Fe-Si solid solution. The poor glass-forming ability of the alloy has been investigated and can be attributed to the bcc-like environment around Si atoms and the relative high content of pure Fe clusters. | Bangshao Dong Shaoxiong Zhou Jingyu Qin Shaopeng Pan Zhengbang Li | 2013 | Progress in Natural Science:Materials International2013，23，2： | 1 |
| 4 | Effect of Co addition on crystallization and magnetic properties of FeSiBPCu alloy显示文摘The effects of Co addition on the microstructure,crystallization processes and soft magnetic properties of(Fe1 xCox)83Si4B8P4Cu1(x?0.35,0.5,0.65)alloys were investigated.The experimental results demonstrated that the addition of Co decreased the thermal stability against crystallization of the amorphous phase,and thus improved the heat treatment temperature of this alloy.Fe Co Si BPCu nanocrystalline alloys with a dispersedα0-Fe Co phase were obtained by appropriately annealing the as-quenched ribbons at 763 K for 10 min.Theα0-Fe Co with grains size ranging from 9 to 28 nm was identified in primary crystallization.The coercivity(Hc)markedly increased with increasing x and exhibited a minimum value at x0.35,while the saturation magnetic flux density(Bs)shows a slight decrease.The(Fe0.65Co0.35)83Si4B8P4Cu1nanocrystalline alloy exhibited a high saturation magnetic flux density Bsof 1.68 T,a low coercivity,Hcof 5.4 A/m and a high effective permeability meof 29,000 at 1 k Hz. | Rui Xiang Shaoxiong Zhou Bangshao Dong Guangqiang Zhang Zongzhen Li Yanguo Wang Chuntao Chang | 2014 | Progress in Natural Science:Materials International2014，24，6： | 0 |
| 5 | Entropy-driven atomic activation in supercooled liquids and its link to the fragile-to-strong transition显示文摘As a common but critical dynamic crossover in glass-forming liquids(GFLs),the discovery of fragile-to-strong(F-S)transition promises a novel route for understanding supercooled liquid and glass transition.The present work,for the first time,successfully realizes the quantitative prediction of the F-S transition in nine metallic glass-forming liquids,by a counter-intuitive approach that focuses on local atomic activation events,rather than relaxation,upon cooling.The dynamic crossover originates from a disorder-to-order transition by self-regulating behavior of atomic position within a cage controlled by finite atomic activation events,due to the appearance of local cooperative motion of nearest neighborhood atoms.Moreover,the dominant role of entropy in this anomaly has been discovered,and the correspondence between the crossover of configuration entropy involved in activation events and the occurrence of F-S transition has been found.Our work implies that the feature of atomic energy fluctuations reflected by atomic activation events has a close linkage to complex dynamic behaviors of disordered systems. | Wei Chu Zheng Wang Nannan Ren Bangshao Dong Jinhua Yu Pengfei Guan Yanhui Liu Yuanzheng Yue Lina Hu | 2023 | Science China(Physics,Mechanics & Astronomy)2023，66，4： | 0 |
| 6 | The Nanoscale Density Gradient as a Structural Stabilizer for Glass Formation显示文摘The rapid cooling of a metallic liquid(ML)results in short-range order(SRO)among the atomic arrangements and a disordered structure in the resulting metallic glass(MG).These phenomena cause various possible features in the microscopic structure of the MG,presenting a puzzle about the nature of the MGs’microscopic structure beyond SRO.In this study,the nanoscale density gradient(NDG)originating from a sequential arrangement of clusters with different atomic packing densities(APDs),representing the medium-range structural heterogeneity in Zr_(60)Cu_(30)Al_(10)MG,was characterized using electron tomography(ET)combined with image simulations based on structure modeling.The coarse polyhedrons with distinct facets identified in the three-dimensional images coincide with icosahedron-like clusters and represent the spatial positions of clusters with high APDs.Rearrangements of the different clusters according to descending APD order in the glass-forming process are responsible for the NDG that stabilizes both the supercooled ML and the amorphous states and acts as a hidden rule in the transition from ML to MG. | Shaoxiong Zhou Bangshao Dong Yanguo Wang Jingyu Qin Weihua Wang | 2023 | Engineering2023，，10： | 0 |
| 7 | The hidden disintegration of cluster heterogeneity in Fe-based glass-forming alloy melt显示文摘The evolution of liquid metal at high temperature is known much less than their solid states. This is partially due to that the message concerning clusters, metastable phase or heterogeneity in liquid is usually too slight to be traced. Here, we shed some light on the nature of structural evolution of Fe-based glass-forming alloy during overheating process by the investigation of high-temperature melt viscometry and first principles simulations. It was found that a structural transition around 1400 ℃ occurred in the melts of initial homogeneous ingot, heterogeneous ingot and amorphous ribbons jointly, and was confirmed by the results from differential scanning calorimeter(DSC), and ab initio molecular dynamics(AIMD). Combining these results with Fe-Si-B ternary phase diagram and the melting characteristics of Fe-B compounds, it is safe to conclude that the disintegration of Fe_2B type clusters to Fe_3B-type clusters leads to the observed transition. These results offer a significant reference for the preparation and property control of Fe-based amorphous alloys. | Bangshao Dong Shaoxiong Zhou Jingyu Qin Ying Li Hui Chen Yanguo Wang | 2018 | Progress in Natural Science:Materials International2018，28，6： | 0 |
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