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| 1 | The critical role of carbon in marrying silicon and graphite anodes for high-energy lithium-ion batteries显示文摘Increasing the energy density of conventional lithium-ion batteries(LIBs)is important for satisfying the demands of electric vehicles and advanced electronics.Silicon is considered as one of the most-promising anodes to replace the traditional graphite anode for the realization of high-energy LIBs due to its extremely high theoretical capacity,although its severe volume changes during lithiation/delithiation have led to a big challenge for practical application.In contrast,the co-utilization of Si and graphite has been well recognized as one of the preferred strategies for commercialization in the near future.In this review,we focus on different carbonaceous additives,such as carbon nanotubes,reduced graphene oxide,and pyrolyzed carbon derived from precursors such as pitch,sugars,heteroatom polymers,and so forth,which play an important role in constructing micrometersized hierarchical structures of silicon/graphite/carbon(Si/G/C)composites and tailoring the morphology and surface with good structural stability,good adhesion,high electrical conductivity,high tap density,and good interface chemistry to achieve high capacity and long cycling stability simultaneously.We first discuss the importance and challenge of the co-utilization of Si and graphite.Then,we carefully review and compare the improved effects of various types of carbonaceous materials and their associated structures on the electrochemical performance of Si/G/C composites.We also review the diverse synthesis techniques and treatment methods,which are also significant factors for optimizing Si/G/C composites.Finally,we provide a pertinent evaluation of these forms of carbon according to their suitability for commercialization.We also make far-ranging suggestions with regard to the selection of proper carbonaceous materials and the design of Si/G/C composites for further development. | Jingxing Wu Yinliang Cao Haimin Zhao Jianfeng Mao Zaiping Guo | 2019 | Carbon Energy2019，1，1： | 18 |
| 2 | Hydrothermal Synthesis of Molybdenum Disulfide for Lithium Ion Battery Applications显示文摘Molybdenum disulfide nanoflakes were synthesized by a simple hydrothermal process using sodium molybdate and thiourea as reactants at a relatively low temperature. X-ray diffraction(XRD) and transmission elec-tron microscopy(TEM) indicate that the samples have the structure of 2H-MoS2 and the morphology of nanoflakes with the average thickness around 5-10 nm. The results of electrochemical properties indicate that the morphology and size of MoS2 particles have effects on their capacity when they are used as the anode for lithium ion battery. The as-prepared MoS2 samples have high reversible discharge capacity up to 994.6 mA·h·g-1 for the MoS2-1 elec-trode and 930.1 mA·h·g-1 for the MoS2-2 electrode and show excellent cycling performances. The MoS2-1 electrode has a better cycling stability than the MoS2-2 electrode due to their difference in the uniformity of the samples. | WANG Shiquan LI Guohua DU Guodong JIANG Xueya FENG Chuanqi GUO Zaiping KIM Seung-Joo | 2010 | Chinese Journal of Chemical Engineering2010，18，6： | 9 |
| 3 | SnSb@carbon nanocable anchored on graphene sheets for sodium ion batteries显示文摘有唯一的 nanostructures 的材料的开发是为在钠离子电池的钠存储的改进的有效策略完成稳定的骑车的性能和好率能力。在这个工作, SnSbcore/carbon-shell nanocables 直接在 graphene 表(GS ) 上抛锚了被热水的技术和化学蒸汽免职综合。同时的碳涂层和 SnSb 合金的封装为在钠离子电池减轻卷变化问题是有效的。在在钠离子电池为 SnSb 优化电解质以后,优化同轴的 SnSb/carbon nanocable/GS (SnSb/CNT@GS ) nanostructure 在 1 M NaClO 表明了稳定的骑车的能力和率性能 < 潜水艇 class= “ a-plus-plus ” > 有丙烯碳酸盐(PC ) 的 4 +5% fluoroethylene 碳酸盐(FEC ) 。SnSb/CNT@GS 电极能为多达 100 个周期保留 360 mAh/g 的一个能力,它是 71% 理论能力。这比在测试的另外的三电解质高( 1 M NaClO <潜水艇class=“ a-plus-plus ”> 4 在 PC , 1 M NaClO <潜水艇class=“ a-plus-plus ”>在 PC/FEC ( 1:1 v/v )和 1 M NaPF 的 4 <潜水艇class=“ a-plus-plus ”> 6 + PC ),并且比没有 graphene 的增加的样品的高。好电气化学的性能能被归因于禁止 SnSb 粒子,以及它的高传导性的凝块的外部碳 nanocable 层和 graphene 提供的有效缓冲。 | Li Li Kuok Hau Seng Dan Li Yongyao Xia Hua Kun Liu Zaiping Guo | 2014 | Nano Research2014，7，10： | 9 |
| 4 | Metal chalcogenides for potassium storage显示文摘Potassium-based energy storage technologies,especially potassium ion batteries(PIBs),have received great interest over the past decade.A pivotal challenge facing high-performance PIBs is to identify advanced electrode materials that can store the large-radius K+ions,as well as to tailor the various thermodynamic parameters.Metal chalcogenides are one of the most promising anode materials,having a high theoretical specific capacity,high in-plane electrical conductivity,and relatively small volume change on charge/discharge.However,the development of metal chalcogenides for PIBs is still in its infancy because of the limited choice of high-performance electrode materials.However,numerous efforts have been made to conquer this challenge.In this article,we overview potassium storage mechanisms,the technical hurdles,and the optimization strategies for metal chalcogenides and highlight how the adjustment of the crystalline structure and choice of the electrolyte affect the electrochemical performance of metal-chalcogenide-based electrode materials.Other potential potassium-based energy storage systems to which metal chalcogenides can be applied are also discussed.Finally,future research directions focusing on metal chalcogenides for potassium storage are proposed. | Jingwen Zhou Ye Liu Shilin Zhang Tengfei Zhou Zaiping Guo | 2020 | InfoMat2020，2，3： | 6 |
| 5 | In situ growth of NiS_(2) nanosheet array on Ni foil as cathode to improve the performance of lithium/sodium-sulfur batteries显示文摘The NiS;nanosheet array on Ni foil(NiS2/NF)was prepared using an in situ growth strategy and sulfidation method and was used as the cathode of lithium sulfur battery.The unique nanostructure of the NiS;nanosheet array can provide abundant active sites for the adsorption and chemical action of polysulfides.Compared with the sulfur powder coated pure NF(pure NF-S)for lithium sulfur battery,the sulfur powder coated NiS_(2)/NF(NiS_(2)/NF-S)electrode exhibits superior electrochemical performance.Specifically,the NiS_(2)/NF-S delivered a high reversible capacity of 1007.5 m Ah g^(-1) at a current density of 0.1 C(1 C=1675 mA g^(-1))and kept 74.5% of the initial capacity at 1.0 C after 200 cycles,indicating the great promise of NiS_(2)/NF-S as the cathode of lithium sulfur battery.In addition,the NiS_(2)/NF-S electrode also showed satisfactory electrochemical performance when used as the cathode for sodium sulfur battery. | FAN MouPing CHEN YuanMao KE Xi HUANG ZeXi CHEN YouChen WU WenLi QU XiaoFeng SHI ZhiCong GUO ZaiPing | 2022 | Science China(Technological Sciences)2022，65，1： | 2 |
| 6 | Ultra-light and flexible pencil-trace anode for high performance potassium-ion and lithium-ion batteries显示文摘Engineering design of battery configurations and new battery system development are alternative approaches to achieve high performance batteries. A novel flexible and ultra-light graphite anode is fabricated by simple friction drawing on filter paper with a commercial 8 B pencil.Compared with the traditional anode using copper foil as current collector, this innovative current-collector-free design presents capacity improvement of over 200% by reducing the inert weight of the electrode. The as-prepared pencil-trace electrode exhibits excellent rate performance in potassium-ion batteries(KIBs), significantly better than in lithium-ion batteries(LIBs), with capacity retention of 66% for the KIB vs. 28% for the LIB from 0.1 to 0.5 A g^(-1). It also shows a high reversible capacity of ~230 mAh g^(-1) at 0.2 A g^(-1), 75% capacity retention over350 cycles at 0.4 A g^(-1)and the highest rate performance(based on the total electrode weight) among graphite electrodes for K+ storage reported so far. | Zhixin Tai Yajie Liu Qing Zhang Tengfei Zhou Zaiping Guo Hua Kun Liu Shi Xue Dou | 2017 | Green Energy & Environment2017，2，3： | 2 |
| 7 | Supe- rior stability and high capacity of restacked molybdenum disulfide as anode material for lithium ion batteries 显示文摘 | Du Guodong Guo Zaiping Wang Shiquan | 2010 | Chemical Communications2010，46，7： | 1 |
| 8 | Accelerating cal-deron multiplicative preconditionerwith multi - gradeadaptive cross approximation algorithm显示文摘 | Guo Han Hu Jun Nie Zaiping | 2011 | APSUR-SI2011，3，8： | 1 |
| 9 | LiCoO2 cathode thin film fabricated by RF sputtering for lithium ion microbatteries显示文摘 | Zhu Xianjun Guo Zaiping Du Guodong | 2010 | Surface and Coatings Technology2010，204，11： | 1 |
| 10 | Controlled synthesis of α-Fe 2 O 3 nanostructures and their size-dependent electrochemical properties for lithium-ion batteries显示文摘 | Yanna NuLi Rong Zeng Peng Zhang Zaiping Guo Huakun Liu | 2008 | Journal of Power Sources2008，，2： | 1 |
| 11 | Dehy- drogenation promotion of LiBH4 ~ NH3 through heating in ammonia or mixing withmetal hydrides 显示文摘 | Guo Yanhui Sun Weiwei Guo Zaiping | 2010 | The Journal of Physical Chemistry C2010，114，12： | 1 |
| 12 | A new class of cathode materials for rechargeable magnesium batteries: organosulfur compounds based on sulfur-sulfur bonds显示文摘 | NuLi Yanna Guo Zaiping Liu Huakun | 2007 | Electrochemistry Communications2007，9，8： | 1 |
| 13 | Confining Sulfur in Double‐Shelled Hollow Carbon Spheres for Lithium–Sulfur Batteries显示文摘 | Chaofeng Zhang Hao Bin Wu Changzhou Yuan Zaiping Guo Xiong Wen (David) Lou | 2012 | Angew. Chem. Int. Ed2012，，38： | 1 |
| 14 | Lay- erd δ-MnO2 as positive electrode for lithium intercala- tion 显示文摘 | Du Guodong Wang Jieqiang Guo Zaiping | 2011 | Materials Letters2011，65，： | 1 |
| 15 | Challenges and prospects of lithium-CO_(2) batteries显示文摘The key role played by carbon dioxide in global temperature cycles has stimulated constant research attention on carbon capture and storage.Among the various options,lithium-carbon dioxide batteries are intriguing,not only for the transformation of waste carbon dioxide to value-added products,but also for the storage of electricity from renewable power resources and balancing the carbon cycle.The development of this system is still in its early stages and faces tremendous hurdles caused by the introduction of carbon dioxide.In this review,detailed discussion on the critical problems faced by the electrode,the interface,and the electrolyte is provided,along with the rational strategies required to address these problematic issues for efficient carbon dioxide fixation and conversion.We hope that this review will provide a resource for a comprehensive understanding of lithium-carbon dioxide batteries and will serve as guidance for exploring reversible and rechargeable alkali metal-based carbon dioxide battery systems in the future. | Shilin Zhang Liang Sun Qining Fan Fangli Zhang Zhijie Wang Jinshuo Zou Shiyong Zhao Jianfeng Mao Zaiping Guo | 2022 | Nano Research Energy2022，1，1： | 1 |
| 16 | Free-standing V205 elec- trode for flexible lithium ion batteries 显示文摘 | Seng K H Liu Jun Guo Zaiping | 2011 | Electrochemistry Com- munications2011，13，5： | 1 |
| 17 | Synthesis and electrochemical properties of non-stoichiometric Li–Mn-spinel (Li 1.02 M x Mn 1.95 O 4? y F y ) for lithium ion battery application显示文摘 | Chuanqi Feng Hua Li Chaofeng Zhang Zaiping Guo Huimin Wu Jing Tang | 2011 | Electrochimica Acta2011，，： | 1 |
| 18 | Innentitelbild: Confining Sulfur in Double‐Shelled Hollow Carbon Spheres for Lithium–Sulfur Batteries (Angew. Chem. 38/2012)显示文摘 | Chaofeng Zhang Hao Bin Wu Changzhou Yuan Zaiping Guo Xiong Wen (David) Lou | 2012 | Angew Chem2012，，38： | 1 |
| 19 | Ultra-fine porous SnO2 nanopowder prepared via a molten salt process: A highly efficient anode material for lithium-ion batteries 显示文摘 | Guo Zaiping Du Guodong Yanna Nuli | 2009 | J Mater Chem2009，19，： | 1 |
| 20 | Synthesis of molybdenum disulfide (MoS 2 ) for lithium ion battery applications显示文摘 | Chuanqi Feng Jun Ma Hua Li Rong Zeng Zaiping Guo Huakun Liu | 2009 | Materials Research Bulletin2009，，9： | 1 |
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