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| 1 | Interface electron collaborative migration of Co–Co3O4/carbon dots:Boosting the hydrolytic dehydrogenation of ammonia borane显示文摘Ammonia borane(AB)is an excellent candidate for the chemical storage of hydrogen.However,its practical utilization for hydrogen production is hindered by the need for expensive noble-metal-based catalysts.Herein,we report Co-Co3O4 nanoparticles(NPs)facilely deposited on carbon dots(CDs)as a highly efficient,robust,and noble-metal-free catalyst for the hydrolysis of AB.The incorporation of the multiinterfaces between Co,Co3O4 NPs,and CDs endows this hybrid material with excellent catalytic activity(rB=6816 mLH2 min^-1 gCo^-1)exceeding that of previous non-noble-metal NP systems and even that of some noble-metal NP systems.A further mechanistic study suggests that these interfacial interactions can affect the electronic structures of interfacial atoms and provide abundant adsorption sites for AB and water molecules,resulting in a low energy barrier for the activation of reactive molecules and thus substantial improvement of the catalytic rate. | Han Wu Min Wu Boyang Wang Xue Yong Yushan Liu Baojun Li Baozhong Liu Siyu Lu | 2020 | Journal of Energy Chemistry2020，29，9： | 7 |
| 2 | Co-Co304@carbon core-shells derived from metal-organic framework nanocrystals as efficient hydrogenevolution catalysts显示文摘Controllable pyrolysis of metal-organic frameworks (MOFs) in confined spacesis a promising strategy for the design and development of advanced functionalmaterials. In this study, Co-C0304@carbon composites were synthesized viapyrolysis of a Co-MOFs@glucose polymer (Co-MOFs@GP) followed by partialoxidation of Co nanoparticles (NPs). The pyrolysis of Co-MOFs@GP generated acore-shell structure composed of carbon shells and Co NPs. The controlled partialoxidation of Co NPs formed Co-Co304 heterojunctions confined in carbon shells.Compared with Co-MOFs@GP and Co@carbon-n (Co@C-n), Co-C0304@carbon-n(Co-Co304@C-n) exhibited higher catalytic activity during NaBH4 hydrolysis.Co-C0304@C-II provided a maximum specific H2 generation rate of5,360 mL.min-l.gco-1 at room temperature due to synergistic interactionsbetween Co and C0304 NPs. The Co NPs also endowed Co-C0304@C-n with theferromagnetism needed to complete the magnetic momentum transfer process. | Yanyan Liu Guosheng Han Xiaoyu Zhang Congcong Xing Chenxia Du Huaqiang Cao Baojun Li | 2017 | Nano Research2017，10，9： | 5 |
| 3 | Generation of strong magnetic fields with a laser-driven coil显示文摘As a promising new way to generate a controllable strong magnetic field, laser-driven magnetic coils have attracted interest in many research fields. In 2013, a kilotesla level magnetic field was achieved at the Gekko XⅡ laser facility with a capacitor–coil target. A similar approach has been adopted in a number of laboratories, with a variety of targets of different shapes. The peak strength of the magnetic field varies from a few tesla to kilotesla, with different spatiotemporal ranges. The differences are determined by the target geometry and the parameters of the incident laser. Here we present a review of the results of recent experimental studies of laser-driven magnetic field generation, as well as a discussion of the diagnostic techniques required for such rapidly changing magnetic fields. As an extension of the magnetic field generation, some applications are discussed. | Zhe Zhang Baojun Zhu Yutong Li Weiman Jiang Dawei Yuan Huigang Wei Guiyun Liang Feilu Wang Gang Zhao Jiayong Zhong Bo Han Neng Hua Baoqiang Zhu Jianqiang Zhu Chen Wang Zhiheng Fang Jie Zhang | 2018 | High Power Laser Science and Engineering2018，6，3： | 2 |
| 4 | Enhanced interfacial polarization of defective porous carbon confined CoP nanoparticles forming Mott-Schottky heterojunction for efficient electromagnetic wave absorption显示文摘Integrating heterogeneous interface through nanostructure design and interfacial modification is essential to realize strengthened interfacial polarization relaxation in electromagnetic wave absorption.However,an in-depth comprehension of the interfacial polarization behavior at hetero-junction/interface is highly desired but remains a great challenge.Herein,a Mott-Schottky heterojunction consisting of honeycomb-like porous N-doped carbon confined CoP nanoparticles(CoP@HNC)is designed to elevate the interfacial polarization strength.Simultaneously,corresponding electron migration and redistribution between the heterointerface of defective carbon and CoP nanoparticles are revealed.The significant difference in the work function on both sides of heterogeneous interface boosts the interfacial polarization in high frequency region.Furthermore,the relevant spectroscopic characterizations demonstrate that electron spontaneously migrates from CoP to N-doped carbon at the heterointerface,thereby contributing to the accumulation of electron on defective carbon side and the distribution of hole on CoP side.Impressively,benefitting from the synergistic effects of three-dimensional porous conductive carbon skeleton,foreign N heteroatoms,special CoP nanoparticles,and the resultant CoP/N-doped carbon Mott-Schottky heterojunction,the CoP@HNC exhibits remarkable electromagnetic wave absorption performances with minimum reflection loss up to−60.8 dB and the maximum effective absorption bandwidth of 4.96 GHz,which is superior to most of recently reported transition metal phosphides microwave absorbing composites.The present work opens a new avenue for designing heterogeneous interface to realize strengthened microwave absorption capability and also reveals the in-depth influence of interface structure on electromagnetic wave absorption. | Baojun Wang Fangzhi Huang Hao Wu Zijie Xu Shipeng Wang Qinghua Han Fenghua Liu Shikuo Li Hui Zhang | 2023 | Nano Research2023，16，3： | 2 |
| 5 | Microstructural evolution of Fe-32% Ni alloy during large strain multi-axial forging 显示文摘 | Han Baojun Xu Zhou | 2007 | Mater Sci Eng A2007，447，12： | 1 |
| 6 | Grain refinement under multi-axial forging in Fe-32%Ni alloy显示文摘 | Han Baojun Xu Zhou | 2008 | J Alloy Compd2008，457，12： | 1 |
| 7 | Martensitic transformation behavior of large strain deformed Fe-32%Ni alloy显示文摘 | Han Baojun Xu Zhou | 2006 | Mater Sci Eng A2006，431，12： | 1 |
| 8 | Martensite microstructure transformed from ultra-fine grained Fe-32%Ni alloy austenite显示文摘 | Han Baojun Xu Zhou | 2008 | Mater Sci Eng A2008，487，12： | 1 |
| 9 | Co_(2)N Nanoparticles Anchored on N-Doped Active Carbon as Catalyst for Oxygen Reduction Reaction in Zinc–Air Battery显示文摘The development of efficient catalytic electrode toward oxygen reduction reaction(ORR)is still a great challenge for the wide use of zinc–air batteries.Herein,Co_(2)N nanoparticles(NPs)anchored on N-doped carbon from cattail were verified with excellent catalytic performances for ORR.The onset and half-wave potentials over the optimal catalyst reach to 0.96 V and 0.84 V,respectively.Current retention rates of 96.8%after 22-h test and 98.8%after running 1600 s were obtained in 1 M methanol solution.Density functional theory simulation proposes an apparently increased electronic states of Co_(2)N in N-doped carbon layer close to the Fermi level.Higher charge density,favorable adsorption,and charge transfer of intermediates originate from the coexistence of Co_(2)N NPs and N atoms in carbon skeleton.The superior catalytic activity of composites also was confirmed in zinc–air batteries.This novel catalytic property and controllable preparation approach of Co_(2)Ncarbon composites provide a promising avenue to fabricate metal-containing catalytically active carbon from biomass. | Xianli Wu Guosheng Han Hao Wen Yanyan Liu Lei Han Xingyu Cui Jiajing Kou Baojun Li Jianchun Jiang | 2022 | Energy & Environmental Materials2022，5，3： | 1 |
| 10 | Grain refinement under multi-axial forging in Fe–32%Ni alloy显示文摘 | Baojun Han Zhou Xu | 2007 | Journal of Alloys and Compounds2007，，1： | 1 |
| 11 | Thermal-physiological Strategies Underlying the Sympatric Occurrence of Three Desert Lizard Species显示文摘Sympatric reptiles are the ideal system for investigating temperature-driven coexistence. Understanding thermally physiological responses of sympatric lizards is necessary to reveal the physiological mechanisms that underpin the sympatric occurrence of reptiles. In this study, we used three lizard species, Eremias argus, E. multiocellata, and Phrynocephalus przewalskii, which are sympatric in the Inner Mongolia desert steppe, as a study system. By comparing their resting metabolic rates(RMR) and locomotion at different body temperatures, we aimed to better understand their physiological responses to thermal environments, which may explain the sympatric occurrence of these lizards. Our results showed that E. argus had significantly higher RMR and sprint speed than E. multiocellata, and higher RMR than P. przewalskii. In addition, the optimal temperature that maximized metabolic rates and locomotion for E. argus and E. multiocellata was 36°C, whereas for P. przewalskii it was 39°C. Our study revealed the physiological responses to temperatures that justify the sympatric occurrence of these lizards with different thermal and microhabitat preferences and active body temperatures. Eremias argus and E. multiocellata, which have lower body temperatures than P. przewalskii, depend on higher RMR and locomotion to compensate for their lower body temperatures in field conditions. Our study also highlights the importance of using an integrative approach, combining behavior and physiology, to explore the basis of sympatric occurrence in ectothermic species. | Xueqing WANG Shuran LI Li LI Fushun ZHANG Xingzhi HAN Junhuai BI Baojun SUN | 2019 | Asian Herpetological Research2019，10，3： | 1 |
| 12 | Oligomerization and Polymerization of Ethylene Initiated by a Novel Ni(Ⅱ)-Based Acetyliminopyridine Complexes as Single-Site Catalysts显示文摘新奇的镍( II )基于 acetyliminopyridine 建筑群 1b , 2b , 3b ( 1 ¨C 3b )从 ligands 1a 被综合, 2a , 3a ( 1-3a )并且[ NiCl2 ( DME )],是为为乙烯 oligomerization 和聚合反应是必要的催化剂的合适的先锋,由 methylaluminoxane (毛)激活。对待 MAO 1 ¨ C 3b 介绍一个活跃催化中心,它可以分别地生产线性 | á - 石蜡和聚乙烯的 oligomerize 和聚合乙烯。被获得的 oligomers 的分子量分布在对 oligomers 的 Schulz-Flory 规则的好同意 > C4。3b-MAO 建筑群的活动是 6.3 ? á 10 (7 ) 在 50 点的 g/(molNi-h )??6 号元素碳的化学符号。oligomers 的活动和分子量分布在催化剂先锋的结构上显示出重要信赖。给词调音:oligomerization;聚合;乙烯;镍(II ) 基于催化剂;| á - | Baojun Zhang Yanji Wang Gang Wang Jun Cao Shukun Sun Lihua Xing Yongcheng Sun Yunguang Han | 2007 | Journal of Natural Gas Chemistry2007，16，1： | 1 |
| 13 | Saponins from Platycodi Radix ameliorate high fat diet-induced obesity in Mice 显示文摘 | Han Likun Zheng Yinan Xu Baojun | 2002 | J Nutr2002，132，： | 1 |
| 14 | Platycodi Radix affects lipid metabolism in mice with high fat diet-induced Obesity显示文摘 | Han Likun Xu Baojun Yoshiyuki Kimura | 2000 | J Nutr2000，130，11： | 1 |
| 15 | Metallogenic characteristics of the region of Northwest Hebei and analysis of ore prospecting potential in its peripheries显示文摘The region of Northwest Hebei is an area where Au-Ag polymetallic ore depsits are concentrated in Hebei Province. There were divided the Au ore-concentrated region with the magmatic-metamorphic diamictite zone as the center and the perpheral cover-strata zone and Ag-polymetallic metallogenic zone along the line of Xuanhua-Songli-Chicheng. Research on mantle branch structure indicates that Au-Ag polymetallic ore-forming materials come mainly from the deep interior of the Earth. The ore-forming materials tend to migrate upwards through the multi-stage evolution of mantle plume, and are concentrated as ores in the favourable tectonic expansion zone of a mantle branch structure. As viewed in plane, from the center to the periphery and as viewed in space, from the lower part to the upper part there exists Au-Ag-Pb-Zn zonation, as evidenced by drilling data from a number of mines. So, there is still great potential for ore prospecting in the region of Northwest Hebei. | SUN Aiqun NIU Shuyin WANG Baode HAN Yuchou WEI Minhui MA Baojun ZHAO Zhiyuan XIA Dong | 2011 | Chinese Journal Of Geochemistry2011，30，1： | 1 |
| 16 | Grain refinement mechanism of Fe-Ni alloys during muhiaxial forging 显示文摘 | Han Baojun Xu Zhou | 2006 | Mater Sci Tech2006，22，11： | 1 |
| 17 | Microstructural evolution of Fe-32%Ni alloy during large strain multi-axial forging显示文摘 | Han Baojun Xu Zhou | 2007 | Mater Sci Eng A2007，447，12： | 1 |
| 18 | Microstructural evolution of Fe 32%Ni alloy during large strain multi-axial forging显示文摘 | Han Baojun Xu Zhou | 2007 | Materials Science and Engineering2007，447，： | 1 |
| 19 | Grain refinement under multi-axial forging in Fe-32%Ni alloy显示文摘 | Han Baojun Xu Zhou | 2008 | J Alloy Comp2008，457，12： | 1 |
| 20 | An Algorithm of Adaptive Fuzzy Enhancement of Infrared Image Sequence for Low SNR显示文摘 | Zhao Baojun Han Yueqiu Mao Erke | 2002 | Chinese Journal of Electronics2002，11，2： | 1 |
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