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| 1 | 毛竹预处理黑液木质素和酶解木质素的结构与热学性质显示文摘【目的】研究毛竹低用碱量硫酸盐法处理的黑液木质素和残留在浆料中木质素结构特征和热学性质,为竹材工业木质素利用提供理论参考。【方法】采用12%有效碱的硫酸盐法处理毛竹竹屑,通过酸化和酶解得到硫酸盐木质素(KL)和酶解木质素(EHL)。利用有机溶剂对2种木质素进行纯化后,采用凝胶渗透色谱分析仪(GPC)测定木质素分子质量大小,运用核磁共振定量碳谱(^(13)C谱)、二维碳氢相关谱(2D-HSQC)和定量磷谱(^(31)P谱)对木质素结构的键型连接、内部连接键含量和官能团含量进行定量分析,应用热重分析仪(TGA)和差示扫描量热仪(DSC)分别对木质素的热稳定性和玻璃化转变温度进行分析比较。【结果】GPC测定结果表明,KL的重均分子质量为5 414 g·mol^(-1),低于EHL的重均分子质量(7 673 g·mol^(-1))。利用定量^(31)P谱,结合定量^(13)C谱和2DHSQC谱分析可知,EHL中的脂肪族羟基含量(4.87/100 C_9)高于KL中的脂肪族羟基含量(3.13/100 C_9),而总酚羟基含量(1.58/100 C_9)低于KL中的总酚羟基含量(3.09/100 C_9);EHL内部木质素单元连接键含量高于KL内部木质素单元连接键含量,EHL的β—O—4芳基醚键、β—β、β—5和β—1含量分别为30.85/100C_9、7.43/100C_9、2.40/100C_9和0.19/100C_9,而KL这些连接键含量仅为11.75/100C_9、2.35/100C_9、0.71/100C_9和0.09/100C_9。热学性质分析表明,在加热条件下KL和EHL的木质素玻璃化转变温度分别为135℃和162℃,最大失重率温度分别为339℃和361℃。【结论】竹屑经低用碱量硫酸盐法预处理后,溶解在黑液中的木质素分子质量大小、内部连接键含量均低于残留在浆料中木质素的含量;而黑液木质素具有更多的酚羟基和羧基,脂肪族羟基含量较少。黑液木质素可能比残留在浆料中的木质素更有优势用来制备热塑性材料,因为其具有更低热稳定性和低玻璃化转变温度的特性。 | 黄曹兴 何娟 赖晨欢 Narron Robert Chang Houmin 勇强 | 2018 | 林业科学2018，54，3： | 12 |
| 2 | Occurrence of the Iron–rich Melt in the Heijianshan Iron Deposit, Eastern Tianshan, NW China: Insights into the Origin of Volcanic Rock–hosted Iron Deposits显示文摘Long-standing controversy persists over the presence and role of iron–rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron–rich and silica–rich melt inclusions observed in thin-sections are considered as direct evidence for the presence of iron-rich melt, yet unequivocal outcrop-scale evidence of iron-rich melts are still lacking in volcanic rock-hosted iron deposits. Submarine volcanic rock-hosted iron deposits, which are mainly distributed in the western and eastern Tianshan Mountains in Xinjiang, are important resources of iron ores in China, but it remains unclear whether iron-rich melts have played a role in the mineralization of such iron ores. In this study, we observed abundant iron-rich agglomerates in the brecciated andesite lava of the Heijianshan submarine volcanic rock–hosted iron deposit, Eastern Tianshan, China. The iron-rich agglomerates occur as irregular and angular masses filling fractures of the host brecciated andesite lava. They show concentric potassic alteration with silicification or epidotization rims, indicative of their formation after the wall rocks. The iron-rich agglomerates have porphyritic and hyalopilitic textures, and locally display chilled margins in the contact zone with the host rocks. These features cannot be explained by hydrothermal replacement of wall rocks(brecciated andesite lava) which is free of vesicle and amygdale, rather they indicate direct crystallization of the iron-rich agglomerates from iron-rich melts. We propose that the iron-rich agglomerates were formed by open-space filling of volatile-rich iron-rich melt in fractures of the brecciated andesite lava. The iron-rich agglomerates are compositionally similar to the wall-rock brecciated andesite lava, but have much larger variation. Based on mineral assemblages, the iron-rich agglomerates are subdivided into five types, i.e., albite-magnetite type, albite-K-feldsparmagnetite type, K-feldspar–magnetite type, epidote-magnetite type and quartz-magnetite type, representing that products formed at different stages during the evolution of a magmatic-hydrothermal system. The albite-magnetite type represents the earliest crystallization product from a residual ironrich melt; the albite-K-feldspar-magnetite and K-feldspar-magnetite types show features of magmatichydrothermal transition, whereas the epidote-magnetite and quartz-magnetite types represent products of hydrothermal alteration. The occurrence of iron-rich agglomerates provides macroscopic evidence for the presence of iron-rich melts in the mineralization of the Heijianshan iron deposit. It also indicates that iron mineralization of submarine volcanic rock-hosted iron deposits is genetically related to hydrothermal fluids derived from iron-rich melts. | LI Houmin LI Lixing DING Jianhua LI Yanhe SONG Zhe MENG Jie MA Yubo | 2018 | Acta Geologica Sinica(English Edition)2018，92，2： | 5 |
| 3 | Geological settings and metallogenesis of high-grade iron deposits in China显示文摘The predominant types of high-grade iron deposits in China include skarn,sedimentary metamorphic(banded ironformation,BIF-type),continental/submarine volcanic-hosted and magmatic Fe-Ti-Voxide deposits.Based on a comprehensive review of current studies on these deposits,this paper suggests that the oxygen concentration in atmosphere played an important role for the formation of BIFs,whereas the tectonic setting and deep magmatic differentiation processes are more important for the other types.Notably,both high temperature and high pressure experiments and melt inclusion studies indicate that during the differentiation,high temperature magmas could develop iron-rich magma via liquid immiscibility but not pure oxide melt('iron ore magma').Fe-P melt could be generated directly by liquid immiscibility under hydrous and oxidized condition.The formation of high-grade iron deposits is mostly associated with the processes related to multiple stages of superimposition,e.g.,desiliconization and iron enrichment,removal of impurity,and remobilization and re-precipitation of iron.According to the temporal evolution,the high-grade iron deposit could be divided into multi-episode superimposition type(temporally discontinuous mineralization)and multi-stage superimposition type(temporally continuous mineralization).The former is represented by the sedimentary metamorphic iron deposit,and the latter includes those related to magmatic-hydrothermal fluids(e.g.,skarn,volcanic-hosted and magmatic types). | Zhaochong ZHANG Houmin LI Jianwei LI Xie-Yan SONG Hao HU Lixing LI Fengmei CHAI Tong HOU Deru XU | 2021 | Science China Earth Sciences2021，64，5： | 4 |
| 4 | Iron Isotopes and Trace Element Compositions of Magnetite from the Submarine Volcanic-Hosted Iron Deposits in East Tianshan,NW China:New Insights into the Mineralization Processes显示文摘The Aqishan-Yamansu metallogenic belt(AYMB)in East Tianshan hosts abundant sub-marine volcanic-hosted iron deposits.Although there is agreement with the magmatic source of the ore-forming materials and the role of hydrothermal replacement in iron ore formation,the mineraliza-tion processes of these iron deposits remain uncertain.Three ore types are identified on the basis of the geological occurrences of minerals and the sequence of mineral in ores.The typeⅠores are characte-rized by magnetite,diopside,amphibole with a few pyrite,and chalcopyrite.The type II ores are mainly composed of magnetite,garnet,chlorite with a few pyrite,while the type III ores are mainly composed of magnetite,quartz,calcite with a few pyrite.In order to constrain the mineralization processes of these ore types,we performed iron isotopes and trace element compositions of magnetite from three typical iron deposits(Yamansu,Duotoushan and Luotuofeng).Trace element and Fe isotope investiga-tions of the three ore types reveal two major groups.The groupⅠconsists of analyses of the typeⅠandⅡores,with both showing a narrow range of positiveδ56Fe values(+0.08‰to+0.22‰for typeⅠores and+0.15‰ to+0.22‰ for typeⅡores)and plotting in the range of the ortho-magmatic field.In contrast,the group 2 is composed merely of the typeⅢores,showing a wider range of negativeδ56Fe values(-0.49‰ to-0.01‰),which is similar to the features of Fe-skarn magnetite.As shown in the binary dia-grams of magnetite trace elements and a fractionation of the Fe isotopes,different ore types were likely produced during gradually changing ore-forming stages from magmatic to hydrothermal.Collectively,the submarine volcanic-hosted iron deposits in the East Tianshan are likely the results of a continuous magmatic-hydrothermal mineralization process. | Zhe Song Houmin Li Lixing Li Jianhua Ding Jie Meng | 2021 | Journal of Earth Science2021，32，1： | 3 |
| 5 | OPTIMAL PURCHASING PROCESS FOR ELECTRICITY AND RENEWABLE ENERGY CREDITS WITH PRICE AND DEMAND UNCERTAINTY显示文摘This paper optimizes the electricity and renewable energy credit (REC) purchasing process for energy distribution. Electricity is traded in deregulated time-sequential markets at fluctuating prices. Optimal electricity purchasing under price and demand uncertainty is a challenging task for electricity distributors, and the recently implemented renewable portfolio standards (RPS) further complicate the purchasing process. Government regulatory decisions concerning the RPS require distributors to purchase corresponding certificates, namely RECs, equivalent to a certain percentage of their electricity sales. This paper formulates and optimizes the joint purchasing process for electricity and RECs. It also analyzes the effect of RPS policy on electricity distributors. | Zhiyuan CHEN Yiwen SU Houmin YAN | 2012 | Journal of Systems Science and Systems Engineering2012，21，2： | 3 |
| 6 | Channel coordination in supply chains with agents having mean-variance objectives显示文摘 | Tsan-Ming Choi Duan Li Houmin Yan Chun-Hung Chiu | 2007 | Omega2007，，4： | 2 |
| 7 | 碳酸钠碱性介质氧脱木素促进火炬松酶解糖化的研究显示文摘分别采用硫酸盐法(KP)和绿液法(GL)蒸煮火炬松,并以碳酸钠为碱性介质进行氧脱木素,所得浆料分别标记为KP-OC浆和GL-OC浆,分析了这两种浆料的化学组分,并对这两种浆料进行酶解以提取可发酵单糖。结果显示,在120℃氧脱木素4 h所得的KP-OC浆和GL-OC浆的木素脱出率均明显优于相近条件下以氢氧化钠为碱性介质且脱木素1 h的浆料。对于GL-OC浆和KP-OC浆,当酶用量为10 FPU/g时,酶解单糖得率、总单糖提取率最高分别可达73.2%和95.8%、72.4%和75.7%,均优于相近条件下以氢氧化钠为碱性介质氧脱木素的浆料。 | 张雨情 吴淑芳 Hasan Jameel Houmin Chang | 2018 | 中国造纸学报2018，33，1： | 2 |
| 8 | Petrological and Geochemical Constraints on the Protoliths of Serpentine-Magnetite Ores in the Zhaoanzhuang Iron Deposit,Southern North China Craton显示文摘The uncommon Mg-rich and Ti-poor Zhaoanzhuang serpentine-magnetite ores within Taihua Group of the North China Craton(NCC) remain unclear whether the protolith was sourced from ultramafic rocks or chemical sedimentary sequences. Here we present integrated petrographic and geochemical studies to characterize the protoliths and to gain insights on the ore-forming processes. Iron ores mainly contain low-Ti magnetite(TiO_2 ~0.1 wt%) and serpentine(Mg#=92.42–96.55), as well as residual olivine(Fo=89–90), orthopyroxene(En=89–90) and hornblende. Magnetite in the iron ores shows lower Al, Sc, Ti, Cr, Zn relative to that from ultramafic Fe-Ti-V iron ores, but similar to that from metamorphic chemical sedimentary iron deposit. In addition, interstitial minerals of dolomite, calcite, apatite and anhydrite are intergrown with magnetite and serpentine, revealing they were metamorphic, but not magmatic or late hydrothermal minerals. Wall rocks principally contain magnesian silicates of olivine(Fo=83–87), orthopyroxene(En=82–86), humite(Mg#=82–84) and hornblende [XMg=0.87–0.96]. Dolomite, apatite and anhydrite together with minor magnetite, thorianite(Th-rich oxide) and monazite(LREE-rich phosphate) are often seen as relicts or inclusions within magnesian silicates in the wall rocks, revealing that they were primary or earlier metamorphic minerals than magnesian silicates. And olivine exists as subhedral interstitial texture between hornblende, which shows later formation of olivine than hornblende and does not conform with sequence of magmatic crystallization. All these mineralogical features thus bias towards their metamorphic, rather than magmatic origin. The dominant chemical components of the iron ores are SiO_2(4.77–25.23 wt%), Fe_2O_3 T(32.9–80.39 wt%) and MgO(5.72–27.17 wt%) and uniformly, those of the wall rocks are also SiO_2(16.34–48.72 wt%), Mg O(16.71–33.97 wt%) and Fe_2O_3 T(6.98–30.92 wt%). The striking high Fe-Mg-Si contents reveal that protolith of the Zhaoanzhuang iron deposit was more likely to be chemical sedimentary rocks. The distinct high-Mg feature and presence of abundant anhydrite possibly indicate it primarily precipitated in a confined seawater basin under an evaporitic environment. Besides, higher contents of Al, Ti, P, Th, U, Pb, REE relative to other Precambrian iron-rich chemical precipitates(BIF) suggest some clastic terrestrial materials were probably input. As a result, we think the Zhaoanzhuang iron deposit had experienced the initial Fe-Mg-Si marine precipitation, followed by further Mg enrichment through marine evaporated process, subsequent high-grade metamorphism and late-stage hydrothermal fluid modification. | MENG Jie LI Houmin LI Lixing SANTOSH M SONG Zhe YANG Xiuqing | 2018 | Acta Geologica Sinica(English Edition)2018，92，2： | 2 |
| 9 | Quick response poli cy with Bayesian information updates显示文摘 | Choi T M Li Duan Yan Houmin | | 0，，03： | 1 |
| 10 | Optimal returns policy for supply chain with e-marketplace显示文摘 | Tsan-Ming Choi Duan Li Houmin Yan | 2003 | International Journal of Production Economics2003，，2： | 1 |
| 11 | The relationship of mantle-derived fluids to gold metallogenesis in the Jiaodong Peninsula: Evidence from D–O–C–S isotope systematics显示文摘 | Jingwen Mao Yitian Wang Houmin Li Franco Pirajno Changqing Zhang Ruiting Wang | 2007 | Ore Geology Reviews2007，，3： | 1 |
| 12 | Coordination of supply chains with risk-averse agents显示文摘 | Xianghua Gan Suresh P S Houmin Yan | 2004 | Production and operations management2004，13，2： | 1 |
| 13 | Coordination of supply chains with risk-averse agents 显示文摘 | Gan Xianghua Sethi P Suresh Yan Houmin | 2004 | Production and Operations Management2004，13，2： | 1 |
| 14 | Channel coordination with a risk-neutral supplier and a downside-risk- averse retailer 显示文摘 | GanXianghua Sethi P Suresh Yan Houmin | 2005 | Production and Operations Management2005，14，： | 1 |
| 15 | Channel coordination in supply chains with agents having mean-variance objectives显示文摘 | CHOI Tsanming DUAN Li YAN Houmin | 2008 | Omega2008，36，： | 1 |
| 16 | Mean-variance analysis of a single supplier and retailer supply chain under a returns policy显示文摘 | CHOI Tsanming DUAN Li YAN Houmin | 2008 | European Journal of Operational Research2008，184，： | 1 |
| 17 | New experimental technique to study blood cardioplegia in the isolated,petgused rat heart显示文摘 | Chandra M Schwalb H Yaroslavsky Houminer E | 1993 | Ann Thorac Surg1993，55，4： | 1 |
| 18 | Optimal Returns Policy for Supply Chain with E-marketplace显示文摘 | Tsan-Ming Choi Duan Li Houmin Yan | 2004 | Int J Production Economics2004，88，2： | 1 |
| 19 | Optimal single ordering policy with multiple delivery modes and Bayesian information updates显示文摘 | Tsan-Ming Choi Duan Li Houmin Yah | 2004 | Computers & OR2004，31，12： | 1 |
| 20 | Optimal returns policy for supply chain with e-marketplace显示文摘 | Tsan M C Duan L Houmin Y | 2004 | Int J Production Economics2004，88，2： | 1 |
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