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| 1 | Effect of extrusion speed on microstructure and mechanical properties of the Mg-Ca binary alloy显示文摘This work reported the effect of extrusion speeds on the microstructures and mechanical properties of Mg-Ca binary alloy.The results showed that yield strength of the as-extruded Mg-1.2wt.%Ca alloys decrease from∼360MPa to∼258MPa as the ram speed increases from 0.4mm/s to 2.4 mm/s,and the elongation increases from∼3.9%to∼12.2%.The microstructure changes from bimodal grain feature to the complete dynamical recrystallization(DRX)with increase of the extrusion speed.The ultrafine DRXed grains in size of∼0.85μm,the numerous nano-Mg_(2)Ca particles dispersing along the grain boundaries and interiors,as well as the high density of residual dislocations,should account for the high strength.It is believed that the high degree of dynamic recrystallization and the resulting texture randomization play the critical roles in the ductility enhancement of the high-speed extruded Mg alloys. | Jingren Li Aiyue Zhang Hucheng Pan Yuping Ren Zhuoran Zeng Qiuyan Huang Changlin Yang Lifeng Ma Gaowu Qin | 2021 | Journal of Magnesium and Alloys2021，9，4： | 9 |
| 2 | Low-cost and high-strength Mg-Al-Ca-Zn-Mn wrought alloy with balanced ductility显示文摘A novel low-cost Mg-Al-Ca-Zn-Mn-based alloy was developed to simultaneously improve its strength and ductility.The high yield strength of 411 MPa and the high elongation to failure of~8.9%have been achieved in the as-extruded Mg-1.3Al-1.2Ca-0.5Zn-0.6Mn(wt%)sample.Microstructure characterizations showed that the high strength is mainly associated with the ultra-fined dynamically recrystallized(DRXed)grains.Moreover,high-density dislocations in the un-DRXed region and nano-precipitates are distributed among theα-Mg matrix.The high ductility property can be ascribed to the high volume fraction of DRXed grains with a much randomized texture,as well as the formations of high-density subgrains in the un-DRXed grain regions. | Kun Yang Hucheng Pan Sen Du Man Li Jingren Li Hongbo Xie Qiuyan Huang Huajun Mo Gaowu Qin | 2022 | International Journal of Minerals,Metallurgy and Materials2022，29，7： | 3 |
| 3 | Direct growth of hexagonal boron nitride films on dielectric sapphire substrates by pulsed laser deposition for optoelectronic applications显示文摘Recently,hexagonal boron nitride(h-BN),an ultra-wide bandgap semiconductor,has attracted considerable atten-tion owing to its excellent properties.In thin films grown on metal catalysts,contamination and damage induced by a transfer process cannot be avoided.Therefore,synthesizing h-BN films on non-catalytic dielectric substrates is desirable for electronic applications.In this study,we demonstrate the direct growth of high-quality h-BN films with a controllable thickness on sapphire substrates by using the pulsed laser deposition(PLD)technique.The effects of the deposition conditions and laser parameters on the growth of the h-BN films are systematically investigated by evaluating their characteristic Raman peaks.Among the various growth parameters studied,the substrate temperature has the greatest influence on the crystalline quality of the h-BN films,and the optimal pres-sure varies depending on the target-substrate distance.The h-BN film grown under optimal conditions exhibits a narrow Raman line width of∼30 cm^(−1),indicating a high crystalline quality.The photodetectors fabricated from the PLD-grown h-BN films exhibit superior deep-ultraviolet detection performance with a large on/offratio of>104,high photoresponsivity,and a sharp cut-offwavelength of 220 nm.This study presents the possibility of producing high-quality h-BN films by applying PLD on dielectric substrates for optoelectronic applications. | Gaokai Wang Jingren Chen Junhua Meng Zhigang Yin Ji Jiang Yan Tian Jingzhen Li Jinliang Wu Peng Jin Xingwang Zhang | 2021 | Fundamental Research2021，1，6： | 1 |
| 4 | Achieving high strength above 400 MPa in conventionally extruded Mg-Ca-Zn ternary alloys显示文摘In this work,the role of Zn content in modifying the microstructure and mechanical properties of the Mg-1.2Ca-xZn(x=0.6,2.0 wt.%,named as XZ10-0 and ZX21-0,respectively)based alloys was studied,and it is found that the yield strength(YS)of the present Mg-(Zn)-Ca based alloys increases monotonically with increasing the Zn concentration,from~339 MPa in low-Zn content XZ10-0 sample to~406 MPa in high-Zn content ZX21-0 sample.Microstructure characterization shows that the enhanced YS can be attributed to the grain refinement,fine and dispersed nano-phases,a large number of lamellae structures,and the decrease of recrystallization fraction.TEM results show that the formation mechanism for the ultra-fine grains in present Mg-(Zn)-Ca based alloys can be attributed to the co-segregation of Ca and Zn elements at the grain boundary,as well as the dynamic nanoprecipitations.When the Zn content is high,the nano-phases in ZX21-0 sample belong to the Ca;Mg;Zn;ternary phases,which exert much higher thermal stability than the nano-sized Mg2 Ca binary phases formed in the low-Zn content XZ10-0 sample.The finer size and higher number density of the nano-Mg Zn Ca phases lead to the much finer grain size and sub-grain lamellae thickness in ZX21-0 sample,which thus results in the higher YS of~406 MPa. | DU Sen YANG Kun LI Man LI JingRen REN YuPing HUANG QiuYan PAN HuCheng QIN GaoWu | 2022 | Science China(Technological Sciences)2022，65，3： | 1 |
| 5 | Spun highly linearly birefringent fibres for current sensors 显示文摘 | Qian Jingren Li Lusun | 1990 | Science in China(Series A)1990，33，1： | 1 |
| 6 | Fluorescence detection of phosphate in an aqueous environment by an aluminum-based metal-organic framework with amido functionalized ligands显示文摘The on-site monitoring of phosphate is important for environmental management.Conventional phosphate detection methods are not appropriate to on-site monitoring owing to the use of complicated detection procedures,and the consequent high cost and maintenance requirements of the detection apparatus.Here,a highly sensitive fluorescence-based method for phosphate detection with a wide detection range was developed based on a luminescent aluminum-based metal-organic framework(Al-MOF).The Al-MOF was prepared by introducing amine functional groups to conventional MIL to enhance phosphate binding,and exhibited excellent fluorescence properties that originated from the ligand-to-metal charge transfer(LMCT).The detection limit was as low as 3.25µmol/L(0.10 mg/L)and the detection range was as wide as 3–350µmol/L(0.10–10.85 mg/L).Moreover,Al-MOF displayed specific recognition toward phosphate over most anions and metal cations,even for a high concentration of the co-existent ions.The mechanism of phosphate detection was analyzed through the characterization of the combination of Al-MOF and phosphate,and the results indicated the high affinity between Al-O and phosphate inhibited that the LMCT process and recovered the intrinsic fluorescence of NH2−H2BDC.The recovery of the developed detection method reached a satisfactory range of 85.1%–111.0%,and the feasibility of on-site phosphate detection was verified using a prototype sensor for tap water and lake water samples.It was demonstrated that the prepared Al-MOF is highly promising for on-site detection of phosphate in an aqueous environment. | Peng Li Lingqian Dong Han Jin Jingren Yang Yonghui Tu Chao Wang Yiliang He | 2022 | Frontiers of Environmental Science & Engineering2022，16，12： | 0 |
| 7 | Remote heteroepitaxy of transition metal dichalcogenides through monolayer hexagonal boron nitride显示文摘As a very promising epitaxy technology,the remote epitaxy has attracted extensive attention in recent years,in which graphene is the most used interlayer material.As an isomorphic of graphene,two-dimensional(2D)hexagonal boron nitride(h-BN),is another promising interlayer for the remote epitaxy.However,there is a current debate on the feasibility of using h-BN as interlayer in the remote epitaxy.Herein,we demonstrate that the potential field of sapphire can completely penetrate monolayer h-BN,and hence the remote epitaxy of ZrS_(2) layers can be realized on sapphire substrates through monolayer h-BN.The field of sapphire can only partially penetrate the bilayer h-BN and result in the mixing of remote epitaxy and van der Waals(vdWs)epitaxy.Due to the weak interfacial scattering and high crystalline quality of ZrS_(2) epilayer,the ZrS_(2) photodetector with monolayer h-BN shows the best performance,with an on/off ratio of more than 2×10^(5) and a responsivity up to 379 mA·W^(-1).This work provides an efficient approach to prepare single-crystal transition metal dichalcogenides and their heterojunctions with h-BN,which have great potential in developing large-area 2D electronic devices. | Jidong Huang Jingren Chen Junhua Meng Siyu Zhang Ji Jiang Jingzhen Li Libin Zeng Zhigang Yin Jinliang Wu Xingwang Zhang | 2024 | Nano Research2024，17，4： | 0 |
| 8 | Synergistic Effect of Platinum Single Atoms and Nanoclusters Boosting Electrocatalytic Hydrogen Evolution显示文摘Maximizing atomic utilization of precious metalbased catalysts is of great significance in heterogeneous catalysis,also becoming a useful strategy to develop efficient electrocatalysts for hydrogen evolution reaction(HER).Although the dispersion of platinum(Pt)as single atoms(SAs)has increasingly been used in the design of HER electrocatalysts,it is still controversial if the SAs possess higher reactivity relative to the nanoparticles with identical atom loading. | Yihui Zhu Pengfei Tian Hongliang Jiang Jingren Mu Lu Meng Xiaozhi Su Yu Wang Yunxiang Lin Yihua Zhu Li Song Chunzhong Li | 2021 | CCS Chemistry2021，3，10： | 0 |
| 9 | Grain refinement and strength enhancement in Mg wrought alloys: A review显示文摘Low absolute strength becomes one major obstacle for the wider applications of low/no rare-earth(RE) containing Mg alloys. This review firstly demonstrates the importance of grain refinement in improving strength of Mg alloys by comprehensively comparing with other strategy, e.g., precipitation strengthening. Dynamic recrystallization(DRX) plays a crucial role in refining grain size of Mg wrought alloys.Therefore, secondly, the DRX models, grain nucleation mechanisms and the related grain refinement abilities in Mg alloys are summarized,including phase boundary, twin boundary and general boundary induced recrystallization. Thirdly, the newly developed low-RE containing Mg alloy, e.g., Mg-Ce, Mg-Nd and Mg-Sm based alloys, and the RE-free Mg alloys, e.g., Mg-Al, Mg-Zn, Mg-Sn and Mg-Ca based alloy,are reviewed, with the focus on enhancing the mechanical properties mainly via the grain refinement strategy. At the last section, the perspectives and outstanding issues concerning high-performance Mg wrought alloys are also proposed. This review is meant to promote the deep understanding on the critical role of grain refinement in Mg alloys and provide reference for the development of other high strength and low-cost Mg alloys which are fabricated by the conventional extrusion/rolling processing. | Sen Wang Hucheng Pan Dongsheng Xie Dongdong Zhang Jingren Li Hongbo Xie Yuping Ren Gaowu Qin | 2023 | Journal of Magnesium and Alloys2023，11，11： | 0 |
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