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| 1 | Maghemite(γ-Fe_2O_3) nanoparticles enhance dissimilatory ferrihydrite reduction by Geobacter sulfurreducens: Impacts on iron mineralogical change and bacterial interactions显示文摘Microbially mediated bioreduction of iron oxyhydroxide plays an important role in the biogeochemical cycle of iron.Geobacter sulfurreducens is a representative dissimilatory ironreducing bacterium that assembles electrically conductive pili and cytochromes.The impact of supplementation withγ-Fe_2O_3 nanoparticles(NPs)(0.2 and 0.6 g)on the G.sulfurreducens-mediated reduction of ferrihydrite was investigated.In the overall performance of microbial ferrihydrite reduction mediated byγ-Fe_2O_3 NPs,stronger reduction was observed in the presence of direct contact withγ-Fe_2O_3 NPs than with indirect contact.Compared to the production of Fe(Ⅱ)derived from biotic modification with ferrihydrite alone,increases greater than 1.6-and 1.4-fold in the production of Fe(Ⅱ)were detected in the biotic modifications in which direct contact with 0.2 g and 0.6 gγ-Fe_2O_3 NPs,respectively,occurred.X-ray diffraction analysis indicated that magnetite was a unique representative iron mineral in ferrihydrite when active G.sulfurreducens cells were in direct contact withγ-Fe_2O_3 NPs.Because of the sorption of biogenic Fe(Ⅱ)ontoγ-Fe_2O_3 NPs instead of ferrihydrite,the addition ofγ-Fe_2O_3 NPs could also contribute to increased duration of ferrihydrite reduction by preventing ferrihydrite surface passivation.Additionally,electron microscopy analysis confirmed that the direct addition ofγ-Fe_2O_3 NPs stimulated the electrically conductive pili and cytochromes to stretch,facilitating long-range electron transfer between the cells and ferrihydrite.The obtained findings provide a more comprehensive understanding of the effects of iron oxide NPs on soil biogeochemistry. | Zheng Chen Yaxian Zhang Qingliu Luo Liuying Wang Shurui Liu Yajuan Peng Haitao Wang Liang Shen Qingbiao Li Yuanpeng Wang | 2019 | Journal of Environmental Sciences2019，31，4： | 5 |
| 2 | Regulation of Leaf Angle by Auricle Development n Maize显示文摘 | Fanying Kong Tingting Zhang Jisheng Liu Siqi Heng Qingbiao Shi Haisen Zhang Zeli Wang Lei Ge Pinghua Li Xiaoduo Lu Gang Li | 2017 | Molecular Plant2017，10，3： | 5 |
| 3 | Component analysis and risk assessment of biogas slurry from biogas plants显示文摘Massive amounts of biogas slurry are produced due to the development of biogas plants.The pollution features and the risk of biogas slurry were fully evaluated in this work.Thirty-one biogas slurry samples were collected from sixteen different cities and five different raw materials biogas plants(e.g.cattle manure,swine manure,straw-manure mixture,kitchen waste and chicken manure).The chemical oxygen demand(COD),ammonia nitrogen(NH_(4)^(+)-N),anions(e.g.Cl^(-1),SO_(4)^(2-),NO_(3)^(-)and PO_(4)^(3-)),antibiotics(e.g.sulphonamides,quinolones,β2-receptor agonists,macrolides,tetracyclines and crystal violet)and heavy metals(e.g.Cu,Cd,As,Cr,Hg,Zn and Pb)contents from these biogas slurry samples were systematically investigated.On this basis,risk assessment of biogas slurry was also performed.The concentrations of COD,NH_(4)^(+)-N and PO_(4)^(3-) in biogas slurry samples with chicken manure as raw material were significantly higher than those of other raw materials.Therefore,the biogas slurry from chicken manure raw material demonstrated the most serious eutrophication threat.The antibiotic contents in biogas slurry samples from swine manure were the highest among five raw materials,mostly sulphonamides,quinolones and tetracyclines.Biogas slurry revealed particularly serious arsenic contamination and moderate potential ecological risk.The quadratic polynomial stepwise regression model can quantitatively describe the correlation among NH_(4)^(+)-N,PO_(4)^(3+) and heavy metals concentration of biogas slurry.This work demonstrated a universal potential threat from biogas slurry that can provide supporting data and theoretical basis for harmless treatment and reuse of biogas slurry. | Lanting Ke Xiaobin Liu Bingqing Du Yuanpeng Wang Yanmei Zheng Qingbiao Li | 2022 | Chinese Journal of Chemical Engineering2022，35，4： | 5 |
| 4 | Nano-sized Fe_2O_3/Fe_3O_4 facilitate anaerobic transformation of hexavalent chromium in soil–water systems显示文摘The purpose of this study is to investigate the effects of nano-sized or submicro Fe_2O_3/Fe_3O_4 on the bioreduction of hexavalent chromium(Cr(VI)) and to evaluate the effects of nano-sized Fe_2O_3/Fe_3O_4 on the microbial communities from the anaerobic flooding soil.The results indicated that the net decreases upon Cr(VI) concentration from biotic soil samples amended with nano-sized Fe_2O_3(317.1 ± 2.1 mg/L) and Fe_3O_4(324.0 ± 22.2 mg/L) within21 days,which were approximately 2-fold of Cr(VI) concentration released from blank control assays(117.1 ± 5.6 mg/L).Furthermore,the results of denaturing gradient gel electrophoresis(DGGE) and high-throughput sequencing indicated a greater variety of microbes within the microbial community in amendments with nano-sized Fe_2O_3/Fe_3O_4 than the control assays.Especially,Proteobacteria occupied a predominant status on the phylum level within the indigenous microbial communities from chromium-contaminated soils.Besides,some partial decrease of soluble Cr(VI) in abiotic nano-sized Fe_2O_3/Fe_3O_4 amendments was responsible for the adsorption of nano-sized Fe_2O_3/Fe_3O_4 to soluble Cr(VI).Hence,the presence of nano-sized Fe_2O_3/Fe_3O_4 could largely facilitate the mobilization and biotransformation of Cr(VI) from flooding soils by adsorption and bio-mediated processes. | Yaxian Zhang Hua Li Libo Gong Guowen Dong Liang Shen Yuanpeng Wang Qingbiao Li | 2017 | Journal of Environmental Sciences2017，29，7： | 4 |
| 5 | Effect of the benzene ring of the dispersant on the rheological characteristics of coal-water slurry:Experiments and theoretical calculations显示文摘In this study,low-rank coal-water slurry(LCWS)was prepared using polyoxyethylene dodecylphenol ether(PDPE)and polyoxyethylene lauryl ether(PLE),respectively.A combination of experiments and simulations was used to investigate the pulping properties and microscopic mechanism of the LCWS samples prepared using the two agents,so as to explore the influence of benzene ring on the performance of dispersant.The results of the LCWS preparation experiments revealed that the pulp-forming performance of PDPE exceeded that of PLE.When LCWS concentration is 62%,64%,and 66%,the apparent viscosity corresponding to PDPE is 247.80,504.17,and 653.10 mPa·s,and the apparent viscosity corresponding to PLE is 548.10,1470.61,and 1549.98 mPa·s,respectively.The C_(1000)(When the apparent viscosity is 1000 mPa·s,the corresponding concentration of LCWS is defined as C_(1000))values of PDPE and PLE are 67.60%and 62.95%,respectively.In addition to the van der Waals forces and hydrogen bonds between the PDPE and/or PLE molecules and coal,the benzene rings of PDPE presentπ-πstacking effect with the aromatic rings of coal.That could facilitate and strengthen the adsorption of PDPE on coal,which would be conducive to further improving the dispersion of coal particles.The two dispersants have no significant difference in effect on the pyrolysis of LCWS.The simulation results indicated that the times for PDPE and PLE molecules to reach flat adsorption state on coal are approximately 290 and 565 ps,respectively.The self-diffusion coefficient(D)of the PDPE and PLE on coal is 3.16 x 10^(-6)and6.57×10^(-6)m~2/s,respectively,and their interaction energies with coal are 785.71 and 648.60 kcal/mol,respectively.The results of the simulation calculations demonstrated that PDPE adsorbed on coal easier than PLE,and its binding is more stable than that of PLE owing to theπ-πstacking effect,which is conducive to uniform dispersion of coal in solution.The simulation results confirmed the experimental results. | Lin Li Chuandong Ma Shanpei Hu Meng He Hao Yu Qingbiao Wang Xiaoqiang Cao Xiaofang You | 2021 | International Journal of Mining Science and Technology2021，31，3： | 4 |
| 6 | Phylogenetic position of Ephedra rhytidosperma,a species endemic to China:Evidence from chloroplast and ribosomal DNA sequences显示文摘The chloroplast genes matK and rbcL, ribo- somal gene 18S and ITS regions of nuclear ribosomal DNA from Ephedra rhytidosperma, a species endemic to China, were sequenced and its phylogenetic position was investi- gated. Independent and combined phylogenetic analyses for the DNA sequences from 16 taxa representing 15 species of the genus Ephedra were performed using the maximum par- simony (MP), neighbor-joining (NJ), minimum evolution (ME) and maximum likelihood (ML) methods. The results indicate that E. rhytidosperma is closely related to E. equiset- ina. The divergence time between them is estimated to be 10.85±2.44 Ma based on the results of the relative-rate tests and the evolutionary rate of rbcL gene. | WANG Qingbiao WANG Li ZHOU Renchao ZHAO Xiaoming SHI Suhua YANG Yong ZHONG Yang | 2005 | Chinese Science Bulletin2005，50，24： | 3 |
| 7 | Preparation of β-Cyclodextrin/Fe3O4/Polyvinylpyrrolidone Composite Magnetic Microspheres for the Adsorption of Methyl Orange显示文摘 | SI Qingbo WEN Qian YANG Qingbiao SONG Yan LI Yaoxian | 2017 | Chemical Research in Chinese Universities2017，33，6： | 2 |
| 8 | Application and prospects of 3D printing in physical experiments of rock mass mechanics and engineering:materials,methodologies and models显示文摘The existence of joints or other kinds of discontinuities has a dramatic efect on the stability of rock excavations and engineering.As a result,a great challenge in rock mass mechanics testing is to prepare rock or rock-like samples with defects.In recent years,3D printing technology has become a promising tool in the feld of rock mass mechanics and engineering.This study frst reviews and discusses the research status of traditional test methods in rock mass mechanics tests of making rock samples with defects.Then,based on the comprehensive analysis of previous research,the application of 3D printing technology in rock mass mechanics is expounded from the following three aspects.The frst is the printing material.Although there are many materials for 3D printing,it has been found that 3D printing materials that can be used for rock mass mechanics research are very limited.After research,we summarize and evaluate printing material that can be used for rock mass mechanics studies.The second is the printing methodology,which mainly introduces the current application forms of 3D printing technology in rock mass mechanics.This includes printed precise casting molds and one-time printed samples.The last one is the printing model,which includes small-scale samples for mechanical tests and large-scale physical models.Then,the benefts and drawbacks of using 3D printing samples in mechanical tests and the validity of their simulation of real rock are discussed.Compared with traditional rock samples collected in nature or synthetic rock-like samples,the samples made by 3D printing technology have unique advantages,such as higher test repeatability,visualization of rock internal structure and stress distribution.There is thus great potential for the use of 3D printing in the feld of rock mass mechanics.However,3D printing materials also have shortcomings,such as insufcient material strength and accuracy at this stage.Finally,the application prospect of 3D printing technology in rock mass mechanics research is proposed. | Qingjia Niu Lishuai Jiang Chunang Li Yang Zhao Qingbiao Wang Anying Yuan | 2023 | International Journal of Coal Science & Technology2023，10，1： | 2 |
| 9 | Electrospinning Preparation ofβ-Cyclodextrin/Glutaraldehyde Crosslinked PVP Nanofibrous Membranes to Adsorb Dye in Aqueous Solution显示文摘 | XIAO Ning WEN Qian LIU Qingwen YANG Qingbiao LI Yaoxian | 2014 | Chemical Research in Chinese Universities2014，30，6： | 2 |
| 10 | Facile synthesis of porous Pd nanoflowers with excellent catalytic activity towards CO oxidation显示文摘Microorganism-mediated,hexadecyltrimethylammonium chloride(CTAC)-directed(MCD) method was employed in this work to synthesize Pd nanoflowers(PdNFs).Proper Pichia pastoris cells(PPCs) dosage,ascorbic acid(AA),Pd(NO_3)_2 and CTAC concentrations were essential for the growth of the PdNFs.The size of the assynthesized PdNFs could be tuned by adjusting the amount of Pd(NO_3)_2 solution and dosage of PPCs used.Characterization techniques such as X-ray diffraction,transmission electron microscopy,and X-ray photoelectron spectroscopy were used to verify the nature of the PdNFs.Finally the PdNF/PPC nanocomposites were immobilized onto TiO_2 supports to obtain bio-PdNF/TiO_2 catalysts which showed excellent catalytic activity for CO oxidation,obtaining 100%conversion at 100℃ and remaining stable over a period of 52 h of reaction time. | Tareque Odoom-Wubah Mingming Du Williams Brown Osei Daohua Sun Jiale Huang Qingbiao Li | 2015 | Chinese Journal of Chemical Engineering2015，23，11： | 2 |
| 11 | State of arts on the bio-synthesis of noble metal nanoparticles and their biological application显示文摘Nanomaterials are materials in which at least one of the dimensions of the particles is 100 nm and below.There are many types of nanomaterials,but noble metal nanoparticles are of interest due to their uniquely large surface-to-volume ratio,high surface area,optical and electronic properties,high stability,easy synthesis,and tunable surface functionalization.More importantly,noble metal nanoparticles are known to have excellent compatibility with bio-materials,which is why they are widely used in biological applications.The synthesis method of noble metal nanoparticles conventionally involves the reduction of the noble metal salt precursor by toxic reaction agents such as NaBH4,hydrazine,and formaldehyde.This is a major drawback for researchers involved in biological application researches.Hence,the bio-synthesis of noble metal nanoparticles(NPs)by bio-materials via bio-reduction provides an alternative method to synthesize noble metal nanoparticles which are potentially non-toxic and safer for biological application.In this review,the bio-synthesis of noble metal nanoparticle including gold nanoparticle(AuNPs),silver nanoparticle(AgNPs),platinum nanoparticle(PtNPs),and palladium nanoparticle(PdNPs)are first discussed.This is followed by a discussion of these biosynthesized noble metal in biological applications including antimicrobial,wound healing,anticancer drug,and bioimaging.Based on these,it can be concluded that the study on bio-synthesized noble metal nanoparticles will expand further involving bio-reduction by unexplored bio-materials.However,many questions remain on the feasibility of bio-synthesized noble metal nanoparticles to replace existing methods on various biological applications.Nevertheless,the current development of the biological application by bio-synthesized noble metal NPs is still intensively ongoing,and will eventually reach the goal of full commercialization. | Kok Bing Tan Daohua Sun Jiale Huang Tareque Odoom-Wubah Qingbiao Li | 2021 | Chinese Journal of Chemical Engineering2021，34，2： | 2 |
| 12 | New Cuprous Adsorbent Prepared by a Bioreduction Method for SOL Removal At Low Temperature显示文摘 | Lishan Jia Hao Song Qingbiao Li | 2008 | Industrial & Engineering Chemistry Research2008，47，22： | 1 |
| 13 | The C_(6)D_(6)detector system on the Back-n beam line of CSNS显示文摘Introduction The neutron capture cross sections are very important in the field of nuclear device design and basic physics research.Hydrogen-free liquid scintillator such as C_(6)D_(6)detectors are widely used in the neutron capture cross-sectional measurements for the low neutron sensitivity and fast time response.The Back-n white neutron source at China Spallation Neutron Source is the first spallation white neutron source in China,and it is suitable for neutron capture cross-sectional measurement.Materials and methods A C_(6)D_(6)detector system was built in the Back-n experimental station.The pulse height weighting technique was used to determine the system’s detection efficiency.The response to gamma rays of the C_(6)D_(6)detector was measured,and the energy resolution function was determined.Monte Carlo simulation with Geant4 code was carried out to get the weighting function of this C_(6)D_(6)detector system.Additionally,the systematic uncertainty of the weighting function was also determined.Conclusion According to the experimental and simulation results,this C_(6)D_(6)detector system can be used to measure neutron capture cross section. | Jie Ren Xichao Ruan Jie Bao Guangyuan Luan Wei Jiang Qi An Huaiyong Bai Ping Cao Qiping Chen Yonghao Chen Pinjing Cheng Zengqi Cui Ruirui Fan Changqing Feng Minhao Gu Fengqin Guo Changcai Han Zijie Han Guozhu He Yongcheng He Yuefeng He Hanxiong Huang Weiling Huang Xiru Huang Xiaolu Ji Xuyang Ji Haoyu Jiang Hantao Jing Ling Kang Mingtao Kang Bo Li Lun Li Qiang Li Xiao Li Yang Li Yang Li Rong Liu Shubin Liu Xingyan Liu Yinglin Ma Changjun Ning Binbin Qi Zhaohui Song Hong Sun Xiaoyang Sun Zhijia Sun Zhixin Tan Hongqing Tang Jingyu Tang Pengcheng Wang Qi Wang Taofeng Wang Yanfeng Wang Zhaohui Wang Zheng Wang Jie Wen Zhongwei Wen Qingbiao Wu Xiaoguang Wu Xuan Wu Likun Xie Yiwei Yang Han Yi Li Yu Tao Yu Yongji Yu Guohui Zhang Jing Zhang Linhao Zhang Liying Zhang Qingmin Zhang Qiwei Zhang Xianpeng Zhang Yuliang Zhang Zhiyong Zhang Yingtan Zhao Liang Zhou Zuying Zhou Danyang Zhu Kejun Zhu Peng Zhu | 2019 | Radiation Detection Technology and Methods2019，3，3： | 1 |
| 14 | Simultaneous biosorption of cadmium (II) and lead (II) ions by pretreated biomass of Phanerochaete chrysosporium显示文摘 | Qingbiao Li Songtao Wu Gang Liu Xinkai Liao Xu Deng Daohua Sun Yuelin Hu Yili Huang | 2003 | Separation and Purification Technology2003，，1： | 1 |
| 15 | New cuprous adsorbent prepared by a bioreduction method for SO2 removal at low temperature显示文摘 | Jia Lishan Song Hao Li Qingbiao | 2008 | Ind Eng Chem Res2008，47，： | 1 |
| 16 | Biosynthesis of silver and gold nanoparticles by novel sundried Cinnamomum camphora leaf显示文摘 | HUANG Jiale LI Qingbiao SUN Daohua | | 0，，03： | 1 |
| 17 | Enhanced active site extraction from perovskite LaCoO_(3) using encapsulated PdO for efficient CO_(2) methanation显示文摘The extraction of metallic nanoparticles from perovskite-type oxides(ABO_(3)) under mild reducing conditions is a novel way to prepare well-dispersed supported catalysts(B/AOd). Herein, we found that the encapsulated PdO in perovskite LaCoO_3(PdO@LaCoO_3) could facilitate the phase transformation of the perovskite structure at a low temperature owing to both strong H2 spillover of Pd and intimate interaction between the encapsulated PdO and LaCoO_(3). The pure LaCoO_(3) without PdO was relatively inert to CO_(2) hydrogenation(CO_(2) conversion <4%). In contrast, PdO@LaCoO_(3) exhibited excellent CO_(2) methanation performance with 62.3% CO_(2) conversion and >99% CH4 selectivity. The characterization results demonstrated that the catalytically active Co2 C was in-situ formed by carburization of the extracted Co0 during CO_(2) methanation for the PdO@LaCoO_(3) sample. Whereas, the LaCoO_(3) with surface supported PdO(PdO/LaCoO_(3)) showed a weak interaction and remained a perovskite structure with few Co_(2)C active centers after the catalytic reaction, which was similar to the parent LaCoO_(3). Accordingly, the PdO/LaCoO_(3) showed an inferior catalytic performance with 31.8% CO_(2) conversion and 87.4% CH_(4) selectivity. Therefore, the designed encapsulation structure of PdO within perovskite is critical to extract metallic NPs from perovskite-type oxides, which has the potential to prepare other integrated nanocatalysts based on perovskite-type oxides. | Kuncan Wang Wen Li Junjie Huang Jiale Huang Guowu Zhan Qingbiao Li | 2021 | Journal of Energy Chemistry2021，30，2： | 1 |
| 18 | Role of Adamantane Amide Based on L-Proline Double-H Potential Organocatalyst in Aidol Reaction with Product Separated via Host-guest Interaction显示文摘 | WANG Rui WEI Zhonglin GUO Jing FENG Yusha XU Enjie DUAN Haifeng LIN Yingjie YANG Qingbiao DU Jianshi LI Yaoxian | 2018 | Chemical Research in Chinese Universities2018，34，2： | 1 |
| 19 | Stimultaneous mercury bioaccumulation and cell propagation by genetically engineered Escherichia coli显示文摘 | Zhao Xiaowei Zhou Maohong Li Qingbiao | | 0，，05： | 1 |
| 20 | Xylitol production from d -xylose and horticultural waste hemicellulosic hydrolysate by a new isolate of Candida athensensis SB18显示文摘 | Jinming Zhang Anli Geng Chuanyi Yao Yinghua Lu Qingbiao Li | 2011 | Bioresource Technology2011，，： | 1 |
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