|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Study on catalytic mechanisms of Fe_(3)O_(4)-rGO_(x) in three typical advanced oxidation processes for tetracycline hydrochloride degradation显示文摘This study explored the catalytic mechanism and performance impacted by the materials ratio of Fe_(3)O_(4)-GO_(x) composites in three typical advanced oxidation processes(AOPs)of O_(3),peroxodisulfate(PDS)and photo-Fenton processes for tetracycline hydrochloride(TCH)degradation.The ratio of GO in the Fe_(3)O_(4)-GO_(x) composites exhibited different trends of degradation capacity in each AOPs based on different mechanisms.Fe_(3)O_(4)-rGO_(20wt%) exhibited the optimum catalytic performance which enhanced the ozone decomposition efficiency from 33.48%(ozone alone)to 51.83%with the major reactive oxygen species(ROS)of O_(2)·-.In PDS and photo-Fenton processes,Fe_(3)O_(4)-rGO_(5wt%) had the highest catalytic performance in PDS and H_(2)O_(2) decomposition for SO_(4)·–,and·OH generation,respectively.Compared with using PDS alone,PDS decomposition rate and TCH degradation rate could be increased by 5.97 and 1.73 times under Fe_(3)O_(4)-rGO_(5wt%) catalysis.In the photo-Fenton system,Fe_(3)O_(4)-rGO_(5wt%) with the best catalyst performance in H_(2)O_(2) decomposition,and TCH degradation rate increased by 2.02 times compared with blank group.Meantime,the catalytic mechanisms in those systems of that the ROS produced by conversion between Fe^(2+)/Fe^(3+)were also analyzed. | Heshan Zheng Yunying Hou Shuo Li Jun Ma Jun Nan Nannan Wang | 2023 | Chinese Chemical Letters2023，34，1： | 1 |
| 2 | Flower-like hierarchical structures consisting of porous single-crystalline ZnO nanosheets and their gas sensing properties to volatile organic compounds (VOCs)显示文摘 | Fanli Meng Nannan Hou Sheng Ge Bai Sun Zhen Jin Wei Shen Lingtao Kong Zheng Guo Yufeng Sun Hao Wu Chen Wang Minqiang Li | 2014 | Journal of Alloys and Compounds2014，，： | 1 |
| 3 | Nitrogen-doped pyrogenic carbonaceous matter facilitates azo dye decolorization by sulfide: The important role of graphitic nitrogen显示文摘Pyrogenic carbonaceous matter(PCM) catalyzes azo dye decolorization by sulfide, but the nitrogen doping catalytic mechanisms are poorly understood. In this study, we found that stagnate time of azo dye methyl orange(MO) decolorization was reduced to 0.54-18.28 min in the presence of various nitrogen-doped graphenes(NGs), remarkably lower compared to graphene itself. Particularly, graphitic nitrogen played a critical role in NGs-catalyzed MO decolorization by sulfide. Gas chromatography-mass spectrometry and in-situ surface Raman analysis demonstrated that doping nitrogen, especially graphite one facilitated reactive intermediate polysulfides formation. This is attributed to the improved electron conductivity through graphitic nitrogen doping, and the enhanced interactions between sulfide and carbon atoms bonded to graphitic nitrogen. This study not only provides a better understanding of PCM impact on transformations and fates of organic pollutants in natural environments, but also offer a new regulation strategy for more efficient wastewater treatment processes in PCM-catalyzed engineering systems. | Han-Qing Zhao Wen-Qiang Li Nannan Hou Lei Li Yiran Wang Peili Lu Yang Mu | 2023 | Chinese Chemical Letters2023，34，2： | 1 |
| 4 | Fabrication of oxygen-doped MoSe2 hierarchical nanosheets for highly sensitive and selective detection of trace trimethylamine at room temperature in air显示文摘Nano Research volume 13,pages1704–1712(2020)Cite this article 191 Accesses Metrics details Abstract Intelligent gas sensors based on the layered transition metal dichalcogenides(TMDs)have attracted great interest in the field of gas sensing due to their multiple active sites,fast electron,mass transfer capability and large surface-to-volume ratio.However,conventional TMDs-based sensors typically work at elevated temperature in inert atmosphere,which would largely limit the corresponding practical applications.Herein,novel oxygen-doped MoSe2 hierarchical nanostructures composed of ultrathin nanosheets with large specific surface area have been designed and generated typically at 200°C in air for fast and facile gas sensing of trimethylamine(TMA),effectively.Benefited from the gas-accessible hierarchical morphology and high surface area with abundant nanochannels,highly sensitive and selective detection of trace TMA has been achieved under ambient condition,and as detected the theoretical limit of detection(LOD)is 8 ppb,which is the lowest for TMA detection under ambient condition among the reported studies.The mechanism of oxygen doping on the improved gas-sensing performance has been investigated,revealing that the oxygen doping could greatly optimize the electronic structure,thus regulate the Fermi level of MoSe2 as well as the affinity between TMA molecule and sensor surface.It is expected that the oxygen doping strategy developed for the highly efficient gas sensors based on TMDs in present work may also be applicable to other types of gas-sensing semiconductors,which could open up a new direction for the rational design of high-performance gas sensors working under ambient condition. | Nannan Hou Qianqian Sun Jing Yang Su You Yun Cheng Qian Xu Wei Li Shiqi Xing Li Zhang Junfa Zhu Qing Yang | 2020 | Nano Research2020，13，6： | 0 |
| 5 | Purification and characterization of a cold-active myrosinase from marine Pseudomonas oleovorans SuMy07显示文摘Myrosinase(EC 3.2.1.147),also known asβ-thioglucoside glucohydrolase,was first discovered in mustard seeds.Myrosinase hydrolyzes glucosinolate to produce D-glucose and an unstable aglycon,which upon rearrangement yields metabolites such as isothiocyanate,sulfate,acetonitrile,and thiocyanate.Isothiocyanate has a wide range of biological functions[1].Previous studies have shown that isothiocyanate has insect-repellant and antibacterial effects[2].Isothiocyanate also has anti-inflammatory and antioxidant properties,making it a potential anticancer compound[3,4].Sulforaphane is one of the most representative isothiocyanate substances against numerous cancers.Myrosinase extraction is technically challenging,although myrosinase metabolites have a variety of uses.At present,myrosinase is primarily extracted from white mustard seeds after a time-consuming and expensive preparation.Therefore,the search for myrosinase that can hydrolyze glucosinolates to produce isothiocyanate efficiently and economically has become an urgent task.Microbes can secrete myrosinase with rapid growth,lack of seasonal variation,simple intensive cultivation,and simple product extraction. | Zhifa Huang Nannan Liu Yaowei Fang Xiaoyue Hou Guang Yang Jing Lu Haoyu Mi Qinwen Ye Rongjun Zhu Shu Liu | 2023 | Acta Biochimica et Biophysica Sinica2023，55，4： | 0 |
| 6 | Control of the morphology of electrodeposited three-dimensional copper foam by tuning the pressure显示文摘Three-dimensional(3D) copper foams have been formed by electrodeposition at different nitrogen pressures and examined by scanning electron microscopy.The results indicate that an increase in system pressure leads to a decrease of the pore size of the copper foam due to the suppressed coalescence of hydrogen bubbles,while the thickness of the copper foam increases with decreasing pressure.Also,the walls around the pores on the copper foam consist of copper dendrites,and the copper dendrites are made up of copper grains with sizes less than 1 μm.The average sizes of the copper grains decrease with increasing system pressure.It has been demonstrated that copper foams with controllable 3D structure formed by electrodeposition at different pressures are comparable to those obtained by electrodeposition at normal pressure in the presence of specific additives. | PANG Kun HOU YuCui WU WeiZe TIAN ShiDong SUN NanNan | 2012 | Science China Chemistry2012，55，7： | 0 |
| 7 | The economic value of grassland ecosystem services: A global meta-analysis显示文摘Background:Grasslands provide a wide variety of ecosystem services that contribute to human wellbeing.While an increasing number of studies are evaluating the monetary value of grassland ecosystem services,most of them focus on specific grassland ecosystem services at regional or local scales,and they use different assessment methods.Methods:This paper provides a comprehensive assessment of the economic value of global grassland ecosystem services based on a meta-analysis of 702 observations from 134 primary studies.Results:The economic values of different ecosystem services cover a wide range of grassland types,regions,and estimation methods.The annual economic value per hectare ranges from$3955 for semidesert grasslands to$5466 for tropical grasslands.On average,regulating services have the highest value,which is approximately four times that of provisioning services or approximately eight times that of food supply services.Several factors impact the estimated ecosystem service values,including the evaluation method,source and year of publication,and study site.The results indicate that the annual economic value of global grasslands exceeds$20.8 trillion.Conclusions:The findings of this study not only provide useful information for understanding the economic value of various ecosystem services associated with different types of grasslands but also have important policy implications for the ecological conservation of grassland globally. | Huifang Liu Lingling Hou Nannan Kang Zhibiao Nan Jikun Huang | 2022 | Grassland Research2022，1，1： | 0 |
| 8 | Morphology controllable urchin-shaped bimetallic nickel-cobalt oxide/carbon composites with enhanced electromagnetic wave absorption performance显示文摘The microscopic morphology of electromagnetic wave absorbers influences the multiple reflections of electromagnetic waves and impedance matching,determining the absorption properties.Herein,the urchin-shaped bimetallic nickel-cobalt oxide/carbon(NiCo_(2)O_(4)/C)composites are prepared via a hy-drothermal route,whose absorption properties are investigated by different morphologies regulated by changing calcination temperature.A minimum reflection loss(RL_(min))of-75.26 dB is achieved at a match-ing thickness of 1.5 mm,and the effective absorption bandwidth(EAB)of 8.96 GHz is achieved at 2 mm.Multi-advantages of the synthesized NiCo_(2)O_(4)/C composites contribute to satisfactory absorption proper-ties.First,the interweaving of the needle-like structures increases the opportunities for scattering and multiple reflections of incident electromagnetic waves,and builds up a conductive network to facilitate the enhancement of conductive losses.Second,the carbon component in the NiCo_(2)O_(4)/C composites en-hances the interfacial polarization and reduces the density of the absorber.Besides,generous oxygen va-cancy defects are introduced into the NiCo_(2)O_(4)/C composites,which induces defect polarization and dipole polarization.In summary,the ternary coordination of components,defects and morphology led to out-standing electromagnetic wave absorption,which lightened the path for improving the electromagnetic wave absorption property and enriching the family of NiCo_(2)O_(4) absorbers with excellent performance. | Fushan Li Qiuyu Li Hideo Kimura Xiubo Xie Xiaoyu Zhang Nannan Wu Xueqin Sun Ben Bin Xu Hassan Algadi Rami Adel Pashameah Abdullah K.Alanazi Eman Alzahrani Handong Li Wei Du Zhanhu Guo Chuanxin Hou | 2023 | Journal of Materials Science & Technology2023，，17： | 0 |
| 9 | Initiating Binary Metal Oxides Microcubes Electromagnetic Wave Absorber Toward Ultrabroad Absorption Bandwidth Through Interfacial and Defects Modulation显示文摘Cobalt nickel bimetallic oxides(NiCo_(2)O_(4))have received numerous attentions in terms of their controllable morphology,high temperature,corrosion resistance and strong electromagnetic wave(EMW)absorption capability.However,broadening the absorption bandwidth is still a huge challenge for NiCo_(2)O_(4)-based absorbers.Herein,the unique NiCo_(2)O_(4)@C core-shell microcubes with hollow structures were fabricated via a facile sacrificial template strategy.The concentration of oxygen vacancies and morphologies of the three-dimensional(3D)cubic hollow core-shell NiCo_(2)O_(4)@C framework were effectively optimized by adjusting the calcination temperature.The specially designed 3D framework structure facilitated the multiple reflections of incident electromagnetic waves and provided rich interfaces between multiple components,generating significant interfacial polarization losses.Dipole polarizations induced by oxygen vacancies could further enhance the attenuation ability for the incident EM waves.The optimized NiCo_(2)O_(4)@C hollow microcubes exhibit superior EMW absorption capability with minimum RL(RLmin)of-84.45 dB at 8.4 GHz for the thickness of 3.0 mm.Moreover,ultrabroad effective absorption bandwidth(EAB)as large as 12.48 GHz(5.52-18 GHz)is obtained.This work is believed to illuminate the path to synthesis of high-performance cobalt nickel bimetallic oxides for EMW absorbers with excellent EMW absorption capability,especially in broadening effective absorption bandwidth. | Fushan Li Nannan Wu Hideo Kimura Yuan Wang Ben Bin Xu Ding Wang Yifan Li Hassan Algadi Zhanhu Guo Wei Du Chuanxin Hou | 2023 | Nano-Micro Letters2023，15，12： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员