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| 1 | Super-plasticity of Zr_(64.80)Cu_(14.85)Ni_(10.35)Al_(10) bulk metallic glass at room temperature显示文摘Generally,bulk metallic glasses(BMGs)exhibit a very limited plastic deformation under a compression load at room temperature,often less than 2% before fracturing.In this letter,through an appropriate choice of BMGs' composition,an amorphous rod of Zr64.80Cu14.85Ni10.35Al10 with a diameter of 2 mm was prepared by using copper mold suction casting.X-ray diffraction and differential scanning calorimetry were utilized to determine its structure and thermal stability,and the uniaxial compression test was adopted to study its plastic deformation behavior at room temperature simultaneously.The results showed that the glass transition temperature and onset temperature of the exothermic reaction of the amorphous rod were 646 and 750 K,respectively,and its micro-hardness was 594.7 Hv.During com-pression,when the engineering strain and engineering stress arrived at 9.05% and 1732 MPa,respec-tively,i.e.,the true strain and true stress reached 9.42% and 1560 MPa,respectively,the amorphous rod started to yield.After yielding,with the increase of load,the strain increased and the glass rod ulti-mately were compressed into flake-like form.Although the maximum engineering strain was larger than 70%,i.e.,the maximum true strain exceeded by 120%,the amorphous specimen was not fractured,indicating that it has super-plasticity at room temperature.Through the appropriate choice of compo-sition and optimization of the technological process,flexible BMG with super-plasticity at room tem-perature could be produced. | TAO PingJun YANG YuanZheng BAI XiaoJun XIE ZhiWei CHEN XianCao DONG ZhenJiang Wen JianGuo | 2008 | Chinese Science Bulletin2008，53，3： | 3 |
| 2 | Effects of rare-earth elements on the glass-forming ability and mechanical properties of Cu_(46)Zr_(47-x)Al_7M_x(M = Ce,Pr,Tb,and Gd) bulk metallic glasses显示文摘Cu46Zr47-xAl7Mx(M = Ce,Pr,Tb,and Gd) bulk metallic glassy(BMG) alloys were prepared by copper-mold vacuum suction casting.The effects of rare-earth elements on the glass-forming ability(GFA),thermal stability,and mechanical properties of Cu46Zr47-xAl7Mx were investigated.The GFA of Cu46Zr47-xAl7Mx(M = Ce,Pr) alloys is dependent on the content of Ce and Pr,and the optimal content is 4.at %.Cu46Zr47-xAl7Tbx(x = 2,4,and 5) amorphous alloys with a diameter of 5 mm can be prepared.The GFA of Cu46Zr47-xAl7Gdx(x = 2,4,and 5) increases with increasing Gd.Tx and Tp of all decrease.Tg is dependent on the rare-earth element and its content.△Tx for most of these alloys decreases except the Cu46Zr42Al7Gd5 alloy.The activation energies △Eg,△Ex,and △Ep for the Cu46Zr42Al7Gd5 BMG alloy with Kissinger equations are 340.7,211.3,and 211.3 kJ/mol,respectively.These values with Ozawa equations are 334.8,210.3,and 210.3 kJ/mol,respectively.The Cu46Zr45Al7Tb2 alloy presents the highest microhardness,Hv 590,while the Cu46Zr43Al7Pr4 alloy presents the least,Hv 479.The compressive strength(σc.f.) of the Cu46Zr43Al7Gd4 BMG alloy is higher than that of the Cu46Zr43Al7Tb4 BMG alloy. | XIE Zhiwei ZHANG Yongzhang YANG Yuanzheng CHEN Xianzhao TAO Pingjun | 2010 | Rare Metals2010，29，5： | 2 |
| 3 | Enhanced wear resistance in Zr-based bulk metallic glasses by hydrogen显示文摘 | TAO PINGJUN YANG YUANZHENG CHEN XIN | 2013 | International Journal of Hydrogen Energy2013，38，21： | 1 |
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