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42篇 您的检索式:作者名="Thomas Eberhard"
    题名 作者 年代 出处 被引量
1Estimation of Time to Maximum Rate Under Adiabatic Conditions(TMR_(ad)) Using Kinetic Parameters Derived From DSC-Investigation of Thermal Behavior of 3-Methyl-4-Nitrophenol显示文摘Kinetic parameters of the decomposition of hazardous chemicals can be applied for the estimation of their thermal behavior under any temperature profile.Presented paper describes the application of the advanced kinetic approach for the determination of the thermal behavior also under adiabatic conditions occurring e.g.in batch reactors in case of cooling failure.The kinetics of the decomposition of different samples(different manufacturers and batches) of 3-methyl-4-nitrophenol were investigated by conventional DSC in non-isothermal(few heating rates varying from 0.25 to 8.0K/min) and isothermal(range of 200~260℃) modes.The kinetic parameters obtained with AKTS-Thermokinetics Software were applied for calculating reaction rate and progress under different heating rates and temperatures and verified by comparing simulated and experimental signals.After application of the heat balance to compare the amount of heat generated during reaction and its removal from the system,the knowledge of reaction rate at any temperature profiles allowed the determination of the temperature increase due to the self-heating in adiabatic and pseudo-adiabatic conditions.Applied advanced kinetic approach allowed simulation the course of the Heat-Wait-Search(HWS) mode of operation of adiabatic calorimeters.The thermal safety diagram depicting dependence of Time to Maximum Rate(TMR) on the initial temperature was calculated and compared with the results of HWS experiments carried out in the system with Ф-factor amounting to 3.2.The influence of the Ф-factor and reaction progress reached at the end of the HWS monitoring on the TMR is discussed.Presented calculations clearly indicate that even very minor reaction progress reduces the TMRad of 24h characteristic for a sample with initial reaction progress amounting to zero.Described estimation method can be verified by just one HWS-ARC,or by one correctly chosen ISO-ARC run of reasonable duration by knowing in advance the dependence of the TMR on the initial temperature for any Ф-factor.Proposed procedure results in significant shortening of the measuring time compared to a safety hazard approach based on series of ARC experiments carried out at the beginning of a process safety evaluation.Bertrand Roduit Patrick Folly Alexandre Sarbach Beat Berger Franz Brogli Francesco Mascarello Mischa Schwaninger Thomas Glarner Eberhard Irle Fritz Tobler Jacques Wiss Markus Luginbühl Craig Williams Pierre Reuse Francis Stoessel 2011化学推进剂与高分子材料2011,9,1:3
2Structural and immunologic cross-reactivity among filarial and mite tropomyosin: Implications for the hygiene hypothesis显示文摘Helton C. Santiago Sasisekhar Bennuru Alexis Boyd Mark Eberhard Thomas B. Nutman 2010The Journal of Allergy and Clinical Immunology2010,,2:2
3Cooling effects and evaporation characteristics of fogging systems in an experimental piggery显示文摘Haeussermann Angelika Hartung Eberhard Jungbluth Thomas 2007Biosystems Enginneering2007,97,:1
4High density process to cultivate Lactobacillus plantarum biomass using wheat stillage and sugar beet molasses显示文摘Magorzata Krzywonos Thomas Eberhard 2011Electronic Journal of Biotechnology2011,14,2:1
5Carbon dioxide absorption during extraperitoneal and transperitoneal endoscopic hernioplasty显示文摘Eberhard S Thomas AC Dirk A 2000Anesth Analg2000,9,1:1
6Safety aspects of chronic low-frequency transcranial magnetic stimulation based on localized proton magnetic resonance spectroscopy and histology of the rat brain显示文摘David Liebetanz Susanne Fauser Thomas Michaelis Boldizsár Czéh Takashi Watanabe Walter Paulus Jens Frahm Eberhard Fuchs 2003Journal of Psychiatric Research2003,,4:1
7A new technique for cyclic in situ amplification and a case report about amplification of a single copy gene sequence in human metaphase chromosomes through PCR-PRINS显示文摘Thomas Harrer Eberhard Schwinger Kirsten Mennicke 2001Hum Mutat2001,17,:1
8Dose-dependent Regional Cerebral Blood Flow Changes during Remifentanil Infusion in Humans: A Positron Emission Tomography Study显示文摘Klaus J. Wagner Frode Willoch Eberhard F. Kochs Thomas Siessmeier Thomas R. T?lle Markus Schwaiger Peter Bartenstein 2001Anesthesiology2001,,5:1
9Pathophysiology, diagnosis and prognostic implications of endothelial dysfunction显示文摘Thomas Münzel Christoph Sinning Felix Post Ascan Warnholtz Eberhard Schulz 2008Annals of Medicine2008,,3:1
10Oxidation of an o-Iminobenzosemiquinone radical ligand by molecular bromine: Structural, spectroscopic, and reactivity studies of a copper(II) o-iminobenzoquinone complex显示文摘Chandan M Thomas W Eberhard B 2008Inorg Chem2008,47,7:1
11Cooling effects and evaporation characteristics of fogging systems in an experimental piggery显示文摘Angelika Haeussermann Eberhard Hartung Thomas Jungbluth 2007Biosystems engineering2007,97,4:1
12Single-incision laparoscopic surgery: outcomes from 224 colonic resections performed at a single center using SILS?显示文摘Boris Vestweber Thomas Galetin Kathrin Lammerting Claudia Paul Jeanette Giehl Eberhard Straub Bodo Kaldowski Angelika Alfes Karl-Heinz Vestweber 2013Surgical Endoscopy2013,,2:1
13Pseudotetra?driella kamillae : taxonomy and ecology of a new member of the algal class Eustigmatophyceae (Stramenopiles)显示文摘Eberhard Hegewald Judit Padisák Thomas Friedl 2007Hydrobiologia2007,,1:1
14Epithelial versus mesenchymal phenotype determines in vitro sensitivity and predicts clinical activity of erlotinib in lung cancer patients 显示文摘Robert L Yauch Thomas Januario David A Eberhard 2005Clin Cancer Res2005,11,:1
15Identification of α-taxilin as an essential factor for the life cycle of Hepatitis B virus显示文摘Jasmin Hoffmann Caroline Boehm Kiyoshi Himmelsbach Christian Donnerhak Hendrik Roettger Thomas S.Weiss Daniela Ploen Eberhard Hildt 2013Journal of Hepatology2013,,:1
16Greenhouse gas emissions from animal houses and manure stores显示文摘Thomas Jungbluth Eberhard Hartung Gregor Brose 2001Ntur Cyel Agroecosys2001,60,:1
17Ultra-wide-band PD diagnostics of power cable terminations in service显示文摘EBERHARD L THOMAS S SACHA M 2008IEEE Transactions on Dielectrics and Electrical Insulation2008,15,6:1
18Fusion of 3D Building Models Derived from First and Last Pulse Laserscanning Data 显示文摘Thomas Vogtle Eberhard Steinle 2005Information Fusion2005,31,6:1
19Association of high-sensitive C-reactive protein with advanced stage β-cell dysfunction and insulin resistance in patients with type 2 diabetes mellitus显示文摘Andreas Pfützner Eberhard Standl Hermann-Josef Strotmann Jan Schulze Cloth Hohberg Georg Lübben Sabine Pahler Thomas Sch?ndorf Thomas Forst 2006Clinical Chemical Laboratory Medicine2006,,5:1
20Cooling effects and evaporation characteristics of fogging systems in an experimental Piggery显示文摘Angelika H Eberhard H Thomas 1 2007Biosystems Engineering2007,97,3:1
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