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| 1 | The study on the safety and efficacy of amnion graft for preventing the recurrence of moderate to severe intrauterine adhesions显示文摘Transcervical resection of adhesion(TCRA)is the standard treatment for the intrauterine adhesions,but the recurrence of adhesions is a tough problem for the gynecologist.In addition,the therapeutic strategy after TCRA about prevention of recurrence remains controversial especially for the patients with moderate to severe intrauterine adhesions(IUAs).Hence,we designed this study to explore the safety and efficacy of fresh amnion grafts for preventing the recurrence after TCRA for patients with moderate to severe IUAs.One hundred patients with moderate to severe IUAs who presented with a history of hypomenorrhea,amenorrhea and infertility were included in the study from January 2015 to December 2017.Patients were divided into amnion group(52 patients)and chitosan group(48 patients).Fresh amnion grafts or intrauterine injections of chitosan were administered after TCRA.Transvaginal ultrasonography(TVUS)and hysteroscopy were performed at the first and third month after the operation.The surgical procedures for all patients were completed successfully without relevant complications.In amnion group,8 patients exhibited relapse in the first month and 2 patients in three months after surgery;in chitosan group,23 women exhibited relapse in the first month and 18 patients in three months after surgery.Statistical analysis revealed that the recurrence rate of adhesion in amnion group was significantly lower than those of chitosan group in the first and three months after surgery(P1=0.000,P2=0.000).After TCRA,fresh amnion graft plays a significant role in preventing further adhesions than injections of chitosan. | Changjiang Li Aiqi Cai Congcong Sun Benyuan Wu Xinpei Chen Yanhua Mao Yingfeng Zhang Yating Gou Jie Yu Yuhan Wang Huanhuan Yu Jia Wang | 2020 | Genes & Diseases2020，7，2： | 11 |
| 2 | Cloning of Ln Gene Through Combined Approach of Map-based Cloning and Association Study in Soybean显示文摘Increasing yield is one of the most important goals in crop breeding.Soybean(Glycine max L.Merr.),one of the most economically important leguminous seed crops,provides the majority of plant proteins,and more than a quarter of the world's food and animal feed(Graham and Vance,2003). The yield of soybean is finally determined by the number of seeds per unit area,which affected by many characters,such as height,branching number,photosynthesis,seed size,seed number.The number of seeds per pod is taken for one of the critical components that related to yield(You et al.,1995),and it has long been considered in soybean production(Takahashi, | Chao Fang Weiyu Li Guiquan Li Zheng Wang Zhengkui Zhou Yanming Ma Yanting Shen Congcong Li Yunshuai Wu Baoge Zhu Weicai Yang Zhixi Tian | 2013 | Journal of Genetics and Genomics2013，40，2： | 7 |
| 3 | A stretchable triboelectric generator with coplanar integration design of energy harvesting and strain sensing显示文摘The rapid development of flexible triboelectric nanogenerators(TENGs)has become an alternative to batteries for wearable devices.Stretchable,multifunctional,and low-cost are the primary development directions for these wearable devices based on TENG.Herein,a stretchable triboelectric generator with coplanar integration was designed for energy harvesting and force sensing.The industrial conductive silicone and silicone were used to fabricate the TENG with a thickness of less than 0.9 mm.When the elongation was less than 150%,TENG exhibited excellent linear characteristics in the resistance-tensile strain correspondence,and the coefficient of determination was 0.99.This stretchable TENG with a sufficient contact area of 9 cm^(2) could generate a short-circuit current of 2μA when it was in contact with the skin.Lastly,an intelligent tension monitoring wearable device that can effectively measure the tensile force was developed.Such a stretchable,coplanar integration-based,and low-cost wearable device has excellent applicability in wearable electronics. | WU Bin ZHANG ZengXing XUE XiaoBin HAO CongCong ZHANG WenJun BI RuiYu WANG Qiang XUE ChenYang | 2022 | Science China(Technological Sciences)2022，65，1： | 3 |
| 4 | Association of assisted reproductive technology, germline de novo mutations and congenital heart defects in a prospective birth cohort study显示文摘Emerging evidence suggests that children conceived through assisted reproductive technology(ART)have a higher risk of congenital heart defects(CHDs)even when there is no family history.De novo mutation(DNM)is a well-known cause of sporadic congenital diseases;however,whether ART procedures increase the number of germline DNM(gDNM)has not yet been well studied.Here,we performed whole-genome sequencing of 1137 individuals from 160 families conceived through ART and 205 families conceived spontaneously.Children conceived via ART carried 4.59 more gDNMs than children conceived spontaneously,including 332 paternal and 1.26 maternal DNMs,after correcting for parental age at conception,cigarette smoking,alcohol drinking,and exercise behaviors.Paternal DNMs in offspring conceived via ART are characterized by C>T substitutions at CpG sites,which potentially affect protein-coding genes and are significantly associated with the increased risk of CHD.In addition,the accumulation of non-coding functional mutations was independently associated with CHD and 87.9% of the mutations were originated from the father.Among ART offspring,infertility of the father was associated with elevated paternal DNMs;usage of both recombinant and urinary follicle-stimulating hormone and high-dosage human chorionic gonadotropin trigger was associated with an increase of maternal DNMs.In sum,the increased gDNMs in offspring conceived by ART were primarily originated from fathers,indicating that ART itself may not be a major reason for the accumulation of gDNMs.Our findings emphasize the importance of evaluating the germline status of the fathers in families with the use of ART. | Cheng Wang Hong Lv Xiufeng Ling Hong Li Feiyang Diao Juncheng Dai Jiangbo Du Ting Chen Qi Xi Yang Zhao Kun Zhou Bo Xu Xiumei Han Xiaoyu Liu Meijuan Peng Congcong Chen Shiyao Tao Lei Huang Cong Liu Mingyang Wen Yangqian Jiang Tao Jiang Chuncheng Lu Wei Wu Di Wu Minjian Chen Yuan Lin Xuejiang Guo Ran Huo Jiayin Liu Hongxia Ma Guangfu Jin Yankai Xia Jiahao Sha Hongbing Shen Zhibin Hu | 2021 | Cell Research2021，31，8： | 2 |
| 5 | A Hybrid Conjugate Gradient Algorithm for Solving Relative Orientation of Big Rotation Angle Stereo Pair显示文摘The fast convergence without initial value dependence is the key to solving large angle relative orientation.Therefore,a hybrid conjugate gradient algorithm is proposed in this paper.The concrete process is:①stochastic hill climbing(SHC)algorithm is used to make a random disturbance to the given initial value of the relative orientation element,and the new value to guarantee the optimization direction is generated.②In local optimization,a super-linear convergent conjugate gradient method is used to replace the steepest descent method in relative orientation to improve its convergence rate.③The global convergence condition is that the calculation error is less than the prescribed limit error.The comparison experiment shows that the method proposed in this paper is independent of the initial value,and has higher accuracy and fewer iterations. | Jiatian LI Congcong WANG Chenglin JIA Yiru NIU Yu WANG Wenjing ZHANG Huajing WU Jian LI | 2020 | Journal of Geodesy and Geoinformation Science2020，3，2： | 2 |
| 6 | Effects of typhoon Roke and Haitang on phytoplankton community structure in northeastern South China sea显示文摘The influence of typhoon and Kuroshio intrusion process on the natural phytoplankton assemblages in the northeastern South China Sea(neSCS)was examined during a cruise in summer 2017.One hundred ninety-six seawater samples were collected and analyzed in the neSCS.In total,299 species were identified belonging to 82 genera,mostly dominated by Bacillariophyta(159),followed by Dinophyta(132),Cyanophyta(4)and Chrysophyta(4).Among all,Thalassionema nitzschioides,Thalassionema frauenfeldii,Thalassiosira minima,in Bacillariophyta,Prorocentrum lenticulatum,Prorocentrum compressum in Dinophyta,and Trichodesmium thiebautii,in the Cyanophyta were the most dominated species,respectively.Correlation analysis shows compared with other groups Bacillariophyta was mostly influenced by silicate,whereas,Dinophyta and Cyanophyta showed significant correlation with temperature,salinity,phosphate,and nitrate.After the typhoon,the higher abundance of Dinophyta was observed,whereas it was lower in case of Bacillariophyta and Cyanophyta,shows typhoon“Roke“and”Haitang”had a significant influence on the phytoplankton assemblages,which could be manifested by the variations of total phytoplankton abundance in the surface water of neSCS.Overall,our present study provides the latest in-depth information about how the environmental factors influencing the phytoplankton density and diversity in the neSCS during summer. | Yingjie Mao Jun Sun Congcong Guo Yuqiu Wei Xingzhou Wang Shuang Yang Chao Wu | 2019 | Ecosystem Health and Sustainability2019，5，1： | 2 |
| 7 | Analysis method of thermal dam deformation显示文摘Based on the internal temperature variation of a dam lagging behind the ambient temperature variation,the ambient temperature of continuous variation is disctetized,and the functional expression of the thermal displacement component of the dam caused by single instantaneous temperature variation is obtained.Considering the temporal and spatial distribution law of the ambient temperature and its relation with air and water temperature,the function is expanded into a Taylor series.As a result,the improved thermal displacement component expression for a dam monitoring model is obtained. | XU BaoSong LIU BeiBei ZHENG DongJian CHEN Lan WU CongCong | 2012 | Science China(Technological Sciences)2012，55，6： | 2 |
| 8 | Effects of injection of anti-corticotropin release hormone serum in the lateral ventricles and electroacupuncture analgesia on pain threshold in rats with adjuvant arthritis显示文摘Rat models of adjuvant arthritis were established, and anti-corticotropin release hormone serum injection in the lateral ventricles and electroacupuncture at right Jiaji (EX-B2) were performed. The pain threshold was decreased at 45 and 60 minutes after injection of the anti-corticotropin release hormone serum. Electroacupuncture at Jiaji can resist this effect. Immunohistochemical staining results showed that the expression of corticotropin release hormone in the hypothalamic paraven-tricular nucleus was greater in the electroacupuncture + anti-corticotropin release hormone serum group compared with the anti-corticotropin release hormone serum group. The expression of corticotropin release hormone was correlated with the pain threshold. The effect of endogenous corticotropin release hormone in pain modulation can be obstructed by anti-corticotropin release hormone serum. The analgesia of electroacupuncture can partially resist the depressed pain threshold caused by injection of anti-corticotropin release hormone serum. The analgesic effect of elec-troacupuncture is associated with the corticotropin release hormone content in the hypothalamus. | Yunying Qiao Fudong Wu Jian Wang Xiaolu Cui Congcong Liu Xinlong Zhu | 2012 | Neural Regeneration Research2012，7，21： | 2 |
| 9 | Meso- porous (N, S)-codoped TiO2 nanoparticles as effective photoanode for dye-sensitized solar cells显示文摘 | Li Yuanyuan Jia Lichao Wu Congcong et a | 2012 | J Alloys Compd2012，512，1： | 1 |
| 10 | A complete assembly of the rice Nipponbare reference genome显示文摘Dear Editor,In 2005,the current commonly used rice reference genome(Oryza sativa ssp.japonica cv.Nipponbare)was initially released by the International Rice Genome Sequencing Project(International Rice Genome Sequencing Project,2005).Thereafter,the reference genome was further updated in 2013 with improved genome assembly(IRGSP-1.0)and gene annotations(MSU7,RAP-DB)(Kawahara et al.,2013;Sakai et al.,2013).In the past 10 years,this reference has been serving as one of the most important genetic resources for subsequent rice functional genomics efforts.As several rice genomes had been assembled into gapless chromosomes with only 2–5 telomeres absent(Li et al.,2021;Song et al.,2021;Zhang et al.,2022),the IRGSP1.0 and its annotations still performed as the most widely used reference.However,limitations of sequencing technology and intricate genomic organization led to an under-representation of complex regions in this reference,leaving a total of 72 major gaps(including 19 telomeres),167 minor gaps,and 779 unknown bases(Kawahara et al.,2013),with an estimated length of3%of the genome unsolved. | Lianguang Shang Wenchuang He Tianyi Wang Yingxue Yang Qiang Xu Xianjia Zhao Longbo Yang Hong Zhang Xiaoxia Li Yang Lv Wu Chen Shuo Cao Xianmeng Wang Bin Zhang Xiangpei Liu Xiaoman Yu Huiying He Hua Wei Yue Leng Chuanlin Shi Mingliang Guo Zhipeng Zhang Bintao Zhang Qiaoling Yuan Hongge Qian Xinglan Cao Yan Cui Qianqian Zhang Xiaofan Dai Congcong Liu Longbiao Guo Yongfeng Zhou Xiaoming Zheng Jue Ruan Zhukuan Cheng Weihua Pan Qian Qian | 2023 | Molecular Plant2023，16，8： | 1 |
| 11 | Mesoporous (N, S)-codoped TiO2 nanoparticles as ef- fective photoanode for dye-sensitized solar cells显示文摘 | LI Yuanyuan JIA Lichao WU Congcong | 2012 | Journal of Alloys and Compounds2012，512，： | 1 |
| 12 | The profound influence of Kuroshio intrusion on microphytoplankton community in the northeastern South China Sea显示文摘To further understand the effect of Kuroshio intrusion on phytoplankton community structure in the northeastern South China Sea(NSCS,14°–23°N,114°–124°E),one targeted cruise was carried out from July to August,2017.A total of 79 genera and 287 species were identified,mainly including Bacillariophyta(129 species),Pyrrophyta(150 species),Cyanophyta(4 species),Chrysophyta(3 species)and Haptophyta(1 species).The average abundance of phytoplankton was 2.14×10~3 cells/L,and Cyanobacterium was dominant species accounting for 86.84%of total phytoplankton abundance.The abundance and distribution of dominant Cyanobacterium were obviously various along the flow of the Kuroshio,indicating the Cyanobacterium was profoundly influenced by the physical process of the Kuroshio.Therefore,Cyanobacterium could be used to indicate the influence of Kuroshio intrusion.In addition,the key controlling factors of the phytoplankton community were nitrogen,silicate,phosphate and temperature,according to Canonical Correspondence Analysis.However,the variability of these chemical parameters in the study water was similarly induced by the physical process of circulations.Based on the cluster analysis,the similarity of phytoplankton community is surprisingly divided by the regional influence of the Kuroshio intrusion,which indicated Kuroshio intrusion regulates phytoplankton community in the NSCS. | Xingzhou Wang Yuqiu Wei Chao Wu Congcong Guo Jun Sun | 2020 | Acta Oceanologica Sinica2020，39，8： | 1 |
| 13 | Optimization methods of production layer combination for coalbed methane development in multi-coal seams显示文摘Based on the productivity equation of coalbed methane(CBM) wells, three indexes, main production layer optimization index, main production layer expansion index and capacity contribution index are proposed, with which the three-step optimization method of production-layer combination is established. In selecting main production layer, the coal seam thickness, CBM content, coal seam permeability, coal seam reservoir pressure and coal structure are considered comprehensively to evaluate the potential of the production layer. In selecting expansion of the main production layer combination, on the premise of ensuring full and slow desorption of the main production layer and non-exposure of the main production layer out of liquid surface, the degree of mutual interference between the main and non-main production layers is comprehensively evaluated by coupling the critical desorption pressure, layer spacing and reservoir pressure gradient difference. In optimizing production layer combination, the main concern is the economic efficiency of the combined layers. Only when the contribution coefficient of the main production layer is greater than 30% and the contribution index of the other production layers is more than 10%, the economic benefit of a CBM well after being put into production can be ensured. Based on the comparative analysis of the development effect of the development test wells in Songhe of Guizhou province, it is proved that the 'three-step method' for the optimization of production-layer combination is scientific and practical, and can be used to design the multi-layer commingling scheme of coalbed methane. | YANG Zhaobiao ZHANG Zhengguang QIN Yong WU Congcong YI Tongsheng LI Yangyang TANG Jun CHEN Jie | 2018 | Petroleum Exploration and Development2018，45，2： | 1 |
| 14 | Increased clonal dissemination of OXA-232-producing ST15 Klebsiella pneumoniae in Zhejiang,China from 2018 to 2021显示文摘Background OXA-232-producing Klebsiella pneumoniae was first identified in China in 2016,and its clonal transmission was reported in 2019.However,there are no prevalence and genotypic surveillance data available for OXA-232 in China.Therefore,we investigated the trends and characteristics of OXA-232 type carbapenemase in Zhejiang Province,China from 2018 to 2021.Methods A total of 3278 samples from 1666 patients in the intensive care units were collected from hospitals in Zhejiang Province from 2018 to 2021.Carbapenem-resistant isolates were initially selected by China Blue agar plates supplemented with 0.3μg/ml meropenem,and further analyzed by matrix-assisted laser desorption/ionization-time-of-flight mass spectrometry identification,immune colloidal gold technique,conjugation experiment,antimicrobial susceptibility testing and whole genome sequencing.Results A total of 79 OXA-producing strains were recovered,with the prevalence increased from 1.8%[95%confidence interval(CI):0.7–3.7%]in 2018 to 6.0%(95%CI:4.4–7.9%)in 2021.Seventy-eight strains produced OXA-232 and one produced OXA-181.The blaOXA-232 gene in all strains was located in a 6141-bp ColKP3-type non-conjugative plasmid and the blaOXA-181 gene was located in a 51,391-bp ColKP3/IncX3-type non-conjugative plasmid.The blaOXA-232-producing K.pneumoniae was dominated(75/76)by isolates of sequence type 15(ST15)that differed by less than 80 SNPs.All OXA-producing strains(100%,95%CI:95.4–100.0%)were multidrug-resistant.Conclusions From 2018 to 2021,OXA-232 is the most prevalent OXA-48-like derivative in Zhejiang Province,and ST15 K.pneumoniae isolates belonging to the same clone are the major carriers.The transmission of ColKP3-type plasmid to E.coli highlighted that understanding the transmission mechanism is of great importance to delay or arrest the propagation of OXA-232 to other species. | Yanyan Zhang Xuemei Yang Congcong Liu Ling Huang Lingbin Shu Qiaoling Sun Hongwei Zhou Yonglu Huang Chang Cai Xiaoyan Wu Sheng Chen Rong Zhang | 2023 | Infectious Diseases of Poverty2023，12，2： | 0 |
| 15 | Effects of Low Temperature Stress on the Morphology and hsp70 and hsp90 Gene Expression of Phascolosoma esculenta显示文摘Phascolosoma esculenta is an intertidal organism that has recently attracted attention because of its ability to survive at relatively low temperatures.However,the gene regulation in P.esculenta in relation to its response to low temperatures is unclear.To explore the low temperature adaptability of P.esculenta,this study analyzed the changes in the morphology and hsp70 and hsp90 gene expression of P.esculenta exposed to a low temperature gradient.At 5℃,P.esculenta stretched and softened,and some individuals moved apart from the group.Histological analysis revealed cuticle breaches,myofiber scattering,disruption of the body wall,and epithelial layer dispersion and muscle fiber rupturing in the nephridium.Furthermore,the mRNA expression levels of hsp70 and hsp90 increased under acute low temperature stress,suggesting that these genes function in low temperature tolerance.Overall,low temperature stress causes morphological changes and histological damage in P.esculenta,and hsp70 and hsp90 potentially function in the low temperature adaptability of P.esculenta.Our results provide new insights into the adaptive strategies of P.esculenta under low temperature environments. | SHEN Weiliang LIU Cheng NI Jie GAO Xinming NI Junjie WANG Jianping JIN Shan HOU Congcong WU Xiongfei ZHU Junquan | 2021 | Journal of Ocean University of China2021，20，1： | 0 |
| 16 | Development unit division and favorable area evaluation for joint mining coalbed methane显示文摘Based on the productivity equation of coalbed methane (CBM) well, considering the impact of coal reservoir reformability on gas well productivity, the main production layer optimization index in the “three-step method” of optimal combination of production layers is corrected, and then the CBM production layer potential index is introduced to evaluate favorable areas for commingled multi-coal seam production. Through analysis of the key parameters of coal reservoirs affecting the CBM productivity index, a development unit division method for areas with multi-coal seams is established, and a quantitative grading index system is proposed. On this basis, the evaluation process of CBM development favorable area is developed: the mature 3-D modeling technology is used to characterize the reservoir physical properties of multi-coal seams in full-scale;the production layer potential index of each grid is calculated, and the production layer potential index contour under single-layer or commingled multi-layer production are plotted;according to the distribution of the contour of production layer potential index, the quantitative index of CBM development unit is adopted to outline the grade I, II, III coal reservoir distribution areas, and thus to pick out the favorable development areas. The practical application in the Yuwang block of Laochang in Yunnan proved that the favorable area evaluation process proposed can effectively overcome the defects of selecting favorable development areas only relying on evaluation results of a major coal seam pay, and enhance the accuracy of the evaluation results, meeting the requirements of selecting favorable areas for multi-coal seam commingled CBM production. | YANG Zhaobiao LI Yangyang QIN Yong SUN Hansen ZHANG Ping ZHANG Zhengguang WU Congcong LI Cunlei CHEN Changxiao | 2019 | Petroleum Exploration and Development2019，46，3： | 0 |
| 17 | New insights into the carotenoid biosynthesis in Torreya grandis kernels显示文摘Torreya grandis is a characteristic rare economic tree species in subtropical mountainous areas. The nut has a variety of bioactive compounds, such as polyphenols and vitamins. However, the carotenoids compositions and its regulatory mechanisms underlying carotenoid biosynthesis in kernels remain unknown. Here, the major carotenoids in the kernel were analyzed. The result showed that lutein and β-carotene were the predominant carotenoids in the kernel, while low levels of a-carotenoid and zeaxanthin were detected. Lutein and β-carotene were decreased during the maturation of kernel. Expression analysis by RNA-seq and q RT-PCR indicated that the expressions of TgCYP97A3 and TgLCYB were also reduced during the maturation of kernel. The contents of lutein or β-carotene were obviously increased in tobacco transiently overexpressing TgCYP97A3 or TgLCYB. Moreover, DPPH radical scavenging activity and FRAP were also significantly enhanced. In addition, several MYB and WRKY transcription factors TgMYBS3, TgMYB48 and TgWRKY11 were identified to positively regulate the TgCYP97A3 expression, while TgMYB48, TgWRKY2 and TgWRKY11 could upregulate the TgLCYB expression. The illustration of carotenoids biosynthesis and its molecular mechanism in kernels not only provides a basis for understanding carotenoids biosynthesis in kernels, but also enables the use of molecular biotechnology to develop new health products rich in carotenoids based on T. grandis nuts. | Jingwei Yan Hao Zeng Weijie Chen Jiali Luo Congcong Kong Heqiang Lou Jiasheng Wu | 2023 | Horticultural Plant Journal2023，9，6： | 0 |
| 18 | Resolving Mixed Intermediate Phases in Methylammonium-Free Sn-Pb Alloyed Perovskites for High-Performance Solar Cells显示文摘The complete elimination of methylammonium(MA)cations in Sn-Pb composites can extend their light and thermal stabilities.Unfortunately,MA-free Sn-Pb alloyed perovskite thin films suffer from wrinkled surfaces and poor crystallization,due to the coexistence of mixed intermediate phases.Here,we report an additive strategy for finely regulating the impurities in the intermediate phase of Cs_(0.25)FA_(0.75)Pb_(0.6)Sn_(0.4)I_(3)and,thereby,obtaining high-performance solar cells.We introduced d-homoserine lactone hydrochloride(D-HLH)to form hydrogen bonds and strong Pb-O/Sn-O bonds with perovskite precursors,thereby weakening the incomplete complexation effect between polar aprotic solvents(e.g.,DMSO)and organic(FAI)or inorganic(CsI,PbI_(2),and SnI_(2))components,and balancing their nucleation processes.This treatment completely transformed mixed intermediate phases into pure preformed perovskite nuclei prior to thermal anneal-ing.Besides,this D-HLH substantially inhibited the oxidation of Sn^(2+) species.This strategy generated a record efficiency of 21.61%,with a Voc of 0.88 V for an MA-free Sn-Pb device,and an efficiency of 23.82%for its tandem device.The unencapsulated devices displayed impressive thermal stability at 85℃ for 300 h and much improved continuous operation stability at MPP for 120 h. | Zhanfei Zhang Jianghu Liang Jianli Wang Yiting Zheng Xueyun Wu Congcong Tian Anxin Sun Zhenhua Chen Chun-Chao Chen | 2022 | Nano-Micro Letters2022，14，10： | 0 |
| 19 | The proximity between hydroxyl and single atom determines the catalytic reactivity of Rh1/CeO_(2) single-atom catalysts显示文摘The local structure of the metal single-atom site is closely related to the catalytic activity of metal single-atom catalysts(SACs).However,constructing SACs with homogeneous metal active sites is a challenge due to the surface heterogeneity of the conventional support.Herein,we prepared two Rh1/CeO_(2)SACs(0.5Rh1/r-CeO_(2)and 0.5Rh1/c-CeO_(2),respectively)using two shaped CeO_(2)(rod and cube)exposing different facets,i.e.,CeO_(2)(111)and CeO_(2)(100).In CO oxidation reaction,the T100 of 0.5Rh1/r-CeO_(2)SACs is 120°C,while the T100 of 0.5Rh1/c-CeO_(2)SACs is as high as 200°C.Via in-situ CO diffuse reflectance infrared Fourier transform spectroscopy(CO-DRIFTS),we found that the proximity between OH group and Rh single atom on the plane surface plays an important role in the catalytic activity of Rh1/CeO_(2)SAC system in CO oxidation.The Rh single atom trapped at the CeO_(2)(111)crystal surface forms the Rh1(OH)adjacent species,which is not found on the CeO_(2)(100)crystal surface at room temperature.Furthermore,during CO oxidation,the OH group far from Rh single atom on the 0.5Rh1/c-CeO_(2)disappears and forms Rh1(OH)adjacent species when the temperature is above 150°C.The formation of Rh1(OH)adjacentCO intermediate in the reaction is pivotal for the excellent catalytic activity,which explains the difference in the catalytic activity of Rh single atoms on two different CeO_(2)planes.The formed Rh1(OH)adjacent-O-Ce structure exhibits good stability in the reducing atmosphere,maintaining the Rh atomic dispersion after CO oxidation even when pre-reduced at high temperature of 500°C.Density functional theory(DFT)calculations validate the unique activity and reaction path of the intermediate Rh1(OH)adjacentCO species formed.This work demonstrates that the proximity between metal single atom and hydroxyl can determine the formation of active intermediates to affect the catalytic performances in catalysis. | Danfeng Wu Shuyun Zhou Congcong Du Juan Li Jianyu Huang Hong-xia Shen Abhaya K.Datye Shan Jiang Jeffrey T.Miller Sen Lin Haifeng Xiong | 2024 | Nano Research2024，17，1： | 0 |
| 20 | A centromere map based on super pan-genome highlights the structure and function of rice centromeres显示文摘Rice(Oryza sativa)is a significant crop worldwide with a genome shaped by various evolutionary factors.Rice centromeres are crucial for chromosome segregation,and contain some unreported genes.Due to the diverse and complex centromere region,a comprehensive understanding of rice centromere structure and function at the population level is needed.We constructed a high-quality centromere map based on the rice super pangenome consisting of a 251-accession panel comprising both cultivated and wild species of Asian and African rice.We showed that rice centromeres have diverse satellite repeat CentO,which vary across chromosomes and subpopulations,reflecting their distinct evolutionary patterns.We also revealed that long terminal repeats(LTRs),especially young Gypsy-type LTRs,are abundant in the peripheral CentO-enriched regions and drive rice centromere expansion and evolution.Furthermore,high-quality genome assembly and complete telomere-to-telomere(T2T)reference genome enable us to obtain more centromeric genome information despite mapping and cloning of centromere genes being challenging.We investigated the association between structural variations and gene expression in the rice centromere.A centromere gene,OsMAB,which positively regulates rice tiller number,was further confirmed by expression quantitative trait loci,haplotype analysis and clustered regularly interspaced palindromic repeats(CRISPR)/CRISPR-associated protein9 methods.By revealing the new insights into the evolutionary patterns and biological roles of rice centromeres,our finding will facilitate future research on centromere biology and crop improvement. | Yang Lv Congcong Liu Xiaoxia Li Yueying Wang Huiying He Wenchuang He Wu Chen Longbo Yang Xiaofan Dai Xinglan Cao Xiaoman Yu Jiajia Liu Bin Zhang Hua Wei Hong Zhang Hongge Qian Chuanlin Shi Yue Leng Xiangpei Liu Mingliang Guo Xianmeng Wang Zhipeng Zhang Tianyi Wang Bintao Zhang Qiang Xu Yan Cui Qianqian Zhang Qiaoling Yuan Noushin Jahan Jie Ma Xiaoming Zheng Yongfeng Zhou Qian Qian Longbiao Guo Lianguang Shang | 2024 | Journal of Integrative Plant Biology2024，66，2： | 0 |
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