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| 1 | Dendrite-structured FeF_(2) consisting of closely linked nanoparticles as cathode for high-performance lithium-ion capacitors显示文摘Lithium-ion capacitors(LICs)are regarded as a good choice for next-generation energy storage devices,which are expected to exhibit high energy densities,high power densities,and ultra-long cycling stability.Nevertheless,only a few battery-type cathode materials with limited kinetic properties can be employed in LICs,and their electrochemical properties need to be optimized urgently.Here,we exploit a new dendrite-structured FeF_(2) consisting of closely linked primary nanoparticles using a facile solvothermal method combined with the subsequent annealing treatment.This particular architecture has favorable transport pathways for both lithium ions and electrons and exhibits an ultrafast chargedischarge capability with high reversible capacities.Furthermore,a well-designed LIC employing the prepared dendrite-structured FeF_(2) as the battery-type cathode and commercialized activated carbon(AC)as supercapacitor-type anode was constructed in an organic electrolyte containing Li ions.The LIC operates at an optimal voltage range of 1.1-3.8 V and shows a maximum high energy density of 152 W h kg^(-1) and a high power density of 4900 W kg^(-1) based on the total mass of cathode and anode.Long-term cycling stability(85%capacity retention after 2000 cycles)was achieved at 1 A g^(-1).This work suggests that the dendrite-structured FeF_(2) is a prime candidate for high-performance LICs and accelerates the development of hybrid ion capacitor devices. | Huanyu Liang Zhengqiang Hu Zhongchen Zhao Dong Chen Hao Zhang Huaizhi Wang Xia Wang Qiang Li Xiangxin Guo Hongsen Li | 2021 | Journal of Energy Chemistry2021，30，4： | 3 |
| 2 | Heterogeneous electrolyte membranes enabling double-side stable interfaces for solid lithium batteries显示文摘The solid polymer electrolyte(SPE) is one of the most promising candidates for building solid lithium batteries with high energy density and safety due to its advantages of flexibility and light-weight.However,the conventional monolayered electrolytes usually exhibit unstable contacts with either high-voltage cathodes or Li-metal anodes during cell operation.Herein,heterogeneous dual-layered electrolyte membranes(HDEMs) consisting of the specific functional polymer matrixes united with the designed solid ceramic fillers are constructed to address the crucial issues of interfacial instability.The electrolyte layers composed of the high-conductivity and oxidation-resistance polyacrylonitrile(PAN) combined with Li_(0.33)La_(0.557)TiO_(3) nanofibers are in contact with the high-voltage cathodes,achieving the compatible interface between the cathodes and the electrolytes.Meanwhile,the electrolyte layers composed of the highstability and dendrite-resistance polyethylene oxide(PEO) with Li_(6.4)La_(3) Zr_(1.4)Ta_(0.6)O_(12) nanoparticles are in contact with the Li-metal anodes,aiming to suppress the dendrite growth,as well as avoid the passivation between the PAN and the Li-metal.Consequently,the solid LiNi_(0.6)Co_(0.2)Mn_(0.2)O2‖Li full cells based on the designed HDEMs show the good rate and cycling performance,i.e.the discharge capacity of 170.1 mAh g^(-1) with a capacity retention of 78.2% after 100 cycles at 0.1 C and 30℃.The results provide an effective strategy to construct the heterogeneous electrolyte membranes with double-side stable electrode/-electrolyte interfaces for the high-voltage and dendrite-free solid lithium batteries. | Shuang Mu Weilin Huang Wuhui Sun Ning Zhao Mengyang Jia Zhijie Bi Xiangxin Guo | 2021 | Journal of Energy Chemistry2021，30，9： | 2 |
| 3 | Sandwiched N-carbon@Co_(9)S_(8)@Graphene nanosheets as high capacity anode for both half and full lithium-ion batteries显示文摘Transition metal sulfides(TMSs) are promising candidates for replacing graphite anode in LIBs. However,the low conductivity and structural collapse caused by the large volume change during lithium insertion and extraction greatly limit its application. Herein, we report a unique design of a two-dimensional(2 D) sandwich structure of N-doped carbon@Co9 S8@graphene(N–C@Co9 S8@G) with multilayer structure. Electrochemical tests reveal that the N–C@Co9 S8@G nanosheets possess a high reversible capacity(1009 mAhg^(-1) at 0.1 Ag^(-1)), and excellent rate capability(422mAhg^(-1) at 10 Ag^(-1)) and long cycle life(853 m Ahg^(-1) at 1Ag^(-1) for 500 cycles). Experimental studies reveal that capacitive storage contributes to the high reversible capacity. The lithium storage kinetics are studied by Galvanostatic intermittent titration technique(GITT) and electrochemical impedance spectroscopy(EIS). Meanwhile, the potential of N–C@Co9 S8@G anode in a full cell using Li Co O2 as the cathode is also demonstrated, exhibiting a high reversible capacity of 300mAhg^(-1) cycles at 0.1Ag^(-1). The strategy proposed in this work paves the way to engineering high performance anodes in LIBs. | Ningning Li Li Sun Kai Wana Sheng Xu Jun Zhang Xiangxin Guo Xianghong Liu | 2020 | Journal of Energy Chemistry2020，29，12： | 2 |
| 4 | Multilayered structure of N-carbonenvelopediron oxide/graphene nanocomposites as an improved anode for Li-ion battery显示文摘Transition metal oxides with high capacity are considered a promising electrode material for lithium-ion batteries(LIBs).Nevertheless,the huge volume expansion and poor conductivity severely hamper their practical application.In this work,a carbon riveting method is reported to address the above issues by designing multilayered N-doped carbon(N-carbon) enveloped Fe3O4/graphene nanosheets.When evaluated as a negative electrode,the N-carbon/Fe3O4/graphene nanocomposites demonstrate greatly enhanced electrochemical properties compared with Fe3O4/graphene.The N-carbon/Fe3O4/graphene presents a superior reversible capacity(807 mAh/g) over Fe3O4/graphene(540 mAh/g).Furthermore,it affords a considerable capacity of 550 mAh/g at 1 A/g over 700 cycles,indicating supe rb cycling stability.The structure-property correlation studies reveal that the carbon riveting layer is essential for enhancing the lithium diffusion kinetics.The good electrochemical properties and effective structure design make the carbon riveting strategy quite general and reliable to manipulate high performance electrodes for future LIBs. | Li Sun Kai Wang Ningning Li Jun Zhang Xiangxin Guo Xianghong Liu | 2020 | Chinese Chemical Letters2020，31，9： | 2 |
| 5 | Combination of Organic and Inorganic Electrolytes for Composite Membranes Toward Applicable Solid Lithium Batteries显示文摘To meet the demand for long-range electric vehicles with high-energy-density batteries,the solid-state batteries(SSBs)have attracted ever-increasing attention due to their enormous potential in affording the energy density greater than 400 W·h/kg.As the key materials,the solid electrolytes can be classified as inorganic electrolyte and organic electrolyte.The former usually has high ionic conductivity,good stability and mechanical properties,whereas being heavy and brittle.The latter is usually flexible,light and easy to mass produce,nevertheless has poor ionic conductivity and stability.Thus,the combination of the organic and the inorganic electrolytes for the composite membranes has become the inevitable trend to achieve the high energy density and safety of lithium batteries.From the perspective of practical application,this paper discusses how to construct the ideal organic-inorganic composite solid electrolyte with low areal specific resistance,thin texture,wide electrochemical window and high safety for applicable SSBs.Furthermore,the critical challenges and future development directions are prospected for the composite solid electrolytes. | MU Shuang BI Zhijie GAO Shenghan GUO Xiangxins | 2021 | Chemical Research in Chinese Universities2021，37，2： | 1 |
| 6 | Tungsten oxide thin films for highly sensitive triethylamine detection显示文摘Metal oxide semiconductor(MOS)thin films are promising sensing layer for integration in gas sensor devices for detecting toxic and harmful molecules.Herein,tungsten oxide(WO_(3))thin films are deposited on interdigital electrodes by vacuum thermal evaporation to realize batch fabrication of high-performance gas sensors.Subsequent annealing at different temperatures allows for regulation of the concentration of oxygen vacancies in the WO_(3) films,which has been found to exert a great influence on the sensor properties.In addition,the surface structure of WO_(3) films is also highly dependent on the annealing temperature.Gas sensing investigations show that the WO_(3) sensor annealed at 500℃ pos-sesses the best sensing properties for detecting triethylamine(TEA)including very high response,good selectivity,fast response,and low limit of detection(63 ppb).The excellent sensor performances are attributed to the enhanced adsorption of oxidative oxygen species due to the presence of abundant oxygen vacancies.The scalable fabrication of WO_(3) thin film gas sensors and the oxygen vacancy engi-neering strategy proposed herein may shed some light to developing high performance environmental sensors. | Guanglu Lei Zishuo Li Guocai Lu Jinyuan Hu Haochuan Shang Xiaolei Zhang Xianghong Liu Jun Zhang Xiangxin Guo | 2022 | Journal of Materiomics2022，8，2： | 1 |
| 7 | Visible transparent,infrared stealthy polymeric films with nanocoating of ITO@MXene enable efficient passive radiative heating and solar/electric thermal conversion显示文摘Visible transparent yet low infrared-emissivity(ε)polymeric materials are highly anticipated in many applications,whereas the fabrication of which remains a formidable challenge.Herein,visible transparent,flexible,and low-εpolymeric films were fabricated by nanocoating decoration of indium tin oxide(ITO)and MXene on polyethylene terephthalate(PET)film surface through magnetron sputtering and spray coating,respectively.The obtained PET-ITO@MXene(PET-IM)film exhibits lowεof 24.7%and high visible transmittance exceeding 50%,endowing it with excellent visible transparent infrared stealthy by reducing human skin radiation temperature from 32 to 20.8°C,and remarkable zero-energy passive radiative heating capability(5.7°C).Meanwhile,the transparent low-εPET-IM film has high solar absorptivity and electrical conductivity,enabling superior solar/electric to thermal conversion performance.Notably,the three heating modes of passive radiative and active solar/electric can be integrated together to cope with complex heating scenarios.These visible transparent low-εpolymeric films are highly promising in infrared stealth,building daylighting and thermal management,and personal precision heating. | Xingyuan Du Xiangxin Li Yuxuan Zhang Xinyi Guo Zhengji Li Yanxia Cao Yanyu Yang Wanjie Wang Jianfeng Wang | 2023 | Nano Research2023，16，2： | 1 |
| 8 | Polydopamine-mediated synthesis of Si@carbon@graphene aerogels for enhanced lithium storage with long cycle life显示文摘The application of Si as the anode materials for lithium-ion batteries(LIBs) is still severely hindered by the rapid capacity decay due to the structural damage caused by large volume change(> 300%) during cycling. Herein, a three-dimensional(3 D) aerogel anode of Si@carbon@graphene(SCG) is rationally constructed via a polydopamine-assisted strategy. Polydopamine is coated on Si nanoparticles to serve as an interface linker to initiate the assembly of Si and graphene oxide, which plays a crucial role in the successful fabrication of SCG aerogels. After annealing the polydopamine is converted into N-doped carbon(N-carbon) coatings to protect Si materials. The dual protection from N-carbon and graphene aerogels synergistically improves the structural stability and electronic conductivity of Si, thereby leading to the significantly improved lithium storage properties. Electrochemical tests show that the SCG with optimized graphene content delivers a high capacity(712 m Ah/g at 100 m A/g) and robust cycling stability(402 m Ah/g at 1 A/g after 1500 cycles). Furthermore, the full cell using SCG aerogels as anode exhibits a reversible capacity of 187.6 m Ah/g after 80 cycles at 0.1 A/g. This work provides a plausible strategy for developing Si anode in LIBs. | Ningning Li Yi Liu Xiaoyu Ji Jiaxin Feng Kai Wang Jiayue Xie Guanglu Lei Xianghong Liu Xiangxin Guo Jun Zhang | 2021 | Chinese Chemical Letters2021，32，12： | 1 |
| 9 | Morphology investigation of yttrium aluminum garnet nano-powders prepared by a sol-gel combustion method显示文摘 | Kai Guo Hao-Hong Chen Xiangxin Guo Xin-Xin Yang Fang-Fang Xu Jing-Tai Zhao | 2010 | Journal of Alloys and Compounds2010，500，： | 1 |
| 10 | CeO_2 thin films grown on biaxially textured nickel(001)显示文摘CeO\-2 films have been grown on biaxially textured Ni substrates at various temperatures. The results show that CeO\-2 films without IBAD are dominated by (111) orientation from room temperature to 800℃ while the preferential orientation of CeO\-2 films with IBAD is (001) at lower deposition temperature and (111) at deposition temperature higher than 450℃. CeO\-2 films with better in_plane texture and out_of_plane orientation can be grown at 360℃ with 240 eV ion energy and 200 μA/cm\+2 ion current density. | WANG Rongping, XIONG Xuming, Guo Xiangxin, ZHOU Yueliang, L Huibin, PAN Shaohua, CHEN Zhenghao and YANG Guozhen Laboratory of Optical Physics, Institute of Physics and Center for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100080, Ch | 1998 | Chinese Science Bulletin1998，43，20： | 1 |
| 11 | The Role of Charge Reactions in Cyclability of Lithium–Oxygen Batteries显示文摘 | Xiangxin Guo Ning Zhao | 2013 | Adv. Energy Mater2013，，： | 1 |
| 12 | In situ Observation of Li Deposition-Induced Cracking in Garnet Solid Electrolytes显示文摘Lithium(Li)penetration through solid electrolytes(SEs)induces short circuits in Li solid-state batteries(SSBs),which is a critical issue that hinders the development of high energy density SSBs.While cracking in ceramic SEs has been often shown to accompany Li penetration,the interplay between Li deposition and cracking remains elusive.Here,we constructed a mesoscale SSB inside a focused ion beam-scanning electron microscope(FIB-SEM)for in situ observation of Li deposition-induced cracking in SEs at nanometer resolution.Our results revealed that Li propagated predominantly along transgranular cracks in a garnet Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO).Cracks appeared to initiate from the interior of LLZTO beneath the electrode surface and then propagated by curving toward the LLZTO surface.The resulting bowl-shaped cracks resemble those from hydraulic fracture caused by high fluid pressure on the surface of internal cracks,suggesting that the Li deposition-induced pressure is the major driving force of crack initiation and propagation.The high pressure generated by Li deposition is further supported by in situ observation of the flow of filled Li between the crack flanks,causing crack widening and propagation.This work unveils the dynamic interplay between Li deposition and cracking in SEs and provides insight into the mitigation of Li dendrite penetration in SSBs. | Jun Zhao Yongfu Tang Qiushi Dai Congcong Du Yin Zhang Dingchuan Xue Tianwu Chen Jingzhao Chen Bo Wang Jingming Yao Ning Zhao Yanshuai Li Shuman Xia Xiangxin Guo Stephen J.Harris Liqiang Zhang Sulin Zhang Ting Zhu Jianyu Huang | 2022 | Energy & Environmental Materials2022，5，2： | 0 |
| 13 | Evaluation of solid electrolytes: Development of conventional and interdisciplinary approaches显示文摘Solid-state lithium batteries(SSLBs)have received considerable attention due to their advantages in thermal stability,energy density,and safety.Solid electrolyte(SE)is a key component in developing high-performance SSLBs.An in-depth understanding of the intrinsic bulk and interfacial properties is imperative to achieve SEs with competitive performance.This review first introduces the traditional electrochemical approaches to evaluating the fundamental parameters of SEs,including the ionic and electronic conductivities,activation barrier,electrochemical stability,and diffusion coefficient.After that,the characterization techniques to evaluate the structural and chemical stability of SEs are reviewed.Further,emerging interdisciplinary visualization techniques for SEs and interfaces are highlighted,including synchrotron X-ray tomography,ultrasonic scanning imaging,time-of-flight secondary-ion mass spectrometry,and three-dimensional stress mapping,which improve the understanding of electrochemical performance and failure mechanisms.In addition,the application of machine learning to accelerate the screening and development of novel SEs is introduced.This review article aims to provide an overview of advanced characterization from a broad physical chemistry view,inspiring innovative and interdisciplinary studies in solid-state batteries. | Muhammad Khurram Tufail Pengbo Zhai Waquar Khokar Mengyang Jia Ning Zhao Xiangxin Guo | 2023 | Interdisciplinary Materials2023，2，4： | 0 |
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