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| 1 | Bismuth oxychloride hollow microspheres with high visible light photocatalytic activity显示文摘二铋氯氧化物, BiOCl 和双性人 24 O 31 Cl 10, 成功地用碳的 microsphere 被综合牺牲的模板。从 BiOCl 的阶段进化到双性人 24 O 31 Cl 10 被在 600 点加热前者容易认识到?? | Pengzhen Cui Jiali Wang Zumin Wang Jun Chen Xianran Xing Lianzhou Wang Ranbo Yu | 2016 | Nano Research2016，9，3： | 4 |
| 2 | Zero-Thermal Expansion and Heat Capacity of Zirconium Pyrovanadate Doped with Zirconia and Vanadium (V) Oxide显示文摘The dominant phase ZrV2O7 material, doped with zirconia and vanadium (V) oxide, was synthesized by solid state reaction and sol-gel methods. X-ray power diffraction patterns show that it is cubic structure. Thermal mechanic analysis measurements exhibit a zero-thermal expansion of this material above 150℃. Meanwhile, the heat capacity dependent on temperature, determined by differential scanning calorimetry, keeps in constant almost in the same temperature range. The relationship between unusual thermal expansion and abnormal heat capacity is discussed with Gruneisen parameter. | Xianran Xing, Zhenqi Zhu, Xinping Qiu, Guirong Liu (Dept. of Physical Chemistry University of Science and Technology Beijing, Beijing 100083, China Dept. of Chemistry, Tsinghua University, Beijing 100084, China) | 2001 | Rare Metals2001，20，1： | 4 |
| 3 | A comprehensive understanding of the anionic redox chemistry in layered oxide cathodes for sodium-ion batteries显示文摘Sodium-ion batteries(SIBs) have demonstrated great application prospects in large-scale energy storage systems and low-speed electric vehicles due to the cost effectiveness and abundant resources. Layered transition-metal oxides are recognized as one of the most attractive sodium-ion storage cathode candidates by virtue of their high compositional diversity, environmental friendliness, ease of synthesis, and promising theoretical capacities. The practicability, however, is still limited by the fact that the energy densities of most Na-storage layered oxide cathodes solely using the conventional cationic redox are not comparable to those of the lithium-ion storage counterparts. Recently, the strategy of activating anionic redox(O^(2-)/O^(n-)) which is popular in Li-rich layered materials has been successfully applied in oxide cathodes of SIBs to promote the energy density to a new level. It is interesting to note that excess Na is not the prerequisite to induce anionic redox in sodium oxides, indicating a new mechanism underlying Na-ion materials. Herein, the latest advances on the anionic redox chemistry in layered oxide cathodes for SIBs,including the fundamental theories, triggering strategies, and applicable cathode materials, are comprehensively reviewed.Moreover, the challenges(mainly O_(2) release) facing anionic redox are discussed, and the possible remedies are outlined for future developments toward a highly reversible oxygen usage. We believe that this review can provide a valuable guidance for the exploration of high-energy layered oxide cathode materials of SIBs. | Junteng Jin Yongchang Liu Xuelu Pang Yao Wang Xianran Xing Jun Chen | 2021 | Science China Chemistry2021，64，3： | 3 |
| 4 | Novel thermal expansion of lead titanate显示文摘Lattice parameters of lead titanate were precisely re-determined in the ternperature range of-150-950℃ by high precision XRPD measurements. It was clarified that there was no any evidence for a new phase transition at low temperatures. Tetragonal distortion strain decreases with temperature increasing. A novel thermal expansion was observed, positive thermal expansion from-150℃ to room temperature (RT) and above 490℃, and the negative thermal expansion in the temperature range of RT-490℃. A big jump of thermal expansion coefficient is attributed to the tetragonal-cubic phase transition. A rationalization for the negative thermal expansion of PbTiO3 is due to the decrease of anion-anion repulsion as polyhedra become more regular at heating. The mechanisms of positive and negative thermal expansions were elucidated as the same nature in the homogenous tetragonal phase at present case. | XING Xianran, DENG Jinxia, CHEN Jun and LIU GuirongDepartment of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083, China | 2003 | Rare Metals2003，22，4： | 3 |
| 5 | Structure and Negative ThermalExpansion in the PbTi03-BiFe03 System 显示文摘 | Chen Jun Xing Xianran | 2006 | Applied Physics Let-ters2006，，10： | 1 |
| 6 | Structure andEnhancement of Negative Thermal Expansion in the PbTi03 -Cd-Ti03 System 显示文摘 | Chen Jun Xing Xianran Yu Ranbo | 2005 | Applied Physics Letters2005，，23： | 1 |
| 7 | Carbon interstitial defects causing emission red shift in YAG:Ce phosphor:First-principles calculation显示文摘Y_3 Al_5 O_(12):Ce3+ is the most famous phosphor material due to its excellent photolumincent properties.Here,through first-principles calculation,the effect of carbon interstitial defects on Y_3 Al_5 O_(12):Ce3+phosphor was investigated. It is found that the carbon interstitials tend to occupy the next-nearest sites of Ce^(3+) ion in Y_3 Al_5 O_(12):Ce3+ lattice. Specially,these interstitial defects can shorten the Ce3+-O^(2-) bond length, leading to a larger crystal field splitting of 5 d orbital of the Ce^(3+) atom and bigger 5 d centroid shift.These two factors cause the emission spectrum of Y_3 Al_5 O_(12)(C):Ce^(3+) red shift compared with that of Y_3 Al_5 O_(12):Ce3+. Moreover, with our comparison experiment, we find that the Y_3 Al_5 O_(12)(C):Ce3+ has an obvious red shift compared with that of Y_3 Al_5 O_(12):Ce^(3+) system,which is in accord with our first principles calculation. Our work systematically investigates the impact of the carbon interstitial defect on Y_3 Al_5 O_(12):Ce^(3+),and provides a new route to tune the emission spectrum in Y_3 Al_5 O_(12):Ce^(3+). | Yaling Zheng Weidong Zhuang Xianran Xing Ronghui Liu Yanfeng Li Yuanhong Liu Yunsheng Hu Xiaoxia Chen Lei Chen Xiaole Ma | 2018 | Journal of Rare Earths2018，36，12： | 1 |
| 8 | Structure and En-hancement of Negative Thermal Expansion in PbTi03 -CdTi03 Sys-tem 显示文摘 | Chen Jun Xing Xianran Yu Ranbo | 2005 | Applied Physics Letters2005，87，23： | 1 |
| 9 | Structure andNegative Thermal Expansion in the PbTi03 -BiFe03 System 显示文摘 | Chen Jun Xing Xianran Liu Guirong | 2006 | Applied Physics Letters2006，89，10： | 1 |
| 10 | Zero Thermal Expan-sion in PbTiOj - Based Perovskites 显示文摘 | Chen Jun Xing Xianran Sun Ce | 2008 | Journal of AmericanChemical Society2008，130，4： | 1 |
| 11 | Hydrothermal synthesis of single crystalline (K, Na) NbO3 powders显示文摘 | Sun Ce Xing Xianran Chen Jun | 2007 | Eur J Inorg Chem2007，13，： | 1 |
| 12 | Synthesis, Electrical and Magnetic Properties of Fe304 Doped by Dy^3+显示文摘 | Wang Jingping Hao Xianfeng Lü Minfeng Liu Jianfen Xing Xianran Meng Jian | 2006 | Journal of Rare Earths2006，24，4： | 1 |
| 13 | A low-cost and large-scale synthesis of nano-zinc oxide from smithsonite显示文摘 | Yucheng Zhang Jinxia Deng Jun Chen Ranbo Yu Xianran Xing | 2014 | Inorganic Chemistry Communications2014，，： | 1 |
| 14 | Leaching of zinc from calcined smithsonite using sodium hydroxide显示文摘 | Yucheng Zhang Jinxia Deng Jun Chen Ranbo Yu Xianran Xing | 2013 | Hydrometallurgy2013，，： | 1 |
| 15 | Synthesis and Characterization of (Zn, Co)TiO3 by Modified Low Temperature Preparing Route 显示文摘 | Luo Jun Xing Xianran Yu Ranbo | 2005 | Journal of Alloys and Compounds2005，402，： | 1 |
| 16 | Hydrother-mal synthesis of ZrWz08 nanorods显示文摘 | Xing Xianran Xing Qifeng Yu Ranbo | 2006 | Physical B2006，371，： | 1 |
| 17 | Semi-empirical estimation for enhancing negative thermal expansion in PbTiO_(3)-based perovskites显示文摘Generally,most materials expand when heated and contract when cooled,whereas negative thermal expansion(NTE)materials are very rare.As a typical NTE material,PbTiO_(3) and related compounds have drawn particular interest in recent years.The discovery of an enhanced NTE system in PbTiO_(3) is beneficial to deepen our understanding of its mechanism and regulate its properties.At present,the method of discriminating an enhanced NTE material based on PbTiO_(3) is not universal.Here,we propose a semi-empirical method through evaluating the average lattice distortion in related systems to estimate the relative coefficient of thermal expansion conveniently.The rationality of the method was verified by the analysis of the 0.6PbTiO_(3)-0.4Bi(Ga_(x)Fe_(1-x))O_(3) system.So far,all PbTiO_(3)-based compounds with enhanced NTE conform well to this method.This method provides the possibility to find more enhanced NTE PbTiO_(3)-based materials. | Tao Yang Longlong Fan Yilin Wang Kun Lin Jun Chen Xianran Xing | 2022 | International Journal of Minerals,Metallurgy and Materials2022，29，4： | 1 |
| 18 | A novel organically templated hybrid open-framework manganese phosphate-oxalate显示文摘 | Yu Ranbo Xing Xianran Takashi Saito | 2005 | Solid State Sciences2005，，7： | 1 |
| 19 | A Novel Organically Templated Hybrid Open-framework Manganese Phosphate-oxalate 显示文摘 | Yu Ranbo Xing Xianran Takashi Saito | 2005 | Solid State Sciences2005，，7： | 1 |
| 20 | Molten salt synthesis of lead lanthanum zirconate titanate ceramic powders显示文摘 | CAI ZONGYING XING XIANRAN LI LU | 2008 | Journal of Alloys and Compounds2008，454，12： | 1 |
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