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| 1 | Synthesis and properties of novel N,C,N terdentate skeleton based on 1,3-di(pyridin-2-yl)benzene moiety-new tricks for old dogs显示文摘Utilization of intermolecular Friedel-Crafts and intramolecular condensation reaction,novel 1,3-di-(pyridine-2-yl)benzene(N,C,N terdentate)skeleton with electro-withdrawing group in 6'position of pyridyl and a cyclization between 6'position of pyridyl and 6 position of benzyl ring were firstly designed and synthesized.The structures of these novel N,C,N terdentate were confirmed by NMR,MS and X-ray single crystalanalyses.The photophysical properties of these compounds were briefly explored. | Shuai Tan Xiugang Wu Yanqiong Zheng Yafei Wang | 2019 | Chinese Chemical Letters2019，30，11： | 1 |
| 2 | Reverse-Time Migration of Converted S-Waves of Varying Densities显示文摘Ocean-Bottom Node(OBN)acquisitions provide both non-converted and converted reflection energy.There is a clear advantage to independently imaging both P-and S-waves,as they provide more information collectively than either does alone.In many conventional converted-wave pre-stack migration algorithms,density is treated as a constant,which is not the real-life case on earth.S-wave velocity and density information is crucial for hydrocarbon detection because it helps in the identification of porefilling fluids.In this paper,we focused on the effect of density on imaging,and developed a method of reverse-time migration(RTM)on converted s-waves of varying densities(VD-RTMCS).Phase correction was required prior to pre-stack migration to avoid constructive interference between data from adjacent sources.Synthetic data examples showed that when density variations were included,image profiles showed advantages in signal-to-noise ratio,vertical resolution and imaging of complex structures. | TONG Siyou CHEN Ming ZHOU Huawei LI Linwei XU Xiugang WU Zhiqiang | 2019 | Journal of Ocean University of China2019，18，5： | 1 |
| 3 | High-efficiency saturated red emission from binuclear cyclo-metalated platinum complex containing 5-(4-octyloxyphenyl)-1,3,4-oxadiazole-2-thiol ancillary ligand in PLEDs显示文摘A novel red-emitting binuclear platinum complex (dfppy)2Pt2(C8OXT)2 was synthesized and characterized,in which dfppy represents 2-(4',6'-difluorophenyl)pyridinato unit and C8OXT is abbreviated for 5-(4-octyloxyphenyl)-1,3,4-oxadiazole-2-thiol as a bridging ancillary ligand.Its photophysical,electrochemical and electroluminescent characteristics were primarily studied.The made single-emissive-layer (SEL) polymer light-emitting devices using (dfppy)2Pt2(C8OXT)2 as emitter exhibited a saturated red emission peaked at 620nm.The best device performances were obtained in the device at 8wt% dopant concentration,with a maximum external quantum efficiency of 8.4%,a current efficiency of 4.2cd/A and brightness of 3228cd/m2.This work provides an effective approach to obtain high-efficiency red emission through construction of new binuclear platinum complex and its doped SEL devices. | YU JunTing WU XiuGang TAN Hua LIU Yu WANG YaFei ZHU MeiXiang ZHU WeiGuo | 2013 | Science China Chemistry2013，56，8： | 1 |
| 4 | Fine-grained rock fabric facies classification and its control on shale oil accumulation: a case study from the Paleogene Kong 2 Member, Bohai Bay Basin显示文摘Lacustrine shale oil resources in China are abundant,with remarkable exploration breakthroughs being achieved.Compared to marine shale oil in North America,efficient exploration of lacustrine shale oil is more difficult;thus,selecting favorable layer and optimization zone for horizontal wells is more important.In this study,based on systematic coring of approximately 500 m fine-grained deposits of the Kong 2 Member,combining laboratory tests and log data,source rock geochemistry and reservoir physical properties,the favorable rock fabric facies for oil accumulation was analyzed and classified.First,the dominant lithologic facies,organic facies,and bed combination facies were determined based on mineral composition from logging,total organic content(TOC),and sedimentary structure.Secondly,10 fabric facies were classified by combining these three facies,with 4 fabric facies were found to have high TOC content,high total hydrocarbon,and strong fluorescence features,indicating good shale oil enrichment.Thirdly,the distribution of the upon good fabric facies was identified to be located at the top of the Kong 2 Member,with evidences of seismic resistivity inversion,thermal maturity,structure depth,and strata thickness.And the favorable facies were found to be stably distributed lateral at the area of about 100 km2.High oil flow has been detected at this layer within this area by several wells,including horizontal wells.The exploratory study of fabric facies classification and evaluation provides a new research idea for lacustrine shale oil exploration and effectively promotes breakthroughs in lacustrine shale oil exploration in Bohai Bay Basin. | Wenzhong HAN Xianzheng ZHAO Xiugang PU Shiyue CHEN Hu WANG Yan LIU Zhannan SHI Wei ZHANG Jiapeng WU | 2021 | Frontiers of Earth Science2021，15，2： | 0 |
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