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| 1 | Aggregation-enhanced emission and efficient electroluminescence of conjugated polymers containing tetraphenylethene units显示文摘Tetraphenylethene (TPE) is a popular luminogen characterized by aggregation-induced emission and has been widely used to construct solid-state emissive materials. In this work, two thermally stable polymers (P1 and P2) consisting of TPE conjugated to the 2,7-positions of fluorene and carbazole, respectively, are synthesized and characterized. Both polymers are weakly fluorescent in solutions but show greatly enhanced emission as the aggregate formation, presenting an aggregation-enhanced emission feature. Two kinds of polymer light-emitting diodes are fabricated utilizing P1 and P2 as emitters (EML) (device I: ITO/PEDOT:PSS (45 nm)/PVK:EML (1:1 wt%, 55 nm)/TPBI (38 nm)/Ca:Ag; device II: ITO/PEDOT:PSS (45 nm)/ PVK:OXD-7:EML (3:1:3 wt%, 55 nm)/TPBI (38 nm)/Ca:Ag). The device II of P2 shows the best performances, affording a maximum luminance of 6500 cd/m 2 and a high peak efficiency of 2.11 cd/A. | HE BaiRong YE ShangHui GUO YanJu CHEN Bin XU XiaoFei QIU HuaYu ZHAO ZuJin | 2013 | Science China Chemistry2013，56，9： | 2 |
| 2 | Blue AIEgens bearing triphenylethylene peripheral:adjustable intramolecular conjugation and good device performance显示文摘The new approaches to construct deep blue aggregation-induced emission(AIE) materials have been explored, which control the conjugation by two different strategies, to make a great step for the commercialization of organic light-emitting diodes. In order to shorten the intramolecular conjugation length, triphenylethylene(t PE)was utilized to construct blue AIEgens as peripheral groups,instead of tetraphenylethylene(TPE), the famous AIE star molecule, to yield three blue AIEgens of 3,4-Bt PE-PI, 4,4-Bt PE-PI and 4,4-Bt PE-PPI. Nondoped electroluminescence devices are fabricated by using these three AIEgens as the emitting material layer, the best performance of 3.8 cd/A as the maximum current efficiency achieved at the commission internationale de l'Eclairage coordinates of(0.17, 0.18). | Can Wang Le Li Xuejun Zhan Zhijun Ruan Yujun Xie Quanyuan Hu Shanghui Ye Qianqian Li Zhen Li | 2016 | Science Bulletin2016，61，22： | 2 |
| 3 | Aguide- weight criterion method for the optimal design of antenna structures 显示文摘 | CHEN Shuxun YE Shanghui | 1986 | Engineering Optimization1986，，103： | 1 |
| 4 | A guide-weight criterion method for the optimal design of antenna structures显示文摘 | Chen Shuxun Ye Shanghui | 1986 | Engineering Optimization1986，10，3： | 1 |
| 5 | A guide-weight erlterlon method for the optimal desigu of antenna structures 显示文摘 | CHEN Shuxun YE Shanghui | 1986 | Engineering Optimization1986，10，3： | 1 |
| 6 | Aguide- weight criterion method for the optimal design of antenna structures 显示文摘 | CHEN Shuxun YE Shanghui | 1986 | Engineering Op- timization1986，，103： | 1 |
| 7 | A Mixed Method for Shape Optimization of Skeletal Structures显示文摘 | Duan Baoyan Ye Shanghui | 1986 | Engineering Optimization1986，10，3： | 1 |
| 8 | A Mixed Method for Shape Optimization of Skeletal Structures 显示文摘 | Duan Baoyan Ye Shanghui | 1986 | Engineering Optimization1986，10，3： | 1 |
| 9 | A mixed method for shape optimization of skeletal structures显示文摘 | Duan Baoyan Ye Shanghui | | 0，，03： | 1 |
| 10 | A GUIDE-WEIGHT CRITERION METHOD FOR THE OPTIMAL DESIGN OF ANTENNA STRUCTURES显示文摘 | Chen Shuxun Ye Shanghui | 1986 | Engineering Optimization1986，，3： | 1 |
| 11 | A guide-weight criterion method for the optimal design of antenna structures显示文摘 | CHEN Shuxun YE Shanghui | 1986 | Engineering Optimi-zation1986，10，3： | 1 |
| 12 | Effects of Different Eelectron-withdrawing Moieties on the General Photoelectric Properties of Fluorene-based Dimers显示文摘Here,9,9.9'-tris(4-butoxyphenyl)-9H-9'Hl-2,2'-difluorene(DF)was synthesized as a reference for compa rison,and diphenyl sulfone and triphenylphosphine oxygen were introduced to the 9-position of fluorene througha C-H coupling reaction to produce two fluorene-based oligomers 9′,9′″-sulfonylbis(4.1-phenylene)bis9,9′,9′tris(4-butoxyphenyl)-9H,9'H-2.2'-bifluorene(DF)SOz and phenylbis(4-{9.9,9-tris(4-butoxyphenyl)-9H,9'H-12.2-bif-luorenel-9-yl} phenyl)phosphine oxidel(DF)2POI.Solid powders of all the three compounds exhibit excellent therma stability with thermal temperature at 5%mass loss of 375,429 and 383 C for(DF)2SO2,(DF)PO and DF.In addition,owing to the distorted molecular structure and weak electron-absorbing ability of the acceptor,(DF)Soz and(DF)2PO do not have obvious intramolecular charge transfer characteristics.and exhibit stable localized 394 nm/375 nm fluorescence emission peaks in different polar solvents.The absolute luminescence quantumefficiencies of(DF)2S02,(DF)PO and DF solid powders are 20.83%,10.03%and 59.46%,Compound DF has the highest quantum yield as an electron donor.The chromaticity coordinates of the blue OLED devices based on DF and DF2SO2 fabricated by solution spin coating were(0.19.0.10)and(0.19.0.11).which were closest to the deep blue region,and the corresponding maximum external quantum efficiencies are 1.45%and 0.87%,respectively,which are higher than that of(DF)2PO(0.25%)and consistent with the difference in the solid-state quantum efficiency between them. | YUAN Xinlei LI Jie LU Zhiwei YE Shanghui JIANG Hongji | 2020 | Chemical Research in Chinese Universities2020，36，6： | 0 |
| 13 | Effect of metal centres and substituents on the structure and optoelectronic properties of diarylethene compounds:A theoretical study显示文摘Diarylethene derivatives are a class of fascinating photochromic materials because of their open and closed isomers with different absorption spectra and many other characteristics.To reveal the detailed structure and optoelectronic properties as well as the effect of metal centres and substituents on them,a systematic study on a series of diarylethene derivatives and their Re(I),Pt(II),and Ir(III) complexes was performed via theoretical calculation.The optimized geometries,electronic properties,frontier molecular orbitals,ionization potentials,electron affinities,reorganization energies,and absorption spectra for both of their open-and closed-isomers have been calculated and analyzed.Metal-coordination and substituents exhibit great influence on the photophysical,charge-injection and-transporting characteristics.In addition,the binding of F-with the boron atom of dimesitylboryl group through Lewis acid/base interactions also induces great changes of structural,photophysical and electronic properties for these diarylethene derivatives,and consequently the compound with the substituent of dimesitylboryl group can be used as selective near-infrared phosphorescent F-probe. | LIU ShuJuan YANG ChengJiang XU WenJuan HUANG YanQin YE ShangHui ZHAO Qiang LIU XiangMei HUANG Wei | 2013 | Science China Chemistry2013，56，1： | 0 |
| 14 | Aggregation-enhanced emission and efficient electroluminescence of conjugated polymers containing tetraphenylethene units显示文摘Tetraphenylethene(TPE)is a popular luminogen characterized by aggregation-induced emission and has been widely used to construct solid-state emissive materials.In this work,two thermally stable polymers(P1 and P2)consisting of TPE conjugated to the 2,7-positions of fluorene and carbazole,respectively,are synthesized and characterized.Both polymers are weakly fluorescent in solutions but show greatly enhanced emission as the aggregate formation,presenting an aggregation-enhanced emission feature.Two kinds of polymer light-emitting diodes are fabricated utilizing P1 and P2 as emitters(EML)(device I:ITO/PEDOT:PSS(45 nm)/PVK:EML(1:1 wt%,55nm)/TPBI(38 nm)/Ca:Ag;device II:ITO/PEDOT:PSS(45 nm)/PVK:OXD-7:EML(3:1:3 wt%,55 nm)/TPBI(38nm)/Ca:Ag).The device II of P2 shows the best performances,affording a maximum luminance of 6500 cd/m2and a high peak efficiency of 2.11 cd/A. | HE BaiRong YE ShangHui GUO YanJu CHEN Bin XU XiaoFei QIU HuaYu ZHAO ZuJin | 2013 | 中国科学:化学2013，43，9： | 0 |
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