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| 1 | Corrigendum to “Properties improvement of SPEEK based proton exchange membranes by doping of ionic liquids and Y_2O_3”[Prog. Nat. Sci.: Mater. Int. 22 (1) (2012) 26-30] | Jianbin Chen a, Qiang Guo a, Dan Li a, Juying Tong a,b, Xia Li a a School of Materials Science and Engineering, Shanghai University, Shanghai 201800, China b School of Wenling, Zhejiang TV University, Wenling 317500, China | 2012 | Progress in Natural Science:Materials International2012，22，3： | 33 |
| 2 | Nitrogen doped porous carbon as excellent dual anodes for Li-and Na-ion batteries显示文摘Biomass-derived carbon materials have obtained great attention due to their sustainability,easy availability,low cost and environmentally benign.In this work,bamboo leaves derived nitrogen doped hierarchically porous carbon have been efficiently synthesized via an annealing approach,followed by an etching process in HF solution.Electrochemical measurements demonstrate that the unique porous structure,together with the inherent high nitrogen content,endow the as-derived carbon with excellent lithium/sodium storage performance.The porous carbon annealed at 700℃presents outstanding rate capability and remarkable long-term stability as anodes for both lithium-ion batteries and sodium-ion batteries.The optimized carbon delivers a high discharge capacity of 450 mAh/g after 500 cycles at the current density of 0.2 A/g for LIBs,and a discharge capacity of 180 mAh/g after 300 cycles at the current density of 0.1 A/g for SIBs. | Zhanheng Yan Qin-Wen Yang Qinghong Wang Jianmin Ma | 2020 | Chinese Chemical Letters2020，31，2： | 20 |
| 3 | A review of nanocarbons in energy electrocatalysis: Multifunctional substrates and highly active sites显示文摘Nanocarbons are of progressively increasing importance in energy electrocatalysis, including oxygen reduction, oxygen evolution, hydrogen evolution, CO_2 reduction, etc. Precious-metal-free or metal-free nanocarbon-based electrocatalysts have been revealed to potentially have effective activity and remarkable durability, which is promising to replace precious metals in some important energy technologies,such as fuel cells, metal–air batteries, and water splitting. In this review, rather than overviewing recent progress completely, we aim to give an in-depth digestion of present achievements, focusing on the different roles of nanocarbons and material design principles. The multifunctionalities of nanocarbon substrates(accelerating the electron and mass transport, regulating the incorporation of active components,manipulating electron structures, generating confinement effects, assembly into 3 D free-standing electrodes) and the intrinsic activity of nanocarbon catalysts(multi-heteroatom doping, hierarchical structure,topological defects) are discussed systematically, with perspectives on the further research in this rising research field. This review is inspiring for more insights and methodical research in mechanism understanding, material design, and device optimization, leading to a targeted and high-efficiency development of energy electrocatalysis. | Cheng Tang Maria-Magdalena Titirici Qiang Zhang | 2017 | Journal of Energy Chemistry2017，26，6： | 13 |
| 4 | Cotton-derived oxygen/sulfur co-doped hard carbon as advanced anode material for potassium-ion batteries显示文摘Hard carbon is regarded as promising anode materials for potassium-ion batteries(KIBs)owing to their low price and easy availability.However,the limited rate capability still needs to be improved.Herein,we demonstrate the fabrication of oxygen/sulfur co-doped hard carbon through a facile hydrolyzationsulfuration process of skimmed cotton.The simultaneous dopants significantly improve potassium ion diffusion rate.When served as the anode for KIBs,this hydrolyzed hard carbon delivered a high reversible capacity(409 mAh/g at 0.1 A/g),superior rate capability(135 mAh/g at 2 A/g)and excellent cyclability(about 120 mAh/g overt 500 cycles at 2 A/g).This work provides a facile strategy to prepare low-cost doped-hard carbon with superior potassium storage property. | Baolin Xu Shihan Qi Fang Li Xiaoxin Peng Jinfeng Cai Jiaojiao Liang Jianmin Ma | 2020 | Chinese Chemical Letters2020，31，1： | 12 |
| 5 | Influence of DCM dye doping on the magnetic field dependent electroluminescence in organic light emitting diodes显示文摘The DCM dye doped organic electroluminescence devices with structure of ITO/NPB/Alq 3 : DCM/Alq 3 /LiF/Al were fabricated. From 15 K to room temperature, the magnetic field dependent of electroluminescence (MEL) of devices was investigated. Our observations indicated that the MEL is composed of two effects in different regimes: a low field (0≤B≤40 mT) effect and a high field (B > 40 mT) effect. For undoped devices, the low field effect exhibits a rapid rising with the increasing field, and the high field effect shows a slow increase and gradually saturates at room temperature. For doped devices, the low field rapid increase is also present, whereas the high field effect displays a decrease with the increasing field. The larger the injection current is, the more apparent the high field decrease is. In addition, the doped device demonstrates less temperature dependence of the high field effect than undoped device, although the undoped devices also present high field decrease of electroluminescence at low temperatures (T≤150 K). Based on the energy level trapping effect due to dye doping and magnetic field modulated triplet exciton annihilation, the experimental results are carefully explained. | CHEN Ping, LEI YanLian, LIU Rong, ZHANG QiaoMing, ZHANG Yong & XIONG ZuHong School of Physical Science and Technology, MOE Key Laboratory on Luminescence and Real-Time Analysis, Southwest University, Chongqing 400715, China | 2010 | Science China(Physics,Mechanics & Astronomy)2010，53，1： | 10 |
| 6 | Porous nitrogen-doped carbon/MnO coaxial nanotubes as an efficient sulfur host for lithium sulfur batteries显示文摘As a promising candidate for next generation energy storage devices, lithium sulfur (Li-S) batteries still confrant rapid capacity degradation and low rate capability. Herein, we report a well-architected porous nitrogen-doped carbon/MnO coaxial nanotubes (MnO@PNC) as an efficient sulfur host material. The host shows excellent electron conductivity, sufficient ion transport channels and strong adsorption capability for the polysulfides, resulting from the abundant nitrogen-doped sites and pores as well as MnO in the carbon shell of MnO@PNC. The MnO@PNC-S composite electrode with a sulfur content of 75 wt.% deliveries a specific capacity of 802 mAh·g^-1 at a high rate of 5.0C and outstanding cycling stability with a capacity retention of 82% after 520 cycles at 1.0C. | Chao Lin Longbing Qu Jiantao Li Zhengyang Cai Haoyun Liu Pan He Xu Xu Liqiang Mai | 2019 | Nano Research2019，12，1： | 10 |
| 7 | Defect and Doping Co‑Engineered Non‑Metal Nanocarbon ORR Electrocatalyst显示文摘Exploring low-cost and earth-abundant oxygen reduction reaction(ORR)electrocatalyst is essential for fuel cells and metal–air batteries.Among them,non-metal nanocarbon with multiple advantages of low cost,abundance,high conductivity,good durability,and competitive activity has attracted intense interest in recent years.The enhanced ORR activities of the nanocarbons are normally thought to originate from heteroatom(e.g.,N,B,P,or S)doping or various induced defects.However,in practice,carbon-based materials usually contain both dopants and defects.In this regard,in terms of the co-engineering of heteroatom doping and defect inducing,we present an overview of recent advances in developing non-metal carbon-based electrocatalysts for the ORR.The characteristics,ORR performance,and the related mechanism of these functionalized nanocarbons by heteroatom doping,defect inducing,and in particular their synergistic promotion effect are emphatically analyzed and discussed.Finally,the current issues and perspectives in developing carbon-based electrocatalysts from both of heteroatom doping and defect engineering are proposed.This review will be beneficial for the rational design and manufacturing of highly efficient carbon-based materials for electrocatalysis. | Jian Zhang Jingjing Zhang Feng He Yijun Chen Jiawei Zhu Deli Wang Shichun Mu Hui Ying Yang | 2021 | Nano-Micro Letters2021，13，4： | 8 |
| 8 | Fluorescence properties and application of doping complexes Eu_(l-x)L_x(TTA)_3Phen as light conversion agents显示文摘Light conversion agents Eul-xLx(TTA)3Phen (L denotes (La3+, Gd3+, Y3+)) complexes were prepared, and the influence of doping ions on fluorescence properties was investigated by elementary analysis, FTIR and fluorescent spectra. The results show that FTIR spectra of Eul-xLx(TTA)3Phen complex system are identical with that of EuTTA3Phen, which indicates that the complexes (Eul-xLx(TTA)3Phen) are similar in structure to (Eu (TTA)3Phen.) For the above doping elements, co-fluorescence enhancement has the following order: Gd3+>Y3+>La3+, and the optimum mole fractions of doping elements are 0.4, 0.2 and 0.5 respectively for Gd3+, Y3+, La3+. Among all the complexes, Eu0.6Gd0.4(TTA)3Phen complex has the strongest fluorescent intensity. Applying Eu0.6Gd0.4(TTA)3Phen complex to plastic and printing inks, bright red fluorescence plastic and printing inks are obtained when the content of europium reaches 0.1%(mass fraction). | 王正祥 舒万艮 周忠诚 刘又年 陈洪 | 2003 | Journal of Central South University of Technology2003，10，4： | 7 |
| 9 | Catalytic performance of Zr-doped CuO-CeO2 oxides for CO selective oxidation in H2-rich stream显示文摘Zr-doped CuO-CeO2 catalysts for CO selective oxidation were designed and prepared by the hydrothermal method and coprecipitation. The experimental samples were characterized by means of N2 adsorption-desorption isotherms, powder X-ray diffraction, temperature-programmed reduction and Xray photoelectron spectroscopy. It is observed that the catalyst prepared by hydrothermal method exhibits larger specific surface area, smaller crystalline size and higher dispersion of active components compared with those of the catalyst obtained by coprecipitation. Meanwhile, redox properties of copper oxide are improved significantly and highly dispersed copper species providing CO oxidation sites are present on the surface. Furthermore, adsorptive centers of CO and active oxygen species increase on the copper-ceria interfaces. The Zr-doped CuO-CeO2 catalyst prepared by hydrothermal method possesses superior catalytic activity and selectivity for selective oxidation of CO at low temperature compared with those of the sample prepared by coprecipitation. The temperature corresponding to 50% CO conversion is only 73 ℃ and the temperature span of total CO conversion is expanded from 120 to 160 ℃. | Limin Shi Chuanlei Gao Fenghai Guo Yujing Wang Tiebang Zhang | 2019 | Journal of Rare Earths2019，37，7： | 7 |
| 10 | Tunable Schottky barrier width and enormously enhanced photoresponsivity in Sb doped SnS2 monolayer显示文摘Doping, which is the intentional introducti on of impurities into a material, can improve the metal-semiconductor interface by reducing Schottky barrier width. Here, we prese nt high-quality two-dime nsional SnS2 nano sheets with well-controlled Sb dopi ng concen tration via direct vapor growth approach and following micromechanical cleavage process. X-ray photoelectro n spectroscopy (XPS) measureme nt dem on strates that Sb contents of the doped samples are approximately 0.22%, 0.34% and 1.21%, respectively, and doping in duces the upward shift of the Fermi level with respect to the pristi ne SnS2. Tran smissio n electro n microscopy (TEM) characterizatio n exhibits that Sb-doped SnS2 nano sheets have a high-quality hexagonal symmetry structure and Sb element is uniformly distributed in the nano sheets. The phototra nsistors based on the Sb-doped SnS2 mono layers show n-type behavior with high mobility which is one order of magn itude higher than that of pristi ne SnS2 phototra nsistors. The photorespo nsivity and exter nal quantum efficiency (EQE) of Sb-S nS2 mono layers phototra nsistors are approximately three orders of magnitude higher than that of pristine SnS2 phototransistor. The results suggest that the method of reducing Shottky barrier width to achieve high mobility and photoresp on sivity is effective, and Sb-doped SnS2 mono layer has significant potential in future nanoelectronic and optoelectronic applications. | Junchi Liu Xiao Liu Zhuojun Chen Lili Miao Xingqiang Liu Bo Li Liming Tang Keqiu Chen Yuan Liu Jingbo Li Zhongming Wei Xidong Duan | 2019 | Nano Research2019，12，2： | 7 |
| 11 | Ce and Er Co-doped TiO2 for rapid bacteria- killing using visible light显示文摘Bacterial infection and related diseases are threatening the health of human beings.Photocatalytic disinfection as a simple and low-cost disinfection strategy is attracting more and more attention.In this work,TiO2 nanoparticles(NPs)were modified by co-doping of Ce and Er using the sol-gel method,which endowed TiO2 NPs with enhanced visible light photocatalytic performance but not pure ultraviolet photocatalytic properties compared the untreated TiO2.Our results disclosed that as the doping content of Er increased,the photocatalytic activity of modified TiO2 NPs initially increased and subsequently decreased.The same trend occurred for Ce doping.When the doping dose of Er and Ce is 0.5 mol%and 0.2 mol%,the 0.5Ce0.2Ti-O calcined at 800℃ presented the best antibacterial properties,with the antibacterial efficiency of 91.23%and 92.8%for Staphylococcus aureus and Escherichia coli,respectively.The existence of Er ions is thought to successfully turn the near-infrared radiation into visible region,which is easier to be absorbed by TiO2 NPs.Meanwhile,the addition of Ce ions can effectively extend spectral response range and inhibit the recombination of electrons and holes,enhancing the photocatalytic disinfection activity of co-doped TiO2. | Yawei Ren Yajing Han Zhaoyang Li Xiangmei Liu Shengli Zhu Yanqin Liang Kelvin Wai Kwok Yeung Shuilin Wu | 2020 | Bioactive Materials2020，5，2： | 7 |
| 12 | The point defect and electronic structure of K doped LaCo_(0.9)Fe_(0.1)O_(3)perovskite with enhanced microwave absorbing ability显示文摘ABO_(3)perovskites,owning unique properties,have great research prospect in electromagnetic wave absorption field.Normally,doping can significantly regulate the dielectric loss,whereas the magnetic loss can be ignored.In this work,the crystal structure and electromagnetic properties can be regulated systematically by the K,Fe co-doping for LaCoO_(3)perovskites(LKCFO)under the condition of fixed F content.In addition,the obtained samples show the obvious interfacial polarization effect on accounting to the small size effect,which is conducive to the effective microwave absorption.By analyzing the evolution of the positron annihilation lifetime and the first-principles calculation of the oxygen density of states for the series of LKCFO perovskites,it is found that the charge transport characteristics will be controlled by the point defect generated by allelic doping.The point defect content decreases and then increases as the doping level rises.The prepared perovskite exhibits the lowest defect density and the largest dielectric loss capability,which indicates that the lower point defects promote electron migration and thus enhance the dielectric loss;thus,the electromagnetic wave absorption bandwidth up to 6.2 GHz is reached.In contrast,both insufficient and excessive K doping are detrimental to the enhancement of microwave absorption.Especially,the practical application value was investigated using Computer Simulation Technology(CST)simulations.The LKCFO-2 exhibits the smallest RCS value(below-10 dBm^(2))at almost-90°-90°with a thickness of 2 mm,providing an effective method for study excellent microwave absorption and scattering property. | Fan Wang Weihua Gu Jiabin Chen Yue Wu Ming Zhou Shaolong Tang Xingzhong Cao Peng Zhang Guangbin Ji | 2022 | Nano Research2022，15，4： | 7 |
| 13 | Progress on rare-earth doped ZnO-based varistor materials显示文摘Rare-earth(RE)doping can greatly enhance the voltage gradient of ZnO-based varistors,and their nonlinear coefficient,leakage current,energy absorption capability,through-current capability and residual voltage can also be improved to certain extent.In this review,the progress on RE-doped ZnO-based varistor materials in recent years was summarized.The mechanism of RE doping on the electrical performance of ZnO varistors was analyzed.The issues in exploring new ZnO-based varistor materials by RE doping were indicated,and the development trends in this area were proposed. | Feng JIANG Zhijian PENG Yanxu ZANG Xiuli FU | 2013 | Journal of Advanced Ceramics2013，2，3： | 6 |
| 14 | Nitrogen and Phosphorus Dual-Doped Multilayer Graphene as Universal Anode for Full Carbon-Based Lithium and Potassium Ion Capacitors显示文摘Lithium/potassium ion capacitors(LICs/PICs) have been proposed to bridge the performance gap between high-energy batteries and high-power capacitors.However,their development is hindered by the choice,electrochemical performance,and preparation technique of the battery-type anode materials.Herein,a nitrogen and phosphorus dual-doped multilayer graphene(NPG) material is designed and synthesized through an arc discharge process,using low-cost graphite and solid nitrogen and phosphorus sources.When employed as the anode material,NPG exhibits high capacity,remarkable rate capability,and stable cycling performance in both lithium and potassium ion batteries.This excellent electrochemical performance is ascribed to the synergistic effect of nitrogen and phosphorus doping,which enhances the electrochemical conductivity,provides a higher number of ion storage sites,and leads to increased interlayer spacing.Full carbon-based NPG‖LiPF6‖active carbon(AC) LICs and NPG‖KPF6‖AC PICs are assembled and show excellent electrochemical performance,with competitive energy and power densities.This work provides a route for the large-scale production of dual-doped graphene as a universal anode material for high-performance alkali ion batteries and capacitors. | Yuting Luan Rong Hu Yongzheng Fang Kai Zhu Kui Cheng Jun Yan Ke Ye Guiling Wang Dianxue Cao | 2019 | Nano-Micro Letters2019，11，2： | 6 |
| 15 | Photocatalytic degradation of Rhodamine B under visible light with Nd-doped titanium dioxide films显示文摘Microporous titanium dioxide films were prepared by the sol-gel methods on glass substrates, using tetrabutyl titanate as source material. In order to absorb the visible light and increase the photocatalytic activities, different concentrations of neodymium ions (Nd/Ti molar ratio was 0.5%, 0.7%, 0.9%, and 1.1% respectively) were added into the sol. X-ray diffraction (XRD), X-ray photoelectron spectros-copy (XPS), and atom force microscopy (AFM) were applied to characterize the modified films. A kind of typical textile industry pollutant (Rhodamine B) was used to evaluate the photocatalytic activities of the films under visible light. The results showed that the activities of the films were improved by doping Nd ions into the sol. | WU Xiaohong SU Peibo LIU Huiling QI Lili | 2009 | Journal of Rare Earths2009，27，5： | 6 |
| 16 | Recent Progress on Carbonaceous Material Engineering for Electrochemical Hydrogen Peroxide Generation显示文摘Electrochemical synthesis of hydrogen peroxide(H2 O2)provides a clean and safe technology for large-scale H2 O2 production.The core of this project is the development of highly active and highly selective catalysts.Recent studies demonstrate that carbonaceous materials are favorable catalysts because of their low-cost and tunable surface structures.This brief review first summarizes the strategies of carbonaceous material engineering for selective two-electron O2 reduction reaction and discusses potential mechanisms.In addition,several device designs using carbonaceous materials as catalysts for H2 O2 production are introduced.Finally,research directions are proposed for practical application and performance improvement. | Baoshan Zhang Wenwen Xu Zhiyi Lu Jie Sun | 2020 | Transactions of Tianjin University2020，26，3： | 6 |
| 17 | Eu^(3+)-doped LaPO_4 and LaAlO_3 nanosystems and their luminescence properties显示文摘Eu3+ ion-doped LaPO4 nanowires or nanorods have been successfully synthesized by a simple hydrothermal method.The influence of varying the hydrothermal and subsequent sintering conditions on the morphology and structure of the LaPO4 host has been investigated by scanning electron microscopy(SEM) and X-ray diffraction(XRD).For comparison,the Eu3+ ions were also doped into monoclinic monazite LaPO4 nanoparticles and perovskite LaAlO3 nanoparticles.The relative intensities of the emission lines of the LaPO4:Eu3+ nanosystems were essentially independent of their shape.The optimal doping concentrations in the monoclinic LaPO4 and perovskite LaAlO3 nanosystems were determined to be about 5.0 and 3.5 mol%,respectively.Under appropriate UV-radiation,the red light emitted from LaAlO3:Eu3+(3.5 mol%) was brighter than that from LaPO4:Eu3+(5.0 mol%) nanomaterial,resulting from differences in their spin-orbit couplings and covalence,which indicates that the nanoscale LaAlO3 is a promising host material for rare earth ions. | WAN Qiang,HE YuPing,DAI Ning & ZOU BingSuo State Key Laboratory of State Key Laboratory of Chemo/Biosensing and Chemometrics and Key Laboratory for Micro-Nano Opto-Electronic Devices of Ministry of Education,Hunan University,Changsha 410082,China | 2009 | Science China Chemistry2009，52，8： | 6 |
| 18 | Preparation and thermal stability of zirconia-doped mullite fibers via sol-gel method | Wei WANG Duan WENG Xiao-dong WU | 2011 | Progress in Natural Science:Materials International2011，21，2： | 6 |
| 19 | Secondary-Atom-Doping Enables Robust Fe-N-C Single-Atom Catalysts with Enhanced Oxygen Reduction Reaction显示文摘Single-atom catalysts(SACs) with nitrogen-coordinated nonprecious metal sites have exhibited inimitable advantages in electrocatalysis.However,a large room for improving their activity and durability remains.Herein,we construct atomically dispersed Fe sites in N-doped carbon supports by secondary-atom-doped strategy.Upon the secondary doping,the density and coordination environment of active sites can be efficiently tuned,enabling the simultaneous improvement in the number and reactivity of the active site.Besides,structure optimizations in terms of the enlarged surface area and improved hydrophilicity can be achieved simultaneously.Due to the beneficial microstructure and abundant highly active FeN_5 moieties resulting from the secondary doping,the resultant catalyst exhibits an admirable half-wave potential of 0.81 V versus 0.83 V for Pt/C and much better stability than Pt/C in acidic media.This work would offer a general strategy for the design and preparation of highly active SACs for electrochemical energy devices. | Xin Luo Xiaoqian Wei Hengjia Wang Wenling Gu Takuma Kaneko Yusuke Yoshida Xiao Zhao Chengzhou Zhu | 2020 | Nano-Micro Letters2020，12，11： | 5 |
| 20 | Hydrothermal synthesis and luminescent properties of BaMoO_4:Sm^(3+) red phosphor显示文摘Trivalent samarium doped barium molybdate(BaMoO_4:Sm^(3+)) red phosphor was successfully synthesized by hydrothermal method. The crystal structure, morphology and photoluminescent property were characterized by X-ray diffraction, field environmental scanning electron microscopy and photoluminescence spectroscopy. The results indicated that the synthesized BaMoO_4:Sm^(3+)phosphor consisted of a pure phase with an octahedral structure. The main excitation peaks were located at 362, 404, 445 and 477 nm, respectively, and were obviously observed. The main emission peaks were located at 533, 566, 602 and 646 nm, respectively. The phosphors exhibited a red performance at 646 nm, which was appropriate for the ultraviolet-light emitting diode(UV-LED) and blue LED. The luminescent intensity of BaMoO_4:Sm^(3+) increased with an increase in the doping amount of Sm^(3+). The luminescent intensity had the optimal value for x=0.03. When the doping amount of Sm^(3+) was further increased, the concentration quenching phenomenon was observed. Monovalent lithium(Li+) cation was used as a charge compensator. The luminescence intensity first increased with increasing Li+ doping concentration, and then decreased. The optimal content of Li+ was about 2%. The BaMoO_4:Sm^(3+) phosphor prepared in this study could act as superior red phosphor for white LEDs. | 李兆 王永锋 曹静 江元汝 赵西成 孟志新 | 2016 | Journal of Rare Earths2016，34，2： | 5 |
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