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| 1 | Recent advances in kaolinite-based material for photocatalysts显示文摘The composite catalytic materials based on the mineral kaolinite are considered to be a potential approach for solving global energy scarcity and environmental pollution,which have excellent catalytic performance,low cost and excellent chemical stability.However,pure kaolinite does not have visible light absorption ability and cannot be used as a potential photocatalytic material.Fortunately,the unique physical and chemical properties of kaolinite can be acted as a good semiconductor carrier.Herein,this paper firstly presents the mineralogical characteristics of kaolinite.Next,kaolinite-based photocatalysts(such as TiO_(2)/kaolinite,g-C_(3)N_(4)/kaolinite,g-C_(3)N_(4)/TiO_(2)/kaolinite,Zn O)are discussed in detail from the formation of heterostructures,synthesis-modification methods,photocatalytic mechanisms,and electron transfer pathways.Furthermore,the specific role of kaolinite in photocatalytic materials is summarized and discussed.In addition,the photocatalytic applications of kaolinite-based photocatalysts in the fields of water decomposition,pollutant degradation,bacterial disinfection are reviewed.However,the modification of kaolinite is hard,the manufacture of a large number of kaolinite-based photocatalysts is difficult,the cost of doping noble metals is expensive,and the utilization rate of visible light is low,which limits its application in industrial practice.Finally,this paper presents some perspectives on the future development of kaolinite-based photocatalysts. | Zhou Cao Qizhao Wang Hongfei Cheng | 2021 | Chinese Chemical Letters2021，32，9： | 3 |
| 2 | Sodium tungsten bronze(Na_(x)WO_(3))-doped near-infrared-shielding bulk glasses for energy-saving applications显示文摘Tungsten bronze coatings and films have attracted global attention for their applications in near-infrared(NIR)-shielding windows.However,they are unstable in strong ultraviolet,humid heat,alkaline and/or oxidizing environments and are difficult to be coated on glass surfaces with complex shape.Here,we address these limitations by doping sodium tungsten bronze(Na_(x)WO_(3))into bulk glasses using a simple glass melting method.X-ray diffraction,Raman spectroscopy,X-ray photoelectron spectroscopy,TEM and SEM-EDS characterization confirmed the presence of sodium tungsten bronze(Na_(x)WO_(3))functional units inside the 34SiO_(2)-38B_(2)O_(3)-28NaF glass matrix.Because the functional units are well protected by the glass matrix,the fabricated glasses are stable under hot,humid,oxidizing conditions,as well as under ambient conditions,with no change after 360 days.The NIR-shielding performance of these glasses can be adjusted to as high as 100%by varying WO_(x)concentration(2-8 mol%)and quenching temperature(1000-1400℃).With a content of 6 mol%WO_(x)and a quenching temperature of 1000℃,the bulk glass shows 63%transmission of visible light and only 11%transmission of NIR light at 1100 nm.Thermal insulation experiments show that the NIR-shielding performance of the glasses are far superior to commercial soda lime window glass or indium-doped tin oxide(ITO)glass,and comparable to cesium tungsten bronze coated glass.The novel bulk glasses have higher stability,simpler processing,and can be easily made into complex shapes,making them excellent alternative materials for energy-saving glasses. | Guang Yang Yunhang Qi Daming Hu Haochen Wang Hongfei Chen Liangmiao Zhang Chuanxiang Cao Bin Liu Fang Xia Yanfeng Gao | 2021 | Journal of Materials Science & Technology2021，，30： | 3 |
| 3 | Downregulation of HNRNPK in human cancer cells inhibits lung metastasis显示文摘Background: Lung cancer frequently occurs in the clinic, leading to poor prognosis and high mortality. Markers for early diagnosis of lung cancer are scarce, and further potential therapeutic targets are also urgently needed.Method: We established a new mouse model in which the specific gene HNRNPK(heterogeneous nuclear ribonucleoprotein K) was downregulated after administration of doxycycline. The lung metastatic nodules were investigated using bioluminescence imaging, micro-CT, and autopsy quantification.Results: Compared with the short hairpin negative control group, less lung metastatic nodules were formed in the short hairpin RNA group.Conclusion: Downregulation of HNRNPK in cancer cells can inhibit lung metastasis. | Mengyuan Li Wenlong Zhang Xingjiu Yang Hongfei Liu Lin Cao Weisha Li Le Wang Guoxin Zhang Ran Gao | 2019 | Animal Models and Experimental Medicine2019，2，4： | 2 |
| 4 | Soluble Sugar Content and Metabolism as Related to the Heat-Induced Chilling Tolerance of Loquat Fruit During Cold Storage显示文摘 | Xingfeng Shao Yong Zhu Shifeng Cao Hongfei Wang Yuxing Song | 2013 | Food and Bioprocess Technology2013，，12： | 1 |
| 5 | An Artificial Neural Network Ensemble Method for Fault Diagnosis of Proton Ex- change Membrane Fuel Cell System 显示文摘 | SHAO Meng ZHU Xin jian CAO Hongfei | 2014 | Energy2014，67，2： | 1 |
| 6 | Coordinatively unsaturated single Co atoms immobilized on C_(2)N for efficient oxygen reduction reaction显示文摘Developing cost-effective and high-efficiency oxygen reduction reaction(ORR)catalysts is imperative for promoting the substantial progress of fuel cells and metal-air batteries.The coordination and geometric engineering of single-atom catalysts(SACs)occurred the promising approach to overcome the thermodynamics and kinetics problems in high-efficiency electrocatalysis.Herein,we rationally constructed atomically dispersed Co atoms on porous N-enriched graphene material C_(2)N(CoSA-C2N)for efficient oxygen reduction reaction(ORR).Systematic characterizations demonstrated the active sites for CoSA-C2N is as identified as coordinatively unsaturated Co-N_(2)moiety,which exhibits ORR intrinsic activity.Structurally,the porous N-enriched graphene framework in C_(2)N could effectively increase the accessibility to the active sites and promote mass transfer rate,contributing to improved ORR kinetics.Consequently,CoSA-C_(2)N exhibited superior ORR performance in both acidic and alkaline conditions as well as impressive long-term durability.The coordination and geometric engineering of SACs will provide a novel approach to advanced catalysts for energy related applications. | Wenjing Xu Yidong Sun Jiaqi Zhou Maoqi Cao Jun Luo Haili Mao Pengfei Hu Hongfei Gu Huazhang Zhai Huishan Shang Zhi Cai | 2023 | Nano Research2023，16，2： | 1 |
| 7 | A hybrid brain computer interface system based on the neurophysiological protocol and brain-actuated switch for wheelchair control显示文摘 | Lei Cao Jie Li Hongfei Ji Changjun Jiang | 2014 | Journal of Neuroscience Methods2014，，： | 1 |
| 8 | Training Students' PracticalInnovation Ability, by Building a Four Level Discipline CompetitionPlatform显示文摘 | Cao Pan Hui Ding Hongfei Liu | 2013 | International Conference on Education Technologyand Information System2013，23，9： | 1 |
| 9 | Numerical Analysis of the Hydrodynamic Behavior of a Remotely Operated Vehicle in Multi-Directional Flow显示文摘In recent years,Remotely Operated Vehicles(ROVs)have played an increasingly important role in the construc-tion and monitoring of underwater pile foundations.However,due to the open frame structure of such vehicles,a gap of knowledge still exists with regard to their hydrodynamic behavior.In this study,the hydrodynamic stability of such vehicles is investigated numerically by means of a multiple reference frame method.The hydrodynamic characteristics of the ROV when it moves horizontally and upward in the vertical plane are examined.It is found that there is interference between the horizontal and vertical thrusters of the ROV.There is also interference between the propeller thrust and drag(or lift).The effect of the vertical thrusters can increase the horizontal thrust by about 5%.The horizontal thrusters create a low-pressure area below the body,which can make vertical drag experienced by the ROV significantly higher. | Hongfei Cao Zhongda Lyu Xi Peng Zhuo Zhao | 2023 | Fluid Dynamics & Materials Processing2023，19，9： | 0 |
| 10 | Analysis of Farmers' Needs for Forestry Information and Technology in Yunnan's Hot Zone: Based on Empirical Survey in Menglian County显示文摘Lack of public forestry information and techniques has restricted the development of forestry management and the income increase of rural farmers in hot region of Yunnan province. Therefore it is necessary to provide forestry information and techniques to rural areas so as to compensate for the information gap between urban and rural areas. Based on the survey about farmer demand for information and technique in Menglian County,the paper analyzed the supply methods and demand characteristics of forestry information and techniques. The results showed that the farmers had very strong demands for forestry information and techniques with diversified trend. But the farmers got the information with backward method and single service supply approach,and it lacked effective expression mechanism for their demands. | Hongfei SHI Yanhui PEI Fan ZHANG Wenzhong YANG Yongpeng LI Jianxin CAO Lei WANG | 2015 | Asian Agricultural Research2015，7，2： | 0 |
| 11 | Production of Potash and N-Mg Compound Fertilizer via Mineral Shoenite from Kunteyi Salt Lake:Phase Diagrams of Quaternary System(NH_(4))_(2)SO_(4)-MgSO_(4)-K_(2)SO_(4)-H_(2)O in the Isothermal Evaporation and Crystallization Process显示文摘Based on the requirement of the new technology for producing potassium sulfate and N-Mg compound fertilizer,boussingaultite,by the reaction of the mineral shoenite from Kunteyi Salt Lake,Qinghai province,and the industrial by-product ammonium sulfate,the solubilities of the quaternary system(NH_(4))_(2)SO_(4)-MgSO_(4)-K_(2)SO_(4)-H_(2)O at 25.0℃in the isothermal evaporation and crystallization process were measured using the isothermal evaporation method,and the corresponding phase diagrams were plotted.According to the diagram,this system contains six saturation points and six solid phase fields of crystallization,which correspond to(K1-m,(NH_(4))m)_(2)SO_(4),(NH_(4))_(2)SO_(4)·MgSO_(4)·6H_(2)O,K_(2)SO_(4)·MgSO_(4)·6H_(2)O,MgSO_(4)·6H_(2)O,(K1-n,(NH_(4))n)_(2)SO_(4)·MgSO_(4)·6H_(2)O and MgSO_(4)·7H_(2)O,respectively.By analyzing and calculating the isothermal evaporation and dissolution phase diagram of this quaternary system at 25.0℃,K_(2)SO_(4)and(NH_(4))_(2)SO_(4)·MgSO_(4)·6H_(2)O can be separated via K_(2)SO_(4)·MgSO_(4)·6H_(2)O and(NH_(4))_(2)SO_(4)as raw materials.Theoretical calculations about the proposed process were carried out and verified by experiment,which indicated that the yield of potassium sulfate was improved and the magnesium resources were fully utilized. | LI Cheng CHEN Xueqing GUO Hongfei ZHOU Xue CAO Jilin | 2021 | Acta Geologica Sinica(English Edition)2021，95，3： | 0 |
| 12 | Synthesis of depsipeptides from L-amino acids and lactones显示文摘By using the corresponding L-amino acid sodium as initiator,ε-caprolactone-depsipeptides CL-Ala and CL-Leu were prepared by the reactions ofε-caprolactone(CL)with L-alanine and L-leucine,respec-tively,and p-dioxanone-depsipeptide(PDO-Leu)was prepared by the reaction of p-dioxanone(PDO)with L-leucine.Two poly(ε-caprolactone)oligomers(PCL-Ala and PCL-Leu)of different molecular weights with depsipeptide unit were synthesized by controlling the feed ratio of L-amino acid sodium and CL.The presence of the depsipeptide structure in these obtained products was confirmed by 1H NMR spectra and the molecular weight of the poly(ε-caprolactone)oligomers was measured by gel permeation chromatography(GPC).These products con-tain a hydroxyl group and a carboxyl group in one molecule,which means they could act as bifunctional monomers for further polymerization to prepare high molecular weight polymers.By this way,the depsipeptide unit could be introduced into the polymers and the biodegradation rates of the novel polymers could be well controlled in vivo by the tailored molecular structures. | Hongfei CAO Yakai FENG Heyun WANG Li ZHANG Musammir KHAN Jintang GUO | 2011 | Frontiers of Chemical Science and Engineering2011，5，4： | 0 |
| 13 | Green synthesis of ZSM-5 using silica fume and catalytic co-cracking of lignin and plastics for production of monocyclic aromatics显示文摘ZSM-5 with hierarchical pore structure was synthesized by a simple two-step hydrothermal crystallization from silica fume without using any organic ammonium templates.The synthesized ZSM-5 were oval shaped particles with a particle size about 2.0 μm and weak acid-dominated with proper Brønsted(B)and Lewis(L)acid sites.The ZSM-5 was used for catalytic co-cracking of n-octane and guaiacol,lowdensity polyethylene(LDPE)and alkali lignin(AL)to enhance the production of benzene,toluene,ethylbenzene and xylene(BTEX).The most significant synergistic effect occurred at n-octane/guaiacol at 1:1 and LDPE/AL at 1:3,under the condition,the achieved BTEX selectivity were 24%and 33%(mass)higher than the calculated values(weighted average).The highest BTEX selectivity reached 88.5%,which was 3.7%and 54.2%higher than those from individual cracking LDPE and AL.The synthesized ZSM-5 exhibited superior catalytic performance compared to the commercial ZSM-5,indicating potential application prospect. | Hongbing Fu Yufei Gu Tianhua Gao Fuwei Li Hengshuo Gu Hucheng Ge Yuke Liu Zhixia Li Hongfei Lin Jiangfei Cao | 2024 | Chinese Journal of Chemical Engineering2024，65，1： | 0 |
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