| 3 | Influence of the angle between two crown ether moieties on supramolecular copolymerization of bis(crown ether)s and bisparaquat homoditopic monomers显示文摘Bis(crown ether) homoditopic monomers containing two bis(p-phenylene)-34-crown-10 moieties with different angles(180° for monomer 3,120°for monomer 4,and 60°for monomer 5) and a complementary bisparaquat homoditopic monomer(7) were designed and synthesized.The three bis(crown ether) monomers could organize into linear supramolecular polymers in concentrated solutions in CHCl3/CH3CN with the bisparaquat monomer 7,as demonstrated by 1 H NMR and viscosity studies. The pseudorotaxanes or supramolecular polymers formed from 3+7 and 4+7 had larger values of Ka,p,n,slope 1,and slope 2 than those of 5+7.This result was attributed to the greater steric hindrance of compound 5 than that of 3 and 4,which resulted in less effective formation of linear supramolecular polymers from 5 with compound 7 than those from compounds 3 and 4 with compound 7,as also demonstrated by UV-vis method. | Zhou, QiZhong Jiang, HuaJiang Ding, Liang Wang, Feng Wu, Tao | 2010 | Science China Chemistry2010，53，5： | 0 |
| 4 | Influence of moderate hypothermia on cerebral oxygenation in pigs with intracranial hypertension显示文摘BACKGROUND: Moderate hypothermia is one of the effective therapeutic methods for head injury in recent years, there are many mechanisms of moderate hypothermia for brain protection, and its influence on cerebral oxygenation is also one of them. OBJECTIVE: To observe the influence of moderate hypothermia on cerebral oxygenation of animals with acute intracranial hypertension, and further investigate the protective mechanism of moderate hypothermia. DESIGN: A randomized controlled trial. SETTING: Department of Neurosurgery, Renji Hospital affiliated to the Medical College of Shanghai Jiao Tong University. MATERIALS: Twenty healthy little pigs, either male or female, weighing 4.5–5.5 kg, were used. Neurotrend-typed multiparameter monitoring system (Diametrics Company, British); CMA/100 micro-injection pump (Carnegie Company, Sweden). METHODS: The experiment was conducted in the Changzheng Hospital affiliated to the Second Military Medical University of Chinese PLA in November, 2001. The pigs were randomized into two groups: the normothermia group (control group, n =10) and moderate hypothermia group (n =10). ① Bilateral femoral arteries were separated, one was connected to pressometer for monitoring mean arterial pressure (MEP), and the other for analysis of blood gases [including peripheral blood pH value, arterial partial pressure of carbon dioxide (PaCO2), arterial partial pressure of carbon dioxide (PaCO2), HCO3–]. ② Rectal temperature was monitored with mercurial thermometer. ③ Intracranial pressure was monitored using Camino optic ICP probe placed in the subdural space. ④ Neurotrend multiparameter monitoring sensor was inserted into the white matter for about 4 cm to determine cerebral perfusion pressure (CPP, CPP=MAP(ICP), brain tissue partial oxygen pressure (PO2), partial pressure of carbon dioxide (PCO2), HCO3– and brain temperature. The rectal temperature of animals in the moderate hypothermia group was lowered to 34 ℃ using ice bags, and the body temperature was maintained at 33–35 ℃ for 2 hours. The changes of the parameters were observed continuously, and the pigs in the normothermia group were not treated with cooling. MAIN OUTCOME MEASURES: ① MAP, ICP, rectal temperature, CCP; Indexes of cerebral oxygenation detected with Neurotrend-typed multiparameter monitoring system; ② Results of blood gases analysis in the moderate hypothermia group. RESULTS: All the 20 pigs were involved in the analysis of results. ① MAP, ICP, rectal temperature, CCP and indexes of cerebral oxygenation: In the moderate hypothermia group, the ICP after cooling was obviously lower than that before cooling [(3.31±1.19), (5.33±0.95) kPa, P < 0.05], CCP was higher, brain tissue PCO2 [(12.03±1.73), (10.59±2.01) kPa, P < 0.05], and brain tissue pH value was higher [(7.03± 1.63), (9.40±1.30) kPa, P < 0.05], whereas the brain temperature was decreased as compared with that before cooling [(34.9±0.3), (37.2±0.2) ℃, P < 0.05]. ② Results of blood gases analysis in the moderate hypothermia group: There were no significant differences in the parameters of peripheral arterial blood gases analysis before and after cooling in the moderate hypothermia group (P > 0.05) CONCLUSION: Moderate hypothermia will not impair the cerebral oxygenation, and it can reduce brain tissue CO2 and decrease brain tissue acidosis. | Yinghui Bao Yumin Liang Jiyao Jiang Qizhong Luo Yicheng Lu | 2007 | Neural Regeneration Research2007，2，5： | 0 |
| 5 | Palaeomagnetic Study on the Precambrian-Cambrian Boundary Candidate Stratotype Section at Meishucun, Yunnan显示文摘The Meishucun secton has been recommended as an international candidate stratotype secton of thePrecambrian-Cambrian boundary. The paper deals with the palaeomagnetic study on the section. A total of159 palaeomagnetic samples were successively collected from the platform-facies sequence of carbonates andphosphates at the section. Thermal demagnetization results indicate a great majority of the rocks at the sectionhave been strongly overprinted by recent magnetic field, but 57 samples have preserved remanentmagnetization with antipodal directions (mean D/I=4.2°/ 7.1°, K=9, α95 = 6.6°). Baaed on calculation,the location of the palaeomagnetic pole was at 68.8°N and 270.7°E, which is different from any palaeopolesobtained from younger Phanerozoic rocks in South China. The results reveal a polarity zonation which in-cludes at least 9 reversal events. A comparison of China’s magnetostratigraphic records with those fromSiberia, Australia and the western U.S.A. shows that all the sections are characterized by frequent polarity re-versals. | Liang Qizhong Fang Wu Rob Van der Voo Yunnan Institute of Geological Science, Kunming,Yunnan Department of Geological Sciences,University of Michigan,Ann Arbor, MI.48109-1063, U.S.A. Liu Linqun | 1991 | Acta Geologica Sinica(English Edition)1991，65，1： | 0 |
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