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| 1 | Unveiling the Effects of Interchain Hydrogen Bonds on Solution Gelation and Mechanical Properties of Diarylfluorene-Based Semiconductor Polymers显示文摘The intrinsically rigid and limited strain of most conjugated polymers has encouraged us to optimize the extensible properties of conjugated polymers.Herein,learning from the hydrogen bonds in glucose,which were facilitated to the toughness enhancement of cellulose,we introduced interchain hydrogen bonds to polydiarylfluorene by amide-containing side chains.Through tuning the copolymerization ratio,we systematically investigated their influence on the hierarchical condensed structures,rheology behavior,tensile performances,and optoelectronic properties of conjugated polymers.Compared to the reference copolymers with a low ratio of amide units,copolymers with 30%and 40%amide units present a feature of the shearthinning process that resembled the non-Newtonian fluid,which was enabled by the interchain dynamic hydrogen bonds.Besides,we developed a practical and universal method for measuring the intrinsic mechanical properties of conjugated polymers.We demonstrated the significant impact of hydrogen bonds in solution gelation,material crystallization,and thin film stretchability.Impressively,the breaking elongation for P4 was even up to~30%,which confirmed the partially enhanced film ductility and toughness due to the increased amide groups.Furthermore,polymer light-emitting devices(PLEDs)based on these copolymers presented comparable performances and stable electroluminescence(EL).Thin films of these copolymers also exhibited random laser emission with the threshold as low as 0.52μJ/cm^(2),suggesting the wide prospective application in the field of flexible optoelectronic devices. | Lubing Bai Yamin Han Chen Sun Xiang An Chuanxin Wei Wei Liu Man Xu Lili Sun Ning Sun Mengna Yu He Zhang Qi Wei Chunxiang Xu Yingguo Yang Tianshi Qin Linghai Xie Jinyi Lin Wei Huang | 2020 | Research2020，，1： | 2 |
| 2 | Alkyl-chain branched effect on the aggregation and photophysical behavior of polydiarylfluorenes toward stable deep-blue electroluminescence and efficient amplified spontaneous emission显示文摘The control of the condensed superstructure of light-emitting conjugated polymers(LCPs)is a crucial factor to obtain high performance and stable organic optoelectronic devices.Side-chain engineering strategy is an effective platform to tune inter chain aggregation and photophysical behaviour of LCPs.Herein,we systematically investigated the alkyl-chain branched effecton the conformational transition and photophysical behaviour of polydiarylfluorenes toward efficient blue optoelectronic devices.The branched side chain will improve materials solubility to inhibit interchain aggregation in solution according to DLS and optical analysis,which is useful to obtain high quality film.Therefore,our branched PEODPF,POYDPF pristine film present high luminance efficiency of 36.1%and 39.6%,enhanced about 20%relative to that of PODPF.Compared to the liner-type sides'chain,these branched chains also suppress chain planarization and improve film morphological stability effectively.Interestingly,the branched polymer also had excellent stable amplified spontaneous emission(ASE)behaviour with low threshold(4.72μJ/cm2)and a center peak of 465 nm,even thermal annealing at 220℃in the air atmosphere.Therefore,side-chain branched strategy for LCPs is an effective means to control interchain aggregation,film morphology and photophysical property of LCPs. | Lili Sun Ning Sun Lubing Bai Xiang An Bin Liu Chen Sun Lixiang Fan Chuanxin Wei Yamin Han Mengna Yu Jinyi Lin Dan Lu Ning Wang Linghai Xie Kang Shen Xinwen Zhang Yanan Xu Juan Cabanillas-Gonzalez Wei Huang | 2019 | Chinese Chemical Letters2019，30，11： | 1 |
| 3 | In Situ Super-Hindrance-Triggered Multilayer Cracks for Random Lasing inπ-Functional Nanopolymer Films显示文摘In situ self-assembly of semiconducting emitters into multilayer cracks is a significant solution-processing method to fabricate organic high-Q lasers.However,it is still difficult to realize from conventional conjugated polymers.Herein,we create the molecular super-hindrance-etching technology,based on theπ-functional nanopolymer PG-Cz,to modulate multilayer cracks applied in organic single-component random lasers.Massive interface cracks are formed by promoting interchain disentanglement with the super-steric hindrance effect ofπ-interrupted main chains,and multilayer morphologies with photonic-crystal-like ordering are also generated simultaneously during the drop-casting method.Meanwhile,the enhancement of quantum yields on micrometer-thick films(Φ=40%to 50%)ensures high-efficient and ultrastable deep-blue emission.Furthermore,a deep-blue random lasing is achieved with narrow linewidths~0.08 nm and high-quality factors Q≈5,500 to 6,200.These findings will offer promising pathways of organicπ-nanopolymers for the simplification of solution processes applied in lasing devices and wearable photonics. | Dongqing Lin Yang Li He Zhang Shuai Zhang Yuezheng Gao Tianrui Zhai Shu Hu Chuanxiang Sheng Heng Guo Chunxiang Xu Ying Wei Shifeng Li Yelong Han Quanyou Feng Shasha Wang Linghai Xie Wei Huang | 2023 | Research2023，，3： | 0 |
| 4 | Enhancement of morphological and emission stability of deep-blue small molecular emitter via a universal side-chain coupling strategy for optoelectronic device显示文摘Film morphology of emissive layers is crucial to the performance and stability of solution-processable organic light-emitting diodes(OLEDs). Compared to the interpenetration of conjugated polymer chain,small molecular emitter with a flexible side chain always presents easily aggregation upon external treatment, and caused π-electronic coupling, which is undesirable for the efficiency and stability of deep-blue OLEDs. Herein, we proposed a side-chain coupling strategy to enhance the film morphological an emission stability of solution-processable small molecular deep-blue emitter. In contrary to “parent” MC8 TPA,the crosslinkable styryl and vinyl units were introduced as ended unit at the side-chain of Cm TPA and OEYTPA. Interestingly, Cm TPA and OEYTPA films present a relatively stable morphology and uniform deep-blue emission after thermal annealing(160 ℃) in the atmosphere, different to the discontinuous MC8 TPA annealed film. Besides, compared to the Cm TPA and OEYTPA ones, serious polaron formation in the MC8 TPA annealed film also negative to the deep-blue emission, according to transient absorption analysis. Therefore, both Cm TPA and OEYTPA annealed film obtained at 140 ℃ present an excellent deep-blue ASE behavior with a 445 nm, but absence for MC8 TPA ones, associated with the disruption of annealed films. Finally, enhancement of device performance based on Cm TPA and OEYTPA film(~40%)after thermal annealing with a similar performance curves also confirmed the assumption above. Therefore, these results also supported the effectiveness of our side-chain coupling strategy for optoelectronic applications. | Ning Sun Han Gao Lili Sun Jingxi An Man Xu Chen Sun Yamin Han Jinyi Lin Jiangli Cai Mingjian Ni Liangliang He Jinghao Yang Zhoulu Wang Lubing Bai Xinwen Zhang Qi Wei Xuehua Ding Chengrong Yin Linghai Xie Wei Huang | 2022 | Chinese Chemical Letters2022，33，2： | 0 |
| 5 | Novel Porphyrin-Containing Polymer Based Memristor for Synaptic Plasticity Simulation显示文摘The porphyrin-based copolymer PZnTPP-SFX is designed and synthesized by alternating porphyrin and spiro[fluorene-9,9'-xanthene]via Suzuki copolymerization.A simple memristor structure of ITO/ZnTPP-SFX/AlOx/Al was fabricated by spin-coating process.The conventional synaptic plasticity is emulated using the single memristor including nonlinear transmission characteristics,spike-timing dependent plasticity and spike-rate dependent plasticity.New spike-voltage dependent plasticity is also found in the memristor which can selectively perform potentiation and depression behaviors at a unipolar voltage.Compared with the device performance of uncoordinated metalloporphyrin polymer,it was found that oxygen vacancies diffuse and migrate into PZnTPP-SFX layer with the assist of coordination metal.This study suggests that porphyrin-based polymers have great promise for synaptic simulation of artificial neural network. | Linyi Bian Meng Xie Hao Chong Zhewei Zhang Guangyi Liu Qiushuo Han Jiaoyang Ge Zheng Liu Yang Lei Guangwei Zhang Linghai Xie | 2022 | Chinese Journal of Chemistry2022，40，20： | 0 |
| 6 | Degradation prediction of proton exchange membrane fuel cell stack using semi-empirical and data-driven methods显示文摘Degradation prediction of proton exchange membrane fuel cell(PEMFC)stack is of great significance for improving the rest useful life.In this study,a PEMFC system including a stack of 300 cells and subsystems has been tested under semi-steady operations for about 931 h.Then,two different models are respectively established based on semi-empirical method and data-driven method to investigate the degradation of stack performance.It is found that the root mean square error(RMSE)of the semi-empirical model in predicting the stack voltage is around 1.0 V,while the predicted voltage has no local dynamic characteristics,which can only reflect the overall degradation trend of stack performance.The RMSE of short-term voltage degradation predicted by the DDM can be less than 1.0 V,and the predicted voltage has accurate local variation characteristics.However,for the long-term prediction,the error will accumulate with the iterations and the deviation of the predicted voltage begins to fluctuate gradually,and the RMSE for the long-term predictions can increase to 1.63 V.Based on the above characteristics of the two models,a hybrid prediction model is further developed.The prediction results of the semi-empirical model are used to modify the input of the data-driven model,which can effectively improve the oscillation of prediction results of the data-driven model during the long-term degradation.It is found that the hybrid model has good error distribution(RSEM=0.8144 V,R2=0.8258)and local performance dynamic characteristics which can be used to predict the process of long-term stack performance degradation. | Yupeng Wang Kangcheng Wu Honghui Zhao Jincheng Li Xia Sheng Yan Yin Qing Du Bingfeng Zu Linghai Han Kui Jiao | 2023 | Energy and AI2023，11，1： | 0 |
| 7 | Photoexcitation dynamics and energy engineering in supramolecular doping of organic conjugated molecules显示文摘Doping and blending strategies are crucial means to precisely control the excited states and energy level in conjugated molecular systems.However,effective models and platforms are rarely proposed to systematically explore the effects of the formation of trapped doped centers on heterogeneous structures,energy level and ultrafast photophysical process.Herein,for deeply understanding the impact of molecular doping in film energy levels and photoexcitation dynamics,we set a supramolecular N-B coordination composed by the conjugated molecules of pyridine functionalized diarylfluorene(host material),named as ODPF-Phpy and ODPF-(Phpy)2,and the molecule of tris(perfluorophenyl)borane(BCF)(guest material).The generation of the molecular-level coordination bond increased the binding energy of N atoms and tuned the band-gap,leading to a new fluorescent emission center with longer excitation wavelength and emission wavelength.The intermolecular Forster resonance energy transfer(FRET)in blending flms make it present inconsistent fluorescent behaviors compared to that in solution.The charge transfer(CT)state of N-B coordinated compounds and the changed dielectric constant of blending films resulted in a large PL spectra red-shift with the increased dopant ratio,causing a wide-tunable fluorescent color.The excited state behaviors of two compounds in blending system was further investigated by the transient absorption(TA)spectroscopy.Finally,we found supramolecular coordination blending can effectively improve the films'photoluminescence quantum yield(PLQY)and conductivity.We believe this exploration in the internal coordination mechanisms would deepen the insights about doped semiconductors and is helpful in developing novel high-efficient fluorescent systems. | Xiang An Chuanxin Wei Lubing Bai Jun Zhou Le Wang Yamin Han Lili Sun Jinyi Lin Heyuan Liu Jiewei Lil Man Xu Haifeng Ling Linghai Xie Wei Huang | 2023 | Light(Science & Applications)2023，12，2： | 0 |
| 8 | Intrinsically Viscoelastic Supramolecular Conjugated Polymer toward Suppressing Coffee-Ring Effect显示文摘The rational molecular design of light-emitting conjugated polymers that inherently suppress the ubiquitous coffee-ring effect(CRE)is a great challenge and the critical bottleneck for printing displays.Herein,we describe a supramolecular route to construct an intrinsically viscoelastic rigid conjugated polymer(RCP)(PHDPF-Cz)toward avoiding the CRE without sacrificing optoelectronic properties.Theπ-πstacking interactions derived fromthe pendant carbazole(Cz)units enable PHDPF-Cz to self-assemble into criss-cross nanofibers and endow its solutionwith great viscosity.Consequently,a high-quality and continuous PHDPFCz film was obtained by impeding the transport of aggregates to the droplet edge due to outward capillary flow during evaporation,in sharp contrast to the random aggregate migration and rapid precipitation generated fromthe controlled poly[4-(6-(9H-diphenylaniline-9-yl)hexyloxy)-9,9-diphenylfluorene]-co-[5-(6-(9H-diphenylaniline-9-yl)hexyloxy)-9,9-diphenylfluorene]and poly(9,9-dioctylfluorene)solutions.Finally,an efficient random laser is also achieved based on these cross-linked films with ultrastable single-chain excitonic behavior,confirming the effectiveness of our design strategy. | Yamin Han Lubing Bai Xiang An Man Xu Chuanxin Wei Zongqiong Lin Mengna Yu Jinyi Lin Lili Sun Ning Sun Changting Wei Linghai Xie Xuehua Ding Qi Wei Chengrong Yin Chenghui Li Wenming Su Wei Huang | 2022 | CCS Chemistry2022，4，11： | 0 |
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